Aluminum Nickel Isopropoxide

CAS #:

Linear Formula:

Ni[Al(OCH(CH3)2)4]2

MDL Number:

MFCD00143593

EC No.:

N/A

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Aluminum Nickel Isopropoxide
AL-NIIP-01
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Aluminum Nickel Isopropoxide Properties (Theoretical)

Compound Formula C24H56Al2NiO8
Molecular Weight 584.92
Appearance Green powder or liquid
Melting Point N/A
Boiling Point 120 °C (0.6mm)
Density N/A
Solubility in H2O N/A
Exact Mass N/A
Monoisotopic Mass N/A
Charge N/A

Aluminum Nickel Isopropoxide Health & Safety Information

Signal Word Warning
Hazard Statements H228-H351-H315-H319-H317-H335
Hazard Codes N/A
Risk Codes 11-36/37/38-40-43
Safety Statements 16-24-26-36/37
RTECS Number N/A
Transport Information UN3181 4.1/PG III
WGK Germany N/A
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/06/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Aluminum Nickel Isopropoxide

Product Number: All applicable American Elements product codes, e.g. AL-NIIP-01

CAS #: 70504-57-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H336 May cause drowsiness or dizziness.
Hazards not otherwise classified No data available
GHS label elements, including precautionary statements

Flame - GHS02Exclamation Mark - GHS07 Health Hazard - GHS08

Hazard pictograms
GHS02 GHS07 GHS08
Signal word Danger
Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
B2 - Flammable liquid
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1
3
1
Health (acute effects) = 1
Flammability = 3
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
70504-57-3 Aluminum nickel isopropoxide, 10% w/v inisopropanol


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Toxic metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Keep away from ignition sources.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Keep ignition sources away.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Store away from water/moisture.
Further information about storage conditions:
Store under dry inert gas.
This product is moisture sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and water.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Nickel and inorganic compounds, as Ni
mg/m3
ACGIH TLV 1.5, A5-inhalable particulate (metal)
0.2, A1-inhalable particulate (insoluble compounds)
0.1, A4-inhalable particulate (soluble compounds)
Austria Carcinogen
Denmark TWA 0.5
Finland TWA 0.1 (skin) Carcinogen
France VME 1; C3-Carcinogen
Germany Carcinogen
Hungary 0.005-STEL; Carcinogen (insoluble compounds)
Japan 1; 2B-Carcinogen
Korea TLV 1.5
Netherlands MAC-TGG 1; Carcinogen
1 (insoluble compounds)
Norway TWA 0.05
Poland TWA 0.25
Russia 0.05-STEL
Sweden NGV 0.5 (dust)
Switzerland MAK-W 0.5; Carcinogen
United Kingdom TWA 0.1
USA PEL 1
Isopropyl alcohol (2-Propanol)
ppm
ACGIH TLV 400; 500-STEL
Austria MAK 400
Belgium TWA 400; 500-STEL
Denmark TWA 200
France VLE 400
Germany MAK 400
Ireland TWA 400; 500-STEL (skin)
Japan TWA 400-STEL
Korea TWA 400; 500-STEL
Netherlands MAC-TGG 400 (skin)
Norway TWA 100
Poland TWA 900; 1200-STEL
Russia TWA 400-STEL
Sweden NGV 150; 250-STEL
Switzerland MAK-W 400
United Kingdom TWA 400; 500-STEL
OSHA PEL 400
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Green
Odor: Alcohol-like
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flash point: 12 °C (54 °F) (i-PrOH)
Flammability (solid, gas) No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures is possible.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: No data available
Density: No data available
Relative density No data available.
Vapor density No data available.
Evaporation rate No data available.
Solubility in / Miscibility with
Water: Decomposes
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts with strong oxidizing agents
Conditions to avoid No data available
Incompatible materials:
Oxidizing agents
Water/moisture
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Toxic metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: No effects known.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Causes skin irritation.
Eye irritation or corrosion: Causes serious eye irritation.
Sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: No effects known.
Carcinogenicity:
Suspected of causing cancer.
IARC-3: Not classifiable as to carcinogenicity to humans.
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure:
May cause drowsiness or dizziness.
May cause respiratory irritation.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
Nickel and nickel compounds may cause a form of dermatitis known as nickel itch. They may also cause intestinal disorders, convulsions and asphyxia. Airborne
nickel contaminated dusts are regarded as carcinogenic to the respiratory tract.
2-Propanol (isopropyl alcohol) may act as a local irritant and in high concentrations as a narcotic with symptoms such as headache, nausea, dizziness, vomiting,
mental depression, anesthesia, and coma. Similar symptoms may be caused by ingestion. It can cause corneal burns on contact with the eyes and has caused
teratogenic, mutagenic and reproductive effects in laboratory animals.
Subacute to chronic toxicity: No effects known.
Subacute to chronic toxicity: Aluminum may be implicated in Alzheimers disease. Inhalation of aluminum containing dusts may cause pulmonary disease.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN1219
UN proper shipping name
DOT Isopropanol (Isopropyl alcohol)
IMDG, IATA ISOPROPANOL (ISOPROPYL ALCOHOL)
Transport hazard class(es)
DOT
Class 3 Flammable liquids.
Label 3
Class 3 (F1) Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids.
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: N/A
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-D
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN1219, Isopropanol (Isopropyl alcohol), 3, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements, including precautionary statements
Hazard pictograms
GHS02 GHS07 GHS08
Signal word Danger
Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
This product is not listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical Substance Inventory. Use of this product is restricted
to research and development only. This product must be used by or directly under the supervision of a technically qualified individual as defined by TSCA. This
product must not be used for commercial purposes or in formulations for commercial purposes.
SARA Section 313 (specific toxic chemical listings)
70504-57-3 Aluminum nickel isopropoxide, 10% w/v inisopropanol
California Proposition 65
Prop 65 - Chemicals known to cause cancer
70504-57-3 Aluminum nickel isopropoxide, 10% w/v inisopropanol
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product contains nickel and is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know act of 1986 and
40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Aluminum Nickel Isopropoxide

Aluminum Nickel Isopropoxide is generally immediately available in most volumes, including bulk quantities. American Elements can produce most materials in high purity and ultra high purity (up to 99.99999%) forms and follows applicable ASTM testing standards; a range of grades are available including Mil Spec (military grade), ACS, Reagent and Technical Grade, Food, Agricultural and Pharmaceutical Grade, Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia). We can also produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. Typical and custom packaging is available, as is additional research, technical and safety (MSDS) data. Please contact us above for information on specifications, lead time and pricing.

Aluminum Nickel Isopropoxide Synonyms

2-Propanol, aluminum nickel(2+) salt (8:2:1) (9CI)

Chemical Identifiers

Linear Formula Ni[Al(OCH(CH3)2)4]2
MDL Number MFCD00143593
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID N/A
IUPAC Name N/A
SMILES N/A
InchI Identifier N/A
InchI Key N/A

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Aluminum

See more Aluminum products. Aluminum (or Aluminium) (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element. Aluminum Bohr Model Aluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. Aluminum was first predicted by Antoine Lavoisier 1787 and first isolated by Hans Christian Øersted in 1825. Aluminum is a silvery gray metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental AluminumAlthough it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements, it imparts a variety of useful properties.

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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