An ultra-low frictional interface combining FDTS SAMs with molybdenum disulfide.

Title An ultra-low frictional interface combining FDTS SAMs with molybdenum disulfide.
Authors X.'an Cao; X. Gan; Y. Peng; Y. Wang; X. Zeng; H. Lang; J. Deng; K. Zou
Journal Nanoscale
DOI 10.1039/c7nr06471c
Abstract

Interfacial friction is of crucial importance to ensure the friction-reducing and anti-wear properties of mechanical microstructures in micro/nanoelectromechanical systems (MEMS/NEMS). An ultra-low frictional interface combining hydrophobic 1H,1H,2H,2H-perfluorodecyltrichlorosilane (FDTS) self-assembled monolayers (SAMs) coated on an AFM tip with mechanically exfoliated molybdenum disulfide (MoS2) nanosheets deposited on a planar Si/SiO2 substrate was achieved. The FDTS SAMs/MoS2 interface between the FDTS SAMs and the MoS2 nanosheets exhibits an ultra-low friction force that is independent of the relative humidity. The incommensurate contact with ultra-low energy dissipation between FDTS and MoS2 nanosheets and hydrophobic surface properties lead to this ultra-low frictional FDTS SAMs/MoS2 interface. Also, the MoS2 nanosheets have a high elastic modulus, which gives them a smaller contact area than the FDTS SAMs and contributes to the low friction. The excellent hydrophobic properties of both the FDTS SAMs and MoS2 enable them to be unaffected by the relative humidity by preventing the capillary interaction. This study paves the way for extensive applications in reducing the friction of nanoscale contact interfaces.

Citation X.'an Cao; X. Gan; Y. Peng; Y. Wang; X. Zeng; H. Lang; J. Deng; K. Zou.An ultra-low frictional interface combining FDTS SAMs with molybdenum disulfide.. Nanoscale. 2017. doi:10.1039/c7nr06471c

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See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

Sulfur

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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