SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin corrosion(Category 1B), H314
Serious eye damage(Category 1), H318
Carcinogenicity(Category 2), H351
Specific target organ toxicity -single exposure(Category 3), Respiratory system, Central nervous system, H335, H336
Specific target organ toxicity -repeated exposure, Oral(Category 2), Liver, Blood, H373
Specific target organ toxicity -repeated exposure, Inhalation(Category 2), Central nervous system,
H373
GHS Label elements, including precautionary statements
Pictogram

Signal word
Danger
Hazard statement(s)
H314
Causes severe skin b
urns and eye damage.
H335
May cause respiratory irritation.
H336
May cause drowsiness or dizziness.
H351
Suspected of causing cancer.
H373
May cause damage to organs (Liver, Blood) through prolonged or repeated exposure if swallowed.
H373
May cause damage to organs (Central nervous system) through prolonged or repeated exposure if inhaled.
Precautionary statement(s)
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264
Wash skin thoroughly after handling.
P271
Use only outdoors or in a well-ventilated area.
P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304 + P340 + P310
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P308 + P313
IF exposed or concerned: Get medical advice/ attention.
P363
Wash contaminated clothing before reuse.
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms:
Trichloroborane-methyl sulfide
Dimethyl sulfide-trichloroborane
Formula: C2H6BCl3S
Molecular weight: 179.30 g/mol

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person.
Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
No data available
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
Store under inert gas.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: liquid
Odour
No data available
Odour Threshold
No data available
pH
No data available
Melting point/freezing point
No data available
Initial boiling point and boiling range
No data available
Flash point
Not applicable
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Relative density
1.344 g/cm3 at 25 °C (77 °F)
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
No data available
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions.-
Carbon oxides, Sulphur oxides, Hydrogen chloride gas, Borane/boron oxides
Other decomposition products-No data available
In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
OSHA specifically regulated carcinogen(Methylene chloride)
Reproductive toxicity
No data available
No data available
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Skin contact or inhalation may result in:, spasm, inflammation and edema of the larynx, Aspiration or inhalation may cause chemical pneumonitis., pulmonary edema, Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence(Methylene chloride)

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 3265
Class: 8
Packing group: II
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.(Boron trichloride methyl sulfide complex)
Reportable Quantity
(RQ): 1372 lbs
Poison Inhalation Hazard: No
IMDG
UN number: 3265
Class: 8
Packing group: II
EMS-No:
F-A, S-B
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(Boron trichloride methyl sulfide complex)
IATA
UN number: 3265
Class: 8
Packing group: II
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.(Boron trichloride methyl sulfide complex)

SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, S
ection 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Methylene chloride
CAS-No.
75-09-2
Revision Date
2007-07-01
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Methylene chloride
CAS-No.
75-09-2
Revision Date
2007-07-01
Pennsylvania Right To Know Components
Methylene chloride
CAS-No.
75-09-2
Revision Date
2007-07-01
Boron trichloride methyl sulfide complex
5523-19-3
New Jersey Right To Know Components
Methylene chloride
CAS-No.
75-09-2
Revision Date
2007-07-01
Boron trichloride methyl sulfide complex
5523-19-3
California Prop. 65 Components
WARNING! This product contains a chemical known to the State of California to cause cancer.
Methylene chloride
CAS-No.
75-09-2
Revision Date
2007-09-28