Ammonium Tetrachlorocuprate(II) Dihydrate

CAS #:

Linear Formula:

(NH4)2CuCl4 · 2H2O

MDL Number:

MFCD00150384

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Ammonium Tetrachlorocuprate(II) Dihydrate
AM-CUCL4-02.2HYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Ammonium Tetrachlorocuprate(II) Dihydrate
AM-CUCL4-03.2HYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Ammonium Tetrachlorocuprate(II) Dihydrate
AM-CUCL4-04.2HYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Ammonium Tetrachlorocuprate(II) Dihydrate
AM-CUCL4-05.2HYD
Pricing > SDS > Data Sheet >

Ammonium Tetrachlorocuprate(II) Dihydrate Properties (Theoretical)

Compound Formula H12Cl4CuN2O2
Molecular Weight 277.47
Appearance Blue crystalline solid
Melting Point 110° C
Boiling Point N/A
Density 1.993
Solubility in H2O N/A
Exact Mass 276.891936
Monoisotopic Mass 276.891936

Ammonium Tetrachlorocuprate(II) Dihydrate Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Risk Codes 36/37/38
Safety Statements 26-36
RTECS Number N/A
Transport Information N/A
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 04/18/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Ammonium Tetrachlorocuprate(II) Dihydrate

Product Number: All applicable American Elements product codes, e.g. AM-CUCL4-02.2HYD , AM-CUCL4-03.2HYD , AM-CUCL4-04.2HYD , AM-CUCL4-05.2HYD

CAS #: 10060-13-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.
Label Elements
Signal Word:
Warning
Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation

Exclamation Mark - GHS07

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component:
Cuprate(2-), tetrachloro-, diammonium, dihydrate
CAS-No.: 10060-13-6
Weight %: <=100


SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.
Most important symptoms and effects
None reasonably foreseeable.
Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media Not combustible.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Nitrogen oxides (NOx). Hydrogen chloride. Ammonia. Copper oxides.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
NFPA
Health - 2
Flammability - 0
Instability - 0
Physical hazards -


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust
formation.
Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological
Information. Do not allow material to contaminate ground water system. Do not flush into
surface water or sanitary sewer system.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed
containers for disposal.


SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid
ingestion and inhalation. Avoid dust formation. Do not get in eyes, on skin, or on clothing.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid Crystalline
Appearance No information available
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range 110 °C / 230 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity 1.993 g/cm3
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula CuCl2.2NH4 Cl.2H2 O
Molecular Weight 277.46 (241.43anhy)


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products.
Incompatible Materials Oxidizing agent
Hazardous Decomposition Products Nitrogen oxides (NOx), Hydrogen chloride, Ammonia, Copper oxides
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
No information available
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.
Persistence and Degradability based on information available. May persist
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG/IMO Not regulated


SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazard Categories See section 2 for more information
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Ammonium Tetrachlorocuprate(II) Dihydrate

Ammonium Tetrachlorocuprate(II) Dihydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Ammonium Tetrachlorocuprate(II) Dihydrate Synonyms

Ammonium copper(2+) chloride hydrate (2:1:4:2); Ammonium copper(II) chloride dihydrate; Ammonium tetrachlorocuprate(2-) hydrate (2:1:2); Ammonium copper chloride

Chemical Identifiers

Linear Formula (NH4)2CuCl4 · 2H2O
MDL Number MFCD00150384
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 16210985
IUPAC Name diazanium; tetrachlorocopper(2-); dihydrate
SMILES Cl[Cu-2](Cl)(Cl)Cl.O.O.[NH4+].[NH4+]
InchI Identifier InChI=1S/4ClH.Cu.2H3N.2H2O/h4*1H;;2*1H3;2*1H2/q;;;;+2;;;;/p-2
InchI Key LLMDTWKBBWCWNN-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

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