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Barium Molybdate

CAS #:

7787-37-3

Linear Formula:

BaMoO4

MDL Number:

MFCD00014182

EC No.:

232-111-7

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Barium Molybdate
BA-MOAT-02 Pricing > SDS > Data Sheet >
(3N) 99.9% Barium Molybdate
BA-MOAT-03 Pricing > SDS > Data Sheet >
(4N) 99.99% Barium Molybdate
BA-MOAT-04 Pricing > SDS > Data Sheet >
(5N) 99.999% Barium Molybdate
BA-MOAT-05 Pricing > SDS > Data Sheet >

Properties

Compound Formula

BaMoO4

Molecular Weight

297.26

Appearance

powder

Density

4.65 g/cm3

Exact Mass

299.790307

Monoisotopic Mass

299.790307

Health & Safety Information

Signal Word Warning
Hazard Statements H302-H332
Hazard Codes Xn
Risk Codes 20/22
Safety Statements 28
RTECS Number N/A
Transport Information UN 1564 6.1/PG 3
WGK Germany 1

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/25/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Barium Molybdate

Product Number: All applicable American Elements product codes, e.g. BA-MOAT-02 , BA-MOAT-03 , BA-MOAT-04 , BA-MOAT-05

CAS #: 7787-37-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Hazards not otherwise classified
No information known.
Label elements
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word
Warning
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
Precautionary statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P264
Wash thoroughly after handling.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/.../if you feel unwell.
P312
Call a POISON CENTER/doctor/.../if you feel unwell.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
7787-37-3 Barium molybdenum oxide
Identification number(s):
EC number: 232-111-7
Index number: 056-002-00-7


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Barium oxide
Molybdenum oxides
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
7787-37-3 Barium molybdenum oxide (100.0%)
PEL (USA) Long-term value: 15* mg/m³
as Mo, total dust
TLV (USA) Long-term value: 10*, 3** mg/m³
*as Mo, inhalable; **as Mo, respirable
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Color: White
Odor: Odorless
Odor threshold: Not determined
pH-value: Not applicable.
Change in condition
Melting point/Melting range: ca 1600 °C (ca 2912 °F)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 4.98 g/cm³ (41.558 lbs/gal)
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Barium oxide
Molybdenum oxides


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN1564
UN proper shipping name
DOT
Barium compounds, n.o.s. (Barium molybdenum oxide)
IMDG, IATA
BARIUM COMPOUND, N.O.S. (Barium molybdenum oxide)
Transport hazard class(es)
DOT
Class
6.1 Toxic substances.
Label
6.1
Class
6.1 (T5) Toxic substances
Label
6.1
IMDG, IATA
Class
6.1 Toxic substances.
Label
6.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
Not applicable.
Special precautions for user
Warning: Toxic substances
EMS Number: F-A,S-A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN1564, Barium compounds, n.o.s. (Barium molybdenum oxide), 6.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS07
Signal word
Warning
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
Precautionary statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P264
Wash thoroughly after handling.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/.../if you feel unwell.
P312
Call a POISON CENTER/doctor/.../if you feel unwell.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
7787-37-3 Barium molybdenum oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Molybdate IonBarium Molybdate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Barium molybdenum oxide, barium dioxido(dioxo)molybdenum, CAS 12323-01-2, Barium trioxomolybdate, BaMoO3

Chemical Identifiers

Linear Formula

BaMoO4

Pubchem CID

6101757

MDL Number

MFCD00014182

EC No.

232-111-7

Beilstein Registry No.

N/A

IUPAC Name

barium(2+); dioxido(dioxo)molybdenum

SMILES

[Ba+2].[O-][Mo]([O-])(=O)=O

InchI Identifier

InChI=1S/Ba.Mo.4O/q+2;;;;2*-1

InchI Key

RCMWGBKVFBTLCW-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Barium products. Barium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental BariumIn its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getterer," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum as load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4) it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy.

See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

Recent Research

Novel design of highly [110]-oriented barium titanate nanorod array and its application in nanocomposite capacitors., Yao, Lingmin, Pan Zhongbin, Zhai Jiwei, and Chen Haydn H. D. , Nanoscale, 2017 Mar 15, (2017)

Three Oxidation States of Manganese in the Barium Hexaferrite BaFe12-xMnxO19., Nemrava, Sandra, Vinnik Denis A., Hu Zhiwei, Valldor Martin, Kuo Chang-Yang, Zherebtsov Dmitry A., Gudkova Svetlana A., Chen Chien-Te, Tjeng Liu Hao, and Niewa Rainer , Inorg Chem, 2017 Mar 14, (2017)

Calix[3]carbazole: A C3-symmetrical receptor for barium ion., Yang, Zhaozheng, Tian Zhangmin, Yang Peng, Deng Tuo, Li Gang, Zhou Xue, Chen Yan, Zhao Liang, and Shen Hongyan , Spectrochim Acta A Mol Biomol Spectrosc, 2017 Mar 05, Volume 174, p.32-36, (2017)

Bio-Inspired Fluoro-polydopamine Meets Barium Titanate Nanowires: A Perfect Combination to Enhance Energy Storage Capability of Polymer Nanocomposites., Wang, Guanyao, Huang Xingyi, and Jiang Pingkai , ACS Appl Mater Interfaces, 2017 Mar 01, Volume 9, Issue 8, p.7547-7555, (2017)

Removal of Acetaminophen in Water by Laccase Immobilized in Barium Alginate., Ratanapongleka, Karnika, and Punbut Supot , Environ Technol, 2017 Mar 01, p.1-28, (2017)

Gastric polyps diagnosed by double-contrast upper gastrointestinal barium X-ray radiography mostly arise from the Helicobacter pylori-negative stomach with low risk of gastric cancer in Japan., Takeuchi, Chihiro, Yamamichi Nobutake, Shimamoto Takeshi, Takahashi Yu, Mitsushima Toru, and Koike Kazuhiko , Gastric Cancer, 2017 Mar, Volume 20, Issue 2, p.314-321, (2017)

Tunable pyroelectric properties of barium strontium titanate thin films., Shirokov, Vladimir, Razumnaya Anna, and Yuzyuk Yu , J Phys Condens Matter, 2017 Jan 05, (2017)

Synthesis of Barium Titanate Using Deep Eutectic Solvents., Boston, Rebecca, Foeller Philip Y., Sinclair Derek C., and Reaney Ian M. , Inorg Chem, 2017 Jan 03, Volume 56, Issue 1, p.542-547, (2017)

The Association Between Barium Examination and Subsequent Appendicitis: A Nationwide Population-Based Study., Li, Hao-Ming, Yeh Lee-Ren, Huang Ying-Kai, Lin Cheng-Li, and Kao Chia-Hung , Am J Med, 2017 Jan, Volume 130, Issue 1, p.54-60.e5, (2017)

Studies on the effects of titanate and silane coupling agents on the performance of poly (methyl methacrylate)/barium titanate denture base nanocomposites., Elshereksi, Nidal W., Ghazali Mariyam J., Muchtar Andanastuti, and Azhari Che H. , J Dent, 2017 Jan, Volume 56, p.121-132, (2017)

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