CAS No. 12045-63-5

Chemical Identifiers

Linear Formula TiB2
Pubchem CID N/A
MDL Number MFCD00049595
EC No. 234-961-4
IUPAC Name diboranylidynetitanium
Beilstein Registry No. N/A
SMILES B#[Ti]#B
InchI Identifier InChI=1S/2B.Ti
InchI Key QYEXBYZXHDUPRC-UHFFFAOYSA-N

Health & Safety Information

Signal Word Warning
Hazard Statements H302-H312-H332
Hazard Codes Xn
Risk Codes 20/21/22
Safety Statements 36
RTECS Number N/A
Transport Information N/A
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 09/23/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #12045-63-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified as hazardous to health or the environment according to the CLP regulation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
N/A
Information concerning particular hazards for human and environment:
No data available
Hazards not otherwise classified
No data available
Label elements
Labelling according to Regulation (EC) No 1272/2008
N/A
Hazard pictograms
N/A
Signal word
N/A
Hazard statements
N/A
WHMIS classification
Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1

1
Health (acute effects) = 1
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
12045-63-5 Titanium boride
Identification number(s):
EC number:
234-961-4


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Metal oxide fume
Boron oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Do not allow product to enter drains, sewage systems, or other water courses.
Do not allow material to penetrate the ground or soil.
Methods and materials for containment and cleanup:
Pick up mechanically.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
None.
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Penetration time of glove material (in minutes)
No data available
Eye protection:
Safety glasses
Body protection:
Protective work clothing


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder or solid in various forms
Color: Grey
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 3225 °C (5837 °F)
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flammability (solid, gas)
No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 4.38 g/cm3 (36.551 lbs/gal)
Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in Water (H2O): Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No data available
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Metal oxide fume
Boron oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
EPA-I: Data are inadequate for an assessment of human carcinogenic potential.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA
N/A
UN proper shipping name
DOT, ADN, IMDG, IATA
N/A
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
N/A
Packing group
DOT, IMDG, IATA
N/A
Environmental hazards: N/A
Special precautions for user
N/A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information: DOT
Marine Pollutant (DOT): No


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • A new approach for fabrication of titanium-titanium boride periodic composite via additive manufacturing and pressure-less sintering. Esmat Sheydaeian, Ehsan Toyserkani. Composites Part B: Engineering, Volume 138, 1 April 2018, Pages 140-148.
  • Analysis of pressureless sintering of titanium diboride ceramics with nickel, cobalt, and tungsten carbide additives. Rainer Telle. Journal of the European Ceramic Society, Volume 39, Issue 7, July 2019, Pages 2266-2276.
  • Corrosion behavior of titanium boride composite coating fabricated on commercially pure titanium in Ringer's solution for bioimplant applications. Bose Sivakumar, Raghuvir Singh, Lokesh Chandra Pathak. Materials Science and Engineering: C, Volume 48, 1 March 2015, Pages 243-255.
  • Densification and grain growth during microwave sintering of titanium diboride. D. Demirskyi, J. Cheng, D. Agrawal, A. Ragulya. Scripta Materialia, Volume 69, Issue 8, October 2013, Pages 610-613.
  • Finite strain analysis of shock compression of brittle solids applied to titanium diboride. J. D. Clayton. International Journal of Impact Engineering, Volume 73, November 2014, Pages 56-65.
  • Formation mechanism of titanium boride nanoparticles by RF induction thermal plasma. Yingying Cheng, Masaya Shigeta, Sooseok Choi, Takayuki Watanabe. Chemical Engineering Journal, Volume 183, 15 February 2012, Pages 483-491.
  • Graphene nanoplatelets induce crystallographic texturing during reactive spark plasma sintering of titanium diboride. N. S. Karthiselva, B. S. Murty, Srinivasa R. Bakshi. Carbon, Volume 133, July 2018, Pages 323-334.
  • Ignition and chemical mechanisms of volume combustion synthesis of titanium diboride. H. Zarrinpour, S. Firoozi, V. Milani. Ceramics International, Volume 42, Issue 9, July 2016, Pages 11217-11223.
  • Growth kinetics of titanium borides produced by CRTD-Bor method. G. Kartal, S. Timur. Surface and Coatings Technology, Volume 215, 25 January 2013, Pages 440-446.
  • Low temperature synthesis of Titanium diboride by carbothermal method. V. Moradi, L. Nikzad, I. Mobasherpour, M. Razavi. Ceramics International, Volume 44, Issue 16, November 2018, Pages 19421-19426.
  • Tough ceramics by microwave sintering of nanocrystalline titanium diboride ceramics. D. Demirskyi, D. Agrawal, A. Ragulya. Ceramics International, Volume 40, Issue 1, Part B, January 2014, Pages 1303-1310.
  • Titanium diboride ceramics for solar thermal absorbers. Elisa Sani, Marco Meucci, Luca Mercatelli, Andrea Balbo, Giacomo Cao. Solar Energy Materials and Solar Cells, Volume 169, September 2017, Pages 313-319.
  • Synthesis of fine dispersed titanium diboride from nanofibrous carbon. Yu. L. Krutskii, A. G. Bannov, E. V. Antonova, V. V. Sokolov, I. A. Bataev. Ceramics International, Volume 43, Issue 3, 15 February 2017, Pages 3212-3217.
  • Surface characterization and diffusion model of pack borided TB2 titanium alloy. Ping Li, Dan Liu, Weizong Bao, Lishi Ma, Yonghua Duan. Ceramics International, Volume 44, Issue 15, 15 October 2018, Pages 18429-18437.