Bis(isopropylcyclopentadienyl)nickel

CAS #:

Linear Formula:

[(C3H7)C5H4]2Ni

MDL Number:

MFCD01862459

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
>98% Bis(isopropylcyclopentadienyl)nickel
BCI-NI-018-LIQ
Pricing > SDS > Data Sheet >

Bis(isopropylcyclopentadienyl)nickel Properties (Theoretical)

Compound Formula C16H22Ni
Molecular Weight 273.04
Appearance Green liquid
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O Not miscible or difficult to mix
Exact Mass 272.107494 g/mol
Monoisotopic Mass 272.107494 g/mol

Bis(isopropylcyclopentadienyl)nickel Health & Safety Information

Signal Word Danger
Hazard Statements H225-H315-H319-H335-H350
Hazard Codes F, T
Risk Codes N/A
Safety Statements N/A
Transport Information UN1993 3/PG II
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/29/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Bis(isopropylcyclopentadienyl)nickel

Product Number: All applicable American Elements product codes, e.g. BCI-NI-018-LIQ

CAS #: 57197-55-4

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Carc. 1A H350 May cause cancer.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).

Flame - GHS02 Health Hazard - GHS08Exclamation Mark - GHS07

Hazard pictograms
GHS02 GHS07d GHS08
Signal word Danger
Hazard-determining components of labeling:
Bis(i-propylcyclopentadienyl)nickel, min. 98%
Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H350 May cause cancer.
H335 May cause respiratory irritation.
Precautionary statements
P231 Handle under inert gas.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P422 Store contents under inert gas.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
1


Health = 1
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*1


Health = *1
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS # / Substance Name
57197-55-4 Bis(i-propylcyclopentadienyl)nickel, min. 98%


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information: Immediately remove any clothing soiled by the product.
If inhaled: In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact: Immediately wash with soap and water; rinse thoroughly.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed: If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture No data available
Advice for firefighters
Protective equipment: No special measures required.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Environmental precautions: Prevent seepage into sewage system, workpits and cellars.
Methods and materials for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling: Handle under inert gas.
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities:
Keep cool.
Store contents under inert gas.
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Recommended storage temperature: Store at temperatures not exceeding -18 °C.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
SProtective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
RTightly sealed goggles


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Green
Odor: Odorless
Odor threshold: No data available.
pH: No data available
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
Flash point: N/A
Flammability (solid, gas): N/A
Ignition temperature:
Decomposition temperature: No data available.
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: no data hPa
Density: No data available.
Relative density No data available.
Vapor density No data available.
Evaporation rate No data available.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No data available
Incompatible materials: No data available
Hazardous decomposition products: No dangerous decomposition products known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Behavior in environmental systems:
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information: Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN1993
UN proper shipping name
DOT Flammable liquids, n.o.s.
IMDG FLAMMABLE LIQUID, N.O.S.
IATA Flammable liquid, n.o.s.
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-E
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": UN 1993 FLAMMABLE LIQUIDS, N.O.S., 3, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
Substance is not listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02d GHS07 GHS08
Signal word Danger
Hazard-determining components of labeling:
Bis(i-propylcyclopentadienyl)nickel, min. 98%
Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H350 May cause cancer.
H335 May cause respiratory irritation.
Precautionary statements
P231 Handle under inert gas.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P422 Store contents under inert gas.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
National regulations:
Additional classification according to Decree on Hazardous Materials:
Carcinogenic hazardous material group I (extremely dangerous).
Carcinogenic hazardous material group II (very dangerous).
Carcinogenic hazardous material group III (dangerous).
Information about limitation of use:
Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in
certain cases.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Bis(isopropylcyclopentadienyl)nickel

Bis(isopropylcyclopentadienyl)nickel is one of numerous organometallic compounds sold by American Elements under the trade name AE Organometallics™. Organometallics are useful reagent, catalyst, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. American Elements supplies Bis(isopropylcyclopentadienyl)nickel in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time.

Bis(isopropylcyclopentadienyl)nickel Synonyms

Bis(i-propylcyclopentadienyl)nickel, Bis(cycloocta-1,5-diene-1-yl) nickel(II)

Chemical Identifiers

Linear Formula [(C3H7)C5H4]2Ni
MDL Number MFCD01862459
EC No. N/A
Pubchem CID 71310856
IUPAC Name nickel(2+); 5-propan-2-ylcyclopenta-1,3-diene
SMILES CC(C)[C-]1C=CC=C1.CC(C)[C-]1C=CC=C1.[Ni+2]
InchI Identifier InChI=1S/2C8H11.Ni/c2*1-7(2)8-5-3-4-6-8;/h2*3-7H,1-2H3;/q2*-1;+2
InchI Key WTNNDNBKPMUIQG-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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