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Boron Nitride Film

Single and Multiple Layer h-BN Films

CAS #:

Linear Formula:

BN

MDL Number:

MFCD00011317

EC No.:

233-136-6

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Boron Nitride Film
BO-N-02-FLM
Pricing > SDS > Data Sheet >
(3N) 99.9% Boron Nitride Film
BO-N-03-FLM
Pricing > SDS > Data Sheet >
(4N) 99.99% Boron Nitride Film
BO-N-04-FLM
Pricing > SDS > Data Sheet >
(5N) 99.999% Boron Nitride Film
BO-N-05-FLM
Pricing > SDS > Data Sheet >

Boron Nitride Film Properties

Compound Formula

BN

Molecular Weight

24.82

Appearance

Crystalline

Density

1.9 to 2.1 g/cm3

Exact Mass

25.0124

Monoisotopic Mass

25.0124

Thermal Expansion

0.54 to 18 µm/m-K

Thermal Conductivity

29 to 96 W/m-K

Young's Modulus

14 to 60 GPa

Poisson's Ratio

0.11

Electrical Resistivity

13 to 15 10x Ω-m

Specific Heat

840 to 1610 J/kg-K

Boron Nitride Film Health & Safety Information

Signal Word Warning
Hazard Statements H319-H335
Hazard Codes Xi
Risk Codes 36/37
Safety Statements 26-36
RTECS Number ED7800000
Transport Information N/A
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/24/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Boron Nitride Film

Product Number: All applicable American Elements product codes, e.g. BO-N-02-FLM , BO-N-03-FLM , BO-N-04-FLM , BO-N-05-FLM

CAS #: 10043-11-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified as hazardous to health or the environment according to the CLP regulation.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
Not applicable
Hazard pictograms
Not applicable
Signal word
Not applicable
Hazard statements
Not applicable
WHMIS classification
Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY



Health (acute effects) = 0
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
10043-11-5 Boron nitride
Identification number(s):
EC number:
233-136-6


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
No special measures required.
After inhalation
Seek medical treatment in case of complaints.
After skin contact
Wash with water and soap and rinse thoroughly.
Generally the product does not irritate the skin.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing
Drink lots of water.
Induce vomiting if patient is conscious.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Nitrogen oxides (NOx)
Boron oxide
Advice for firefighters
Protective equipment:
No special measures required


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Particular danger of sli
pping on leaked/spilled product.
Not required.
Environmental precautions:
No special measures required.
Methods and material for containment and cleaning up:
Pick up mechanically.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
No dangerous substances are released.
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires:
The product is not flammable
No special measures required.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions
in well sealed containers.
Specific end use(s)
No further relevant information available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information:
The exposure limits that were valid when the MSDS was created were used.
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Not necessary if room is well-ventilated.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
Not required.
Recommended filter device for short term use:
Filter P1
Protection of hands:
Protective gloves.
Not required.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form:
Solid in various forms
Color:
White
Odor:
Odorless
Odor threshold:
Not determined.
pH-value:
Not applicable.
Change in condition
Melting point/Melting range:
None
Boiling point/Boiling range:
None
Sublimation temperature / start:
3000 °C (5432 °F)
Flash point:
Not applicable
Flammability (solid, gaseous)
Not determined.
Ignition temperature:
Not determined
Decomposition temperature:
Not determined
Auto igniting:
Not determined.
Danger of explosion:
Product does not present an explosion hazard.
Explosion limits:
Lower:
Not determined
Upper:
Not determined
Vapor pressure at 20 °C (68 °F):
0 hPa
Density at 20 °C (68 °F):
Not determined.
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with
Water:
Insoluble
Partition coefficient (n-octanol/water):
Not determined.
Viscosity:
dynamic:
Not applicable.
kinematic:
Not applicable.
Other information
No further relevant information available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and
stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Nitrogen oxides
Boron oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
No irritant effect.
Eye irritation or corrosion:
No irritant effect.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
EPA-I: Data are inadequate for an assessment of human carcinogenic potential.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
The substance is not subject to classification.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Not known to be hazardous to water.
Do not allow material to be released to the
environment without proper governmental permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Smaller quantities can be disposed of with household waste.
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. EXPOSURE CONTROLS/PERSONAL PROTECTION

UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
Item:
UN "Model Regulation"


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substancot listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.e of Very High Concern (SVHC) accord
ing to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Boron Nitride Film

Boron Nitride Films are composed of h-BN, a semiconducting insulator with a direct band gap of 5.97 eV. Hexagonal boron nitride has been shown to have similar properties to graphene with even higher chemical stability. American Elements produces single layer h-BN and multilayer h-BN films grown on copper via chemical vapor deposiiton (CVD) and are available on copper foil or SiO2/Si silicon oxide wafers. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available, as is additional research, technical and safety (MSDS) data. Please contact us for information on lead time and pricing above.

