SECTION 2. HAZARDS IDENTIFICATION

Statement of Hazard:
Irritant, Respiratory irritant, Toxic
Acute Health Hazard:
Irritant to eyes, skin, mucous membranes and respiratory system.
May be fatal by ingestion, skin absorption and inhalation.
Chronic Health Hazard: Not Available
To the best of our knowledge, the toxicological properties of this chemical have not been
thoroughly investigated. Use appropriate procedures and precautions to prevent or minimize
exposure.
HMIS Rating:
H: 4
F: 0
P: 0
NFPA Rating:
H: 4
F: 0
R: 0
Pictogram:

Signal Word:
Danger
Hazard Statement(s):
H300 Fatal if swallowed.
H310 Fatal in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
Precautionary Statement(s):
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name: Calcium fluorosilicate dihydrate
CAS Number: 16925-39-6
EINECS Number: 240-991-9

SECTION 4. FIRST AID MEASURES

Eye Contact:
Flush eyes with large amounts of water for fifteen minutes. Separate
eyelids with fingers. If irritation persists, seek medical attention.
Skin Contact:
Wash skin with soap and water. If irritation persists, seek medical
attention.
Ingestion:
Do not induce vomiting. Seek medical attention.
Inhalation:
Move to a fresh air environment. Contact a physician if breathing
becomes difficult.

SECTION 5. FIREFIGHTING MEASURES

Flash Point (ºC):
Not Available
Explosion Limits:
Not Available
Autoignition (ºC):
Not Available
Extinguishing Media:
Carbon dioxide, dry chemical powder, alcohol-resistant foam, or water spray
Protective Equipment:
Wear self-contained respirator and fully protective impervious suit.
Specific Hazards:
May emit hazardous fumes under fire conditions.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Protection:
Wear a self-contained breathing apparatus, rubber boots and gloves, and disposable coveralls. Dispose of coveralls after use. Remove from ignition sources if safe to do so. Follow emergency response plan and contact proper authorities if needed.
Keep unprotected persons away.
Environmental Protection:
Keep spills out of sewers and bodies of water. Dike and contain the spill with inert material. Absorb on sand, vermiculite or diatomite. Transfer material to a container for disposal or recovery. Ventilate area and wash spill site after material pickup is complete.

SECTION 7. HANDLING AND STORAGE

Handling and Storage:
Avoid breathing dust, vapor, mist or gas. Avoid contact with skin and eyes. Avoid prolonged or repeated exposure. Use only in a chemical fume hood. Open and handle container with care. Keep ignition sources away.
Store in a tightly closed container in a dry, well-ventilated place.
Sensitivities:
Not Available
Storage Temperature (ºC):
15 to 30

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls:
Use product in a well ventilated area or under a fume hood. Use proper lab equipment while handling this product. Keep away from incompatible materials for possible risk of hazardous reaction.
Eye Protection:
Wear appropriate protective eyeglass or chemical safety goggles. Make sure that there is an eyewash station in your vicinity.
Skin Protection:
Wear impervious gloves and protective clothing.
Respiratory Protection:
Use a NIOSH approved respirator when exposure limits are exceeded or if irritation or other symptoms are experienced.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: White crystals or powder
Odor: Odorless
Odor Threshold: Not Available
Flash Point (ºC): Not Available
Autoignition (ºC): Not Available
UEL % by Volume: Not Available
LEL % by Volume: Not Available
Melting Point (ºC): Not Available
Boiling Point (ºC): Not Available
Evaporation Rate: Not Available
pH Value: Not Available
Density (g/cm³): 2.622
Refractive Index (n²ºD): Not Available
Viscosity: Not Available
Solubility in Water: Not Available
Solubility in Other: Not Available
Vapor Pressure (mmHg): Not Available
Vapor Density (Air=1): Not Available

SECTION 10. STABILITY AND REACTIVITY

Stability:
Stable under normal temperatures and pressures.
Incompatibility:
Not Available
Reactivity:
Product may react with incompatible materials to release other hazardous substances.
Conditions to Avoid:
Heat, flame, sparks, other ignition sources.
Hazardous Decomposition Products:
Calcium oxides, Hydrogen fluoride gas, Silicon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

RTECS Reference: EW4025000
Target Organs: Not Available
Toxicity Data: Not Available
National Toxicology Program (NTP) listed: Not Available
Carcinogenicity: International Agency for Research on Cancer (IARC) listed: Not Available
Potential Symptoms: Not Available

SECTION 12. ECOLOGICAL INFORMATION

Toxicity: Not Available

SECTION 13. DISPOSAL CONSIDERATIONS

Contact a licensed professional waste disposal service. Dispose in a manner consistent with
federal, state and local environmental regulations.

SECTION 14. TRANSPORT INFORMATION

DOT Shipping Name: Fluorosilicates, N.O.S.
DOT UN Number: UN2856
DOT Hazard Class: Class 6.1
DOT Packing Group: PGIII

IMDG Shipping Name: Fluorosilicates, N.O.S.
IMDG UN Number: UN2856
IMDG Hazard Class: Class 6.1
IMDG Packing Group: PGIII

IATA Shipping Name: Fluorosilicates, N.O.S.
IATA UN Number: UN2856
IATA Hazard Class: Class 6.1
IATA Packing Group: PGIII

SECTION 15. REGULATORY INFORMATION

United Sates
Toxic Substance Control Act (TSCA) listed:
Yes
Superfund Amendments and Reauthorization Act (SARA 302) listed:
No
Superfund Amendments and Reauthorization Act (SARA 311/312) listed:
No
Superfund Amendments and Reauthorization Act (SARA 313) listed:
No
European Union
European Inventory of Existing Chemical Substances (EINECS): 240-991-9
Canada
Canadian Domestic Substances List (DSL) listed: No
Canadian Non-Domestic Substances List (NDSL) listed: Yes