Antimony- and Bismuth-Based Chalcogenides for Sodium-Ion Batteries.

Title Antimony- and Bismuth-Based Chalcogenides for Sodium-Ion Batteries.
Authors B. Xu; S. Qi; P. He; J. Ma
Journal Chem Asian J
DOI 10.1002/asia.201900784
Abstract

Sodium-ion batteries (SIBs) have received much attention, owing to their great potential for large-scale application. A lack of efficient anode materials with high reversible capacity is one main challenge facing the development of SIBs. Antimony- and bismuth-based chalcogenides materials can store large amounts of Na ions, owing to the alloying/dealloying reaction mechanism within a low potential range, and thus, are regarded as promising anodes for SIBs. However, these materials face great challenges of poor ion diffusion rate, multiple phase transformations, and severe morphology pulverization. Herein, recent developments in antimony- and bismuth-based chalcogenides materials, mainly rational structural design strategies used and the electrochemical reaction mechanisms involved, are summarized. Perspectives for further improving antimony- and bismuth-based chalcogenides anodes are also provided.

Citation B. Xu; S. Qi; P. He; J. Ma.Antimony- and Bismuth-Based Chalcogenides for Sodium-Ion Batteries.. Chem Asian J. 2019;14(17):29252937. doi:10.1002/asia.201900784

Related Elements

Antimony

See more Antimony products. Antimony (atomic symbol: Sb, atomic number: 51) is a Block P, Group 15, Period 5 element with an atomic radius of 121.760. Antimony Bohr Model The number of electrons in each of antimony's shells is 2, 8, 18, 18, 5 and its electron configuration is [Kr] 4d10 5s2 5p3. The antimony atom has a radius of 140 pm and a Van der Waals radius of 206 pm. Antimony was discovered around 3000 BC and first isolated by Vannoccio Biringuccio in 1540 AD. In its elemental form, antimony has a silvery lustrous gray appearance. Elemental Antimony The most common source of antimony is the sulfide mineral known as stibnite (Sb2S3), although it sometimes occurs natively as well. Antimony has numerous applications, most commonly in flame-retardant materials. It also increases the hardness and strength of lead when combined in an alloy and is frequently employed as a dopant in semiconductor materials. Its name is derived from the Greek words anti and monos, meaning a metal not found by itself.

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

Sodium

Sodium Bohr ModelSee more Sodium products. Sodium (atomic symbol: Na, atomic number: 11) is a Block D, Group 5, Period 4 element with an atomic weight of 22.989769. The number of electrons in each of Sodium's shells is [2, 8, 1] and its electron configuration is [Ne] 3s1. The sodium atom has a radius of 185.8 pm and a Van der Waals radius of 227 pm. Sodium was discovered and first isolated by Sir Humphrey Davy in 1807. In its elemental form, sodium has a silvery-white metallic appearance. It is the sixth most abundant element, making up 2.6 % of the earth's crust. Sodium does not occur in nature as a free element and must be extracted from its compounds (e.g., feldspars, sodalite, and rock salt). The name Sodium is thought to come from the Arabic word suda, meaning "headache" (due to sodium carbonate's headache-alleviating properties), and its elemental symbol Na comes from natrium, its Latin name.