Boron Nitride Film Synonyms

h-BN; Elbor; hexagonal boron nitride; Boron mononitride; Nitridoborane; Nitriloborane; hBN; CVD hBN

Boron Nitride Film Chemical Identifiers

Linear Formula

BN

Pubchem CID

66227

MDL Number

MFCD00011317

EC No.

233-136-6

Beilstein Registry No.

N/A

IUPAC Name

azanylidyneborane

SMILES

B#N

InchI Identifier

InChI=1S/BN/c1-2

InchI Key

PZNSFCLAULLKQX-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808. It was first isolated by Humphry Davy, also in 1808. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Boron is found in borates, borax, boric acid, colemanite, kernite, and ulexite.The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. In its elemental form, nitrogen's CAS number is 7727-37-9. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Recent Research

Boron nitride nanowalls: low-temperature plasma-enhanced chemical vapor deposition synthesis and optical properties., Merenkov, Ivan S., Kosinova Marina L., and Maximovskii Eugene A. , Nanotechnology, 2017 May 05, Volume 28, Issue 18, p.185602, (2017)

Optical Signatures of Quantum Emitters in Suspended Hexagonal Boron Nitride., Exarhos, Annemarie L., Hopper David A., Grote Richard R., Alkauskas Audrius, and Bassett Lee C. , ACS Nano, 2017 Mar 28, Volume 11, Issue 3, p.3328-3336, (2017)

Thermal transport and anharmonic phonons in strained monolayer hexagonal boron nitride., Li, Shasha, and Chen Yue , Sci Rep, 2017 Mar 06, Volume 7, p.43956, (2017)

Thymine adsorption on two-dimensional boron nitride structures: first-principles studies., Castro-Medina, J, García-Toral D, López-Fuentes M, Sánchez-Castillo A, Torres-Morales S, L de la Garza Morales, and Cocoletzi Gregorio H. , J Mol Model, 2017 Apr, Volume 23, Issue 4, p.109, (2017)

Encapsulation of cisplatin as an anti-cancer drug into boron-nitride and carbon nanotubes: Molecular simulation and free energy calculation., Roosta, Sara, Hashemianzadeh Seyed Majid, and Ketabi Sepideh , Mater Sci Eng C Mater Biol Appl, 2016 Oct 1, Volume 67, p.98-103, (2016)

The structural and dynamical aspects of boron nitride nanotubes under high velocity impacts., Machado, Leonardo D., Ozden Sehmus, Tiwary ChandraSekhar, Autreto Pedro A. S., Vajtai Robert, Barrera Enrique V., Galvao Douglas S., and Ajayan Pulickel M. , Phys Chem Chem Phys, 2016 May 18, (2016)

A simple method for the enrichment of bisphenols using boron nitride., Fischnaller, Martin, Bakry Rania, and Bonn Günther K. , Food Chem, 2016 Mar 1, Volume 194, p.149-55, (2016)

Dielectric Engineering of a Boron Nitride/Hafnium Oxide Heterostructure for High-Performance 2D Field Effect Transistors., Zou, Xuming, Huang Chun-Wei, Wang Lifeng, Yin Long-Jing, Li Wenqing, Wang Jingli, Wu Bin, Liu Yunqi, Yao Qian, Jiang Changzhong, et al. , Adv Mater, 2016 Mar, Volume 28, Issue 10, p.2062-9, (2016)

Ultrasensitive electrochemical immunoassay for surface array protein, a Bacillus anthracis biomarker using Au-Pd nanocrystals loaded on boron-nitride nanosheets as catalytic labels., Sharma, Mukesh Kumar, Narayanan J, Pardasani Deepak, Srivastava Divesh N., Upadhyay Sanjay, and Goel Ajay Kumar , Biosens Bioelectron, 2016 Jun 15, Volume 80, p.442-9, (2016)

Boron nitride nanotube as a delivery system for platinum drugs: Drug encapsulation and diffusion coefficient prediction., Khatti, Zahra, and Hashemianzadeh Seyed Majid , Eur J Pharm Sci, 2016 Jun 10, Volume 88, p.291-7, (2016)

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June 23, 2017
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