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Calcium Vanadate

CAS #:

Linear Formula:

Ca(VO3)2

MDL Number:

MFCD00049401

EC No.:

237-952-3

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Calcium Vanadate
CA-VO-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Calcium Vanadate
CA-VO-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Calcium Vanadate
CA-VO-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Calcium Vanadate
CA-VO-05
Pricing > SDS > Data Sheet >

Calcium Vanadate Properties (Theoretical)

Compound Formula CaV2O6
Molecular Weight 236.16
Appearance Yellowish-green powder
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 237.82 g/mol
Monoisotopic Mass 237.820007
Charge N/A

Calcium Vanadate Health & Safety Information

Signal Word Danger
Hazard Statements H302-H331-H351-H361-H335-H372
Hazard Codes T, Xn
Precautionary Statements P260-P261-P281-P304+P340-P405-P501
Risk Codes N/A
Safety Statements N/A
Transport Information UN 3285 6.1 / PGIII
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/16/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Calcium Vanadate

Product Number: All applicable American Elements product codes, e.g. CA-VO-02 02 , CA-VO-03 03 , CA-VO-04 04 , CA-VO-05 05

CAS #: 12135-52-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS06 Skull and crossbones
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 Health hazard
Carc. 2
H351 Suspected of causing cancer.
Repr. 2
H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
STOT SE 3 H335 May cause respiratory irritation.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms

Skull and Crossbones - GHS06 Health Hazard - GHS08

GHS06 GHS08
Signal word: Danger
Hazard statements
H302 Harmful if swallowed.
H331 Toxic if inhaled.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P281
Use personal protective equipment as required.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
14100-64-2 / 12135-52-3/ Calcium vanadium oxide


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Toxic metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Do not store with interhalogens.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Yellowish green
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flash point: N/A
Flammability (solid, gas): No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density: No data available
Relative density: No data available.
Vapor density: N/A
Evaporation rate: N/A
Solubility in Water (H2O): No data available
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
Toxic metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Irritant to skin and mucous membranes.
Eye irritation or corrosion: Irritating effect.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: Suspected of causing cancer.
Reproductive toxicity:
Suspected of damaging fertility or the unborn child.
Specific target organ system toxicity - repeated exposure:
Causes damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
Inhalation of magnesium compounds may cause metal fume fever.
Metallic magnesium which perforates the skin may cause local lesions. Some magnesium salts have produced muscle weakness, cardiac arrhythmias, respiratory effects and changes in blood chemistry following ingestion.
Subacute to chronic toxicity: No effects known.
Subacute to chronic toxicity:
Vanadium pentoxide is poisonous by ingestion and inhalation as well as other routes. Ingestion causes disturbances of the gastrointestinal tract. May also cause apapular skin rash. VanadiuInformation on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Irritant to skin and mucous membranes.
Eye irritation or corrosion: Irritating effect.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: Suspected of causing cancer.
Reproductive toxicity:
Suspected of damaging fertility or the unborn child.
Specific target organ system toxicity - repeated exposure:
Causes damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
Subacute to chronic toxicity: No effects known.
Subacute to chronic toxicity:
Vanadium pentoxide is poisonous by ingestion and inhalation as well as other routes. Ingestion causes disturbances of the gast rointestinal tract. May also cause apapular skin rash. Vanadium pentoxide is a respiratory irritant. Effects include
skin pallor, greenish-black tongue, chest pain, cough, dsypnea, palpitation and lung changes. Causes reproductive and mutagenic effects in laboratory animals.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.pentoxide is a respiratory irritant. Effects include skin pallor, greenish-black tongue, chest pain, cough, dsypnea, palpitation and lung changes. Causes reproductive and mutagenic effects in laboratory animals.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ecotoxical effects:
Remark:
Toxic for aquatic organisms
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Toxic for aquatic organisms
Do not allow product to reach groundwater, water courses, or sewage systems, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3285
UN proper shipping name
DOT
Vanadium compound, n.o.s. (Calcium vanadium oxide)
IMDG, IATA
VANADIUM COMPOUND, N.O.S. (Calcium vanadium oxide)
Transport hazard class(es)
DOT
Class
6.1 Toxic substances.
Label
6.1
Class
6.1 (T5) Toxic substances
Label
6.1
IMDG, IATA
Class
6.1 Toxic substances.
Label
6.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
Environmentally hazardous substance, solid
Special precautions for user
Warning: Toxic substances
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3285, Vanadium compound, n.o.s. (Calcium vanadium oxide), 6.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS GHS label elements, including precautionary statements
Hazard pictograms
GHS06
GHS08
Signal word: Danger
Hazard statements
H302 Harmful if swallowed.
H331 Toxic if inhaled.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P281
Use personal protective equipment as required.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
SARA Section 313 (specific toxic chemical listings)
14100-64-2 Calcium vanadium oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on themarket and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Calcium Vanadate

