Bismuth Granules

CAS #:

Linear Formula:

Bi

MDL Number:

MFCD00134033

EC No.:

231-177-4

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Bismuth Granules
BI-M-02-GR
Pricing > SDS > Data Sheet >
(3N) 99.9% Bismuth Granules
BI-M-03-GR
Pricing > SDS > Data Sheet >
(4N) 99.99% Bismuth Granules
BI-M-04-GR
Pricing > SDS > Data Sheet >
(5N) 99.999% Bismuth Granules
BI-M-05-GR
Pricing > SDS > Data Sheet >
(6N) 99.9999% Bismuth Granules
BI-M-06-GR
Pricing > SDS > Data Sheet >

Bismuth Granules Properties (Theoretical)

Molecular Weight 208.98
Appearance solid
Melting Point 271.3 °C
Boiling Point 1560 °C
Density 9.747 g/cm3
Solubility in H2O N/A
Electrical Resistivity 106.8 microhm-cm @ 0 °C
Electronegativity 1.9 Paulings
Heat of Fusion 2.505 Cal/gm mole
Heat of Vaporization 42.7 K-Cal/gm atom at 1560 °C
Poisson's Ratio 0.33
Specific Heat 0.0296 Cal/g/K @ 25 °C
Tensile Strength N/A
Thermal Conductivity 0.0792 W/cm/ K @ 298.2 K
Thermal Expansion (25 °C) 13.4 µm·m-1·K-1
Vickers Hardness N/A
Young's Modulus 32 GPa

Bismuth Granules Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Precautionary Statements N/A
Risk Codes N/A
Safety Statements N/A
RTECS Number EB2600000
Transport Information NONH for all modes of transport
WGK Germany nwg

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/08/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Bismuth Granules

Product Number: All applicable American Elements product codes, e.g. BI-M-02-GR , BI-M-03-GR , BI-M-04-GR , BI-M-05-GR , BI-M-06-GR

CAS #: 7440-69-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Sol. 2 H228 Flammable solid.
Hazards not otherwise classified
No data available.
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Flame - GHS02

GHS02
Signal word
Warning
Hazard statements
H228 Flammable solid.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P240
Ground/bond container and receiving equipment.
P241
Use explosion-proof electrical/ventilating/lighting/equipment.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
WHMIS classification
B4 - Flammable solid
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 2
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment:
PBT:
N/A.
vPvB:
N/A.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
7440-69-9 Bismuth
Identification number(s):
EC number:
231-177-4


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No information available.
Indication of any immediate medical attention and special treatment needed
No information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing media
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and material for containment and cleanup:
Keep away from ignition sources.
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure adequate ventilation.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
Store away from halogens.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that should be monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Penetration time of glove material (in minutes)
No data available.
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: gray
Odor: Odorless
Odor threshold: No data available.
pH: N/A.
Melting point/range: 271.4 °C (521 °F)
Boiling point/range: 1564 °C (2847 °F)
Sublimation temperature / start: No data available.
Flash point: N/A
Flammability (solid, gas):
Highly flammable.
Ignition temperature: No data available.
Decomposition temperature: No data available.
Auto igniting: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure at 840 °C (1544 °F): 1 hPa (1 mm Hg)
Density at 20 °C (68 °F): 9.79 g/cm³ (81.698 lbs/gal)
Bulk density at 20 °C (68 °F): 6000 kg/m³
Relative density
No data available.
Vapor density
N/A.
Evaporation rate
N/A.
Solubility in Water (H2O): Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A.
Kinematic: N/A.
Other information
No information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No information available.
Incompatible materials:
Acids
Halogens
Oxidizing agents
Hazardous decomposition products:
Metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
Oral LD50 5000 mg/kg (rat)
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
N/A
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
N/A
Specific target organ system toxicity - repeated exposure:
N/A
Specific target organ system toxicity - single exposure:
N/A
Aspiration hazard:
N/A
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No information available.
Persistence and degradability:
No information available.
Bioaccumulative potential:
No information available.
Mobility in soil:
No information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without official permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT:
N/A.
vPvB:
N/A.
Other adverse effects
No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation:
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3089
UN proper shipping name
DOT
Metal powders, flammable, n.o.s. (Bismuth powder)
IMDG, IATA
METAL POWDER, FLAMMABLE, N.O.S. (Bismuth powder)
Transport hazard class(es)
DOT
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Class
4.1 (F3) Flammable solids, self-reactive substances and solid desensitised explosives
Label
4.1
IMDG, IATA
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
N/A.
Special precautions for user
Warning: Flammable solids, self-reactive substances and solid desensitised explosives
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3089, Metal powders, flammable, n.o.s. (Bismuth powder), 4.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS02
Signal word
Warning
Hazard statements
H228 Flammable solid.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P240
Ground/bond container and receiving equipment.
P241
Use explosion-proof electrical/ventilating/lighting/equipment.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Bismuth Granules

Ultra High Purity Granules American Elements specializes in producing high purity Bismuth Granules with the highest possible density and smallest possible average grain sizes for use in Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Our standard granules are amorphous uniform pieces in sizes ranging from < 1 mm, 1-2 mm, and 3-5 mm. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar, or plate form, as well as other machined shapes and through other processes such as nanoparticles and in the form of solutions and organometallics. We also produce Bismuth as rod, pellets, powder, pieces, disc, ingot, wire, and in compound forms, such as oxide. Other shapes are available by request.

Bismuth Granules Synonyms

95372, 44807

Chemical Identifiers

Linear Formula Bi
MDL Number MFCD00134033
EC No. 231-177-4
Beilstein/Reaxys No. N/A
Pubchem CID 5359367
SMILES [Bi]
InchI Identifier InChI=1S/Bi
InchI Key JCXGWMGPZLAOME-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

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