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Barium 4-Diphenylamine Sulfonate

CAS #:

Linear Formula:

(C12H10NO3S)2Ba

MDL Number:

MFCD00007497

EC No.:

228-278-0

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
>95% Barium 4-Diphenylamine Sulfonate
BA4DPH-SUNAT-01-P
Pricing > SDS > Data Sheet >
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Barium 4-Diphenylamine Sulfonate Properties

Compound Formula

C24H20BaN2O6S2

Molecular Weight

633.88

Appearance

Off-white to faint yellowish-green powder

Melting Point

300 °C

Exact Mass

633.981526 g/mol

Monoisotopic Mass

633.981526 g/mol

Charge

0

Barium 4-Diphenylamine Sulfonate Health & Safety Information

Signal Word Danger
Hazard Statements H302-H332
Hazard Codes Xi
Risk Codes Xi
Safety Statements N/A
Transport Information NONH for all modes of transport
WGK Germany 1

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/27/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Barium 4-Diphenylamine Sulfonate

Product Number: All applicable American Elements product codes, e.g. BA4DPH-SUNAT-01-P

CAS #: 6211-24-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification
Acute toxicity - Oral Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Label elements
Signal word Warning
Hazard statements
HARMFUL IF SWALLOWED
HARMFUL IF INHALED
Symbols/Pictograms

Exclamation Mark - GHS07

Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after
handling
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF SWALLOWED: Call a POISON CENTER or doctor/physician if
you feel unwell
Rinse mouth
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal
plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
NFPA Health hazards 2 HMIS
Flammability 0
Instability -
Physical and chemicalproperties
-
Health hazards 2
Flammability 1
Physical hazards
Personal protection -


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

CAS No 6211-24-1
Molecular Weight 633.88
Formula C24H20BaN2O6S2
Chemical Name Barium diphenylamine-4-sulfonate
CAS No 6211-24-1
weight-% >98
Oral LD50, dermal LD50, Inhalation LC50 -


SECTION 4. FIRST AID MEASURES

First Aid Measures
General advice If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Do
not get in eyes, on skin, or on clothing.
Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms
persist, call a physician.
Skin Contact Consult a physician if necessary. Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes.
Inhalation Remove to fresh air. Call a physician. If breathing is irregular or stopped, administer
artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth
resuscitation.
Ingestion Rinse mouth. Drink plenty of water. If symptoms persist, call a physician. Do NOT induce
vomiting.
Self-protection of the first aider Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable Extinguishing Media None.
Specific hazards arising from the chemical
Specific hazards arising from the
chemical
No information available.
Hazardous combustion products Hydrogen sulfide. Carbon oxides. Nitrogen oxides (NOx).
Explosion data
Sensitivity to Mechanical Impact No information available.
Sensitivity to Static Discharge No information available.
Protective equipment and precautions for firefighters
Protective equipment and precautions
for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation, especially in confined areas.
Environmental precautions
Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into
surface water or sanitary sewer system. See Section 12 for additional Ecological
Information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Use personal protective equipment as required. Cover powder spill with plastic sheet or tarp
to minimize spreading and keep powder dry. Take up mechanically, placing in appropriate
containers for disposal. Avoid creating dust. Clean contaminated surface thoroughly.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray.
Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of
children. Store at room temperature.
Incompatible materials None known based on information supplied.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure Guidelines .
Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Barium diphenylamine-4-sulfonate
6211-24-1
TWA: 0.5 mg/m3 Ba TWA: 0.5 mg/m3 Ba
(vacated) TWA: 0.5 mg/m3 Ba
TWA: 0.5 mg/m3 except Barium
sulfate Ba
NIOSH IDLH Immediately Dangerous to Life or Health
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and Body Protection Wear protective gloves and protective clothing.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid
Appearance No information available
Odor No information available
Property Values
pH No information available
Melting point/freezing point No information available
Boiling point No information available
Flash point No information available
Density No information available
Evaporation rate No information available
Upper flammability limits No information available
Lower flammability limit No information available
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
Water solubility No information available
Solubility in other solvents No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available


SECTION 10. STABILITY AND REACTIVITY

Reactivity Not applicable
Chemical stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization No information available.
Conditions to avoid Extremes of temperature and direct sunlight.
Incompatible materials Strong oxidizing agents.
Hazardous Decomposition Products Hydrogen sulfide. Carbon oxides. Nitrogen oxides (NOx).


SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Inhalation No data available.
Eye contact No data available.
Skin Contact No data available.
Ingestion No data available.
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity No information available.
Numerical measures of toxicity - Product Information
Unknown acute toxicity No information available
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 500 mg/kg
ATEmix (inhalation-dust/mist) 1.5 mg/l


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity May cause long lasting harmful effects to aquatic life
100% of the mixture consists of components(s) of unknown hazards to the aquatic environment.
Persistence and degradability No information available.
Bioaccumulation No information available.
Mobility No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.
Other Information Waste codes should be assigned by the user based on the application for which the product
was used.
California Hazardous Waste Status This product contains one or more substances that are listed with the State of California as
a hazardous waste.
Chemical Name California Hazardous Waste Status
Barium diphenylamine-4-sulfonate
6211-24-1
Toxic Toxic soluble


SECTION 14. TRANSPORT INFORMATION

DOT
UN/ID no UN1564
Hazard Class 6.1
Packing Group III
Proper shipping name Barium compounds, n.o.s.
Description UN1564, Barium compounds, n.o.s. (Barium diphenylamine-4-sulfonate), 6.1, III
Emergency Response Guide Number 154
IMDG
UN/ID no UN1564
Hazard Class 6.1
Packing Group III
Proper shipping name Barium compound, n.o.s.
Description UN1564, Barium compound, n.o.s. (Barium diphenylamine-4-sulfonate), 6.1, III
Special Provisions IB8, IP3, T1, TP33
EmS-No
F-A, S-A
IATA
UN/ID no UN1564
Hazard Class 6.1
Packing Group III
Proper shipping name Barium compound, n.o.s.
Description UN1564, Barium compound, n.o.s., 6.1, III


SECTION 15. REGULATORY INFORMATION

International Inventories
All of the components in the product are on the following Inventory lists
TSCA (United States): Canada (DSL/NDSL) Europe (EINECS/ELINCS/NLP) Australia (AICS) South Korea (KECL): China (IECSC)
Philippines (PICCS)
Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
Barium
diphenylamine-4-sulfonate
X X - X - - X X X X
X - Listed
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Barium diphenylamine-4-sulfonate
6211-24-1
X Not Listed X


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Barium 4-Diphenylamine Sulfonate

Barium 4-Diphenylamine Sulfonate is one of numerous organometallic compounds sold by American Elements under the trade name AE Organometallics™. Organometallics are useful reagent, catalyst, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. American Elements supplies Barium 4-Diphenylamine Sulfonate in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time.

Barium 4-Diphenylamine Sulfonate Synonyms

Barium diphenylamine p-sulfonate; Barium 4-(phenylamino)benzenesulfonic acid; Barium diphenylaminesulfonate; Barium 4-(phenylamino)benzenesulfonate 4-(Phenylamino)benzenesulfonic acid barium salt, Diphenylamine-4-sulfonic acid barium salt

Barium 4-Diphenylamine Sulfonate Chemical Identifiers

Linear Formula

(C12H10NO3S)2Ba

Pubchem CID

517003

MDL Number

MFCD00007497

EC No.

228-278-0

Beilstein Registry No.

3795146

IUPAC Name

2-anilinobenzenesulfonate; barium(2+)

SMILES

C1=CC=C(C=C1)NC2=CC=C(C=C2)S(=O)(=O)[O-].C1=CC=C(C=C1)NC2=CC=C(C=C2)S(=O)(=O)[O-].[Ba+2]

InchI Identifier

InChI=1S/2C12H11NO3S.Ba/c2*14-17(15,16)12-8-6-11(7-9-12)13-10-4-2-1-3-5-10;/h2*1-9,13H,(H,14,15,16);/q;;+2/p-2

InchI Key

IVCNVXFNTKXMCA-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Barium products. Barium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental BariumIn its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getterer," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum as load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4) it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy.

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. In its elemental form, nitrogen's CAS number is 7727-37-9. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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