Calcium Vanadate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, researchand safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Calcium Vanadate Synonyms

Calcium vanadium oxide; Calcium divanadium hexaoxide; Vanadate (VO31-), calcium (2:1); Calcium bis[trioxovanadate(1-)]; 14100-64-2; 52014-63-8; Calcium vanadate(ortho); Calcium vanadate, meta; calcium metavanadate; calcium orthovanadate - Ca3(VO4)2; CaO6V2

Chemical Identifiers

Linear Formula Ca(VO3)2
MDL Number MFCD00049401
EC No. 237-952-3
Beilstein Registry No. N/A
Pubchem CID 18780327
IUPAC Name calcium; oxido(dioxo)vanadium
SMILES [O-][V](=O)=O.[O-][V](=O)=O.[Ca+2]
InchI Identifier InChI=1S/Ca.6O.2V/q+2;;;;;2*-1;;
InchI Key DNWNZRZGKVWORZ-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Calcium products. Calcium (atomic symbol: Ca, atomic number: 20) is a Block S, Group 2, Period 4 element with an atomic weight of 40.078. The number of electrons in each of Calcium's shells is [2, 8, 8, 2] and its electron configuration is [Ar] 4s2. Calcium Bohr ModelThe calcium atom has a radius of 197 pm and a Van der Waals radius of 231 pm. Calcium was discovered and first isolated by Sir Humphrey Davy in 1808. It is the fifth most abundant element in the earth's crust and can be found in minerals such as dolomite, gypsum, plagioclases, amphiboles, pyroxenes and garnets. In its elemental form, calcium has a dull gray-silver appearance. Calcium is a reactive, soft metal that is a member of the alkaline earth elements. Elemental CalciumIt frequently serves as an alloying agent for other metals like aluminum and beryllium industrial materials like cement and mortar are composed of calcium compounds like calcium carbonate. It is also an biologically essential substance found in teeth, bones, and shells. The name "calcium" originates from the Latin word "calics," meaning lime.

See more Vanadium products. Vanadium (atomic symbol: V, atomic number: 23) is a Block D, Group 5, Period 4 element with an atomic weight of 50.9415. Vanadium Bohr ModelThe number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electron configuration is [Ar] 3d3 4s2. The vanadium atom has a radius of 134 pm and a Van der Waals radius of 179 pm. Vanadium was discovered by Andres Manuel del Rio in 1801 and first isolated by Nils Gabriel Sefström in 1830. In its elemental form, vanadium has a bluish-silver appearance. Elemental VanadiumIt is a hard, ductile transition metal that is primarily used as a steel additive and in alloys such as Titanium-6AL-4V, which is composed of titanium, aluminum, and vanadium and is the most common titanium alloy commercially produced. Vanadium is found in fossil fuel deposits and 65 different minerals. Vanadium is not found free in naturehowever, once isolated it forms an oxide layer that stabilizes the free metal against further oxidation. Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology.

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October 16, 2019
Los Angeles, CA
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