CAS No. 12654-86-3

Chemical Identifiers

Linear Formula Ti2CN
Pubchem CID 88400291
MDL Number MFCD01868685
EC No. N/A
IUPAC Name titanium; cyanide
SMILES [C-]#N.[Ti].[T
InchI Identifier InChI=1S/CN.2Ti/c1-2;;/q-1;;
InchI Key KNGFPHLGNCUHTB-UHFFFAOYSA-N

Health & Safety Information

Signal Word Warning
Hazard Statements H228
Hazard Codes F
Precautionary Statements P210-P280-P240-P241-P370+P378
Risk Codes N/A
Safety Statements N/A
Transport Information UN3178 4.1/PG III
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/27/2020
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #12654-86-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Sol. 2 H228 Flammable solid.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms

Flame - GHS02

GHS02
Signal word: Warning
Hazard statements
H228 Flammable solid.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P370+P378 In case of fire: Use for extinction: CO2, sand, extinguishing powder.
WHMIS classification
B4 - Flammable solid
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 2
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
12654-86-3 Titanium carbonitride


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water.
Use carbon dioxide, extinguishing powder or foam. Water may be ineffective but may be used for cooling exposed containers.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Tantalum oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow product to enter drains, sewage systems, or other water courses.
Methods and materials for containment and cleanup:
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
None.
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands: Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.11 mm
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Dark grey
Odor: No data available
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flammability (solid, gas): Highly flammable.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): No data available
Relative density: No data available.
Vapor density: N/A
Evaporation rate: N/A
Solubility in Water (H2O): No data available
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No data available
Incompatible materials:
Acids
Oxidizing agents
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Tantalum oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3178
UN proper shipping name
DOT
Flammable solid, inorganic, n.o.s. (Titanium carbonitride)
IMDG, IATA
FLAMMABLE SOLID, INORGANIC, N.O.S. (Titanium carbonitride)
Transport hazard class(es)
DOT
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Class
4.1 (F3) Flammable solids, self-reactive substances and solid desensitised explosives
Label
4.1
IMDG, IATA
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
N/A
Special precautions for user
Warning: Flammable solids, self-reactive substances and solid desensitised explosives
EMS Number:
F-A,S-G
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3178, Flammable solid, inorganic, n.o.s. (Titanium carbonitride), 4.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS GHS label elements, including precautionary statements
Hazard pictograms
GHS02
Signal word: Warning
Hazard statements
H228 Flammable solid.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P370+P378 In case of fire: Use for extinction: CO2, sand, extinguishing powder.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • Enhanced toughness of titanium carbonitride-based cermets by addition of (Ti,W)C carbides. Choongkwon Park, Sangwoo Nam, Shinhoo Kang. Materials Science and Engineering: A, Volume 649, 1 January 2016, Pages 400-406.
  • Spark-plasma-sintering (SPS) of nanostructured titanium carbonitride powders. Angerer P, Yu LG, Khor KA, Korb G, Zalite I. Journal of the European Ceramic Society. 2005 Jul 1;25(11):1919-27.
  • Properties of titanium carbonitride matrix cermets. Zhang H, Yan J, Zhang X, Tang S. International Journal of Refractory Metals and Hard Materials. 2006 May 1;24(3):236-9.
  • Direct formation of titanium carbonitrides by SHS in nitrogen. Yeh CL, Chen YD. Ceramics international. 2005 Jan 1;31(5):719-29.
  • Synthesis of titanium (IV) guanidinate complexes and the formation of titanium carbonitride via low-pressure chemical vapor deposition. Carmalt CJ, Newport AC, O'Neill SA, Parkin IP, White AJ, Williams DJ. Inorganic chemistry. 2005 Feb 7;44(3):615-9.
  • Synthesis of titanium carbonitride phases by reactive milling of the elemental mixed powders. Córdoba JM, Sayagués MJ, Alcalá MD, Gotor FJ. Journal of the American Ceramic Society. 2005 Jul;88(7):1760-4.
  • Cutting performance of titanium carbonitride cermet tools. Zhang H, Tang S, Yan J, Hu X. International Journal of Refractory Metals and Hard Materials. 2007 Sep 1;25(5-6):440-4.
  • Environmental friendly scalable production of colloidal 2D titanium carbonitride MXene with minimized nanosheets restacking for excellent cycle life lithium-ion batteries. Du F, Tang H, Pan L, Zhang T, Lu H, Xiong J, Yang J, Zhang CJ. Electrochimica Acta. 2017 May 1;235:690-9.
  • High surface area carbon nanotube-supported titanium carbonitride aerogels. Worsley MA, Kuntz JD, Pauzauskie PJ, Cervantes O, Zaug JM, Gash AE, Satcher JH, Baumann TF. Journal of Materials Chemistry. 2009 Jul 28;19(31):5503-6.
  • Synthesis and electromagnetic absorbing properties of titanium carbonitride with quantificational carbon doping. Hong X, Wang Q, Tang Z, Khan WQ, Zhou D, Feng T. The Journal of Physical Chemistry C. 2015 Dec 24;120(1):148-56.
  • Microstructural study of titanium carbonitride produced by combustion synthesis. Carole D, Frety N, Paris S, Vrel D, Bernard F, Marin-Ayral RM. Ceramics International. 2007 Dec 1;33(8):1525-34.
  • Partially oxidized titanium carbonitride as a non-noble catalyst for oxygen reduction reactions. Dam DT, Nam KD, Song H, Wang X, Lee JM. International Journal of Hydrogen Energy. 2012 Oct 1;37(20):15135-9.