CAS No. 10099-58-8

Chemical Identifiers

Linear Formula LaCl3
Pubchem CID 165791
MDL Number MFCD00011068
EC No. 233-237-5
IUPAC Name trichlorolanthanum
SMILES Cl[La](Cl)Cl
InchI Identifier InChI=1S/3ClH .La/h3*1H;/ q;;;+3/p-3
InchI Key ICAKDTKJOYSXGC-UHFFFAOYSA-K

Health & Safety Information

Signal Word Danger
Hazard Statements H290-H318-H317
Hazard Codes Xi
Precautionary Statements P261-P280-P234-P305+P351+P338-P310-P363-P321-P333+P313-P406-P501
Flash Point Not applicable
Risk Codes 36/37/38
Safety Statements 26-36
RTECS Number OE4375000
Transport Information UN3077 Class 9, PG III
WGK Germany 2
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised: 01/15/2022

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #10099-58-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Met. Corr.1 H290 May be corrosive to metals.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Hazards not otherwise classified No data available
GHS label elements, including precautionary statements

Corrosion - GHS05
Exclamation Mark - GHS07

Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard statements
H290 May be corrosive to metals.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2

1
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
10099-58-8 Lanthanum(III) chloride, anhydrous
Identification number(s):
EC number: 233-237-5


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Hydrogen chloride (HCl)
Lanthanum oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow product to enter drains, sewage systems, or other water courses.
Methods and materials for containment and cleanup: Pick up mechanically.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Store away from water/moisture.
Do not store together with acids.
Store away from oxidizing agents.
Store away from metals.
Further information about storage conditions:
Store under dry inert gas.
This product is hygroscopic.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and water.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
None.
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if airpurifying
respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves Nitrile rubber, NBR
Penetration time of glove material (in minutes) 480
Glove thickness 0.11 mm
Eye protection: Tightly sealed goggles
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Various forms (powder/flake/crystalline/beads, etc.)
Color: White
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 860 °C (1580 °F)
Boiling point/Boiling range: 1000 °C (1832 °F)
Sublimation temperature / start: No data available
Flammability (solid, gas) No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 3.842 g/cm3 (32.061 lbs/gal)
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water at 20 °C (68 °F): 861.06 g/l
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts with strong oxidizing agents
Conditions to avoid No data available
Incompatible materials:
Acids
Water/moisture
Oxidizing agents
Metals
Hazardous decomposition products:
Hydrogen chloride (HCl)
Lanthanum oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts with strong oxidizing agents
Conditions to avoid No data available
Incompatible materials:
Acids
Water/moisture
Oxidizing agents
Metals
Hazardous decomposition products:
Hydrogen chloride (HCl)
Lanthanum oxide


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information:
Do not allow product to reach groundwater, water courses, or sewage systems.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN3077
UN proper shipping name
DOT Environmentally hazardous substances, solid, n.o.s. (Lanthanum(III) chloride,
anhydrous)
IMDG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Lanthanum(III) chloride, anhydrous)
Transport hazard class(es)
DOT, IMDG
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Class 9 (M7) Miscellaneous dangerous substances and articles
Label 9
IATA
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Special marking (ADR): Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
EMS Number: F-A,S-F
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3077, Environmentally hazardous substances, solid, n.o.s. (Lanthanum(III)
chloride, anhydrous), 9, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements, including precautionary statements
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard statements
H290 May be corrosive to metals.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings) Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • Determination of activity coefficient of lanthanum chloride in molten LiCl-KCl eutectic salt as a function of cesium chloride and lanthanum chloride concentrations using electromotive force measurements. Prashant Bagri, Michael F. Simpson. Journal of Nuclear Materials, Volume 482, 15 December 2016, Pages 248-256.
  • Evolution of the corrosion process of AA 2024-T3 in an alkaline NaCl solution with sodium dodecylbenzenesulfonate and lanthanum chloride inhibitors. Biner Zhou, Yishan Wang, Yu Zuo. Applied Surface Science, Volume 357, Part A, 1 December 2015, Pages 735-744.
  • Friction and wear performances of borates and lanthanum chloride in water. Boshui Chen, Jianhua Fang, Jiu Wang, Jia LI, Fang Lou. Journal of Rare Earths, Volume 26, Issue 4, August 2008, Pages 590-593.
  • Growth, thermo-stability and radiation damage of cerium-doped lanthanum chloride (LaCl3:Ce) scintillation crystal. Guohao Ren, Yu Pei, Xiaofeng Chen, Dongmin Yao, Zhongbo Li. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Volume 579, Issue 1, 21 August 2007, Pages 11-14.
  • Identification of prompt fission γ-rays with lanthanum-chloride scintillation detectors. A. Oberstedt, S. Oberstedt, R. Billnert, W. Geerts, J. Karlsson. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Volume 668, 11 March 2012, Pages 14-20.
  • Inhibition of thioredoxin reductase by lanthanum chloride. Anna Citta, Alessandra Folda, Guido Scutari, Luca Cesaro, Maria Pia Rigobello. Journal of Inorganic Biochemistry, Volume 117, December 2012, Pages 18-24.
  • Lanthanum trichloride: An efficient catalyst for the silylation of hydroxyl groups by activating hexamethyldisilazane (HMDS). Akkirala Venkat Narsaiah. Journal of Organometallic Chemistry, Volume 692, Issue 17, 1 August 2007, Pages 3614-3618.
  • Lanthanum(III) chloride/chloroacetic acid as an efficient and reusable catalytic system for the synthesis of new 1-((2-hydroxynaphthalen-1-yl)(phenyl)methyl)semicarbazides/thiosemicarbazides. Behjat Pouramiri, Esmat Tavakolinejad Kermani. Arabian Journal of Chemistry, Volume 10, Supplement 1, February 2017, Pages s730-s734.
  • Mesoporous carbons modified with lanthanum(III) chloride for methyl orange adsorption. Joanna Goscianska, Michał Marciniak, Robert Pietrzak. Chemical Engineering Journal, Volume 247, 1 July 2014, Pages 258-264.
  • Thermal stability of polybenzoxazines with lanthanum chloride and their crosslinked structures. Qi-Chao Ran, Nian Gao, Yi Gu. Polymer Degradation and Stability, Volume 96, Issue 9, September 2011, Pages 1610-1615.