Ni(dmamb)2

CAS #:

Linear Formula:

C14H32N2O2Ni

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
>98% Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)
NI-OMX-018-LIQ
Pricing > SDS > Data Sheet >
(2N) 99% Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)
NI-OMX-02-LIQ
Pricing > SDS > Data Sheet >
(3N) 99.9% Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)
NI-OMX-03-LIQ
Pricing > SDS > Data Sheet >
(4N) 99.99% Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)
NI-OMX-04-LIQ
Pricing > SDS > Data Sheet >
5N (99.999%) Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)
NI-OMX-05-LIQ
Pricing > SDS > Data Sheet >

Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II) Properties (Theoretical)

Compound Formula C14H32N2O2Ni
Molecular Weight 319.115
Appearance Dark green viscous liquid
Melting Point <10 °C
Boiling Point 148 °C
Density N/A
Solubility in H2O N/A
Exact Mass 318.182 g/mol
Monoisotopic Mass 318.182 g/mol

Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II) Health & Safety Information

Signal Word Danger
Hazard Statements H315-H319-H334-H371
Hazard Codes T
Precautionary Statements P260-P261-P264-P270-P280-P285-P321-P362-P302+P352-P304+P341-P305+P351+P338-P309+P311-P332+P313-P337+P313-P342+P311-P405-P501
Flash Point 140 °C (Cleveland open cup)
Risk Codes R20/21/22 R42/43 R45
Safety Statements S24 S36/37 S45
Transport Information UN3398 4.3/PG II
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/19/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)

Product Number: All applicable American Elements product codes, e.g. NI-OMX-018-LIQ , NI-OMX-03-LIQ , NI-OMX-02-LIQ , NI-OMX-04-LIQ , NI-OMX-05-LIQ

CAS #: 942311-35-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Hazards description

Flame - GHS02 Health Hazard - GHS08

Emergency Overview
OSHA Hazards: Toxic, Harmful
Information pertaining to particular dangers for mans and environment
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R 43 May cause sensitization by skin contact
R 45 May cause cancer.
HMIS Classification: Health: 1; Flammability: 1; Reactivity: 1
NFPA Ratings: Health: 1; Flammability: 1; Reactivity: 1
Route of Exposure: Skin, Inhalation
Potential Health Effects
May cause cancer. Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Possible teratogen. Neurological hazard.
Target Organs: Respiratory system


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Description: Nickel(II) 1-dimethylamino-2-methyl-2-butoxide
Molecular Formula: C14H32N2O2Ni


SECTION 4. FIRST AID MEASURES

Eyes: In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
Skin: In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.
Ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media:
Suitable: Carbon dioxide, dry chemical powder, or appropriate foam.
Products of Combustion: CO, CO2, NOx, Nickel/Nickel oxide
Special Protective Equipment for Fire-Fighters: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Flash Point: Not available
Flammable Limits: Not available
Auto-Ignition Temperature: Not available.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Spill: Evacuate area.
Personal Precautions: Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.


SECTION 7. HANDLING AND STORAGE

Handling
Do not breathe dust. Avoid all contact. Avoid prolonged or repeated exposure.
Storage
Keep container tightly closed in a dry and well-ventilated place. Store in cool place.
Special Requirements
Hygroscopic.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls
Safety shower and eye bath. Use only in a chemical fume hood.
Personal Protective Equipment
Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
General Hygiene Measures
Wash thoroughly after handling. Discard contaminated clothing and shoes.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Dark green liquid
Molecular Weight: 319.13 g/mol
Melting Point: Not available
Boiling Point: 148℃ (298.4℉) at 3.32 torr
Flash Point: Not available
Volatility: Not available
Liquid Density: Not available
Vapor Pressure: 0.1 torr at 80℃
Solubility in water: React
Vapor Density: Not available
n-octanol/water Partition Coefficient: Not available
pH (1% soln/water): N/A


SECTION 10. STABILITY AND REACTIVITY

Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Moisture
Materials to Avoid: Strong oxidizing agents. Hazardous Decomposition Products: CO, CO2, NOx, Nickel/Nickel oxides
Hazardous Polymerization: Has not been reported.


SECTION 11. TOXICOLOGICAL INFORMATION

Route of Exposure
Skin Contact: Irritation
Eye Contact: Irritation
Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity: No information available.
Bioaccumulation: No information available.
Biodegredation: No information available.
Environmental Stability: No information available


SECTION 13. DISPOSAL CONSIDERATIONS

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accuate classification.


SECTION 14. TRANSPORT INFORMATION

UN No: 3398
CLASS: 4.3
Packing Group: Packing Group II
Proper Shipping Name: Organometallic substance, liquid, water-reactive
(Nickel(II) 1-dimethylamino-2-methyl-2-butoxide)


SECTION 15. REGULATORY INFORMATION

OSHA Hazards
Toxic
Product related hazard information:
Hazard symbols:
T Toxic
Risk phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R 42/43 May cause sensitization by inhalation and skin contact.
R 45 May cause cancer.
Safety phrases:
S 24 Avoid contact with the skin.
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II)

Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II) (Ni(dmamb)2) is a volatile nickel-based organometallic precursor for atomic layer or chemical vapor deposition of nickel thin films.

Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II) Synonyms

Ni(dmamb)2, bis(dimethylamino-2-methyl-2-butoxo)nickel, Nickel(II) 1-dimethylamino-2-methyl-2-butoxide, Bis(1-dimethylamino-2-methyl-2-butoxide)nickel(II)), Nickel(II) 1-dimethylamino-2-methyl-2-butoxide, Bis[1-methyl-1-[(dimethylamino)methyl]propyloxy] nickel(II), MABONi

Chemical Identifiers

Linear Formula C14H32N2O2Ni
MDL Number N/A
EC No. N/A
Pubchem CID 89558561
IUPAC Name 1-(dimethylamino)-2-methylbutan-2-olate; nickel(2+)
SMILES CCC(C)(CN(C)C)[O-].CCC(C)(CN(C)C)[O-].[Ni+2]
InchI Identifier InChI=1S/2C7H16NO.Ni/c2*1-5-7(2,9)6-8(3)4;/h2*5-6H2,1-4H3;/q2*-1;+2
InchI Key LECAMOYWYJUYIH-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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