CAS No. 130469-99-7

Health & Safety Information

Signal Word Danger
Hazard Statements H260-H317-H330-H334-H341-H350-H360-H372-H411
Hazard Codes F, T, N
Precautionary Statements P201 - P231 + P232 - P273 - P280 - P302 + P352 - P304 + P340 + P310
Risk Codes 14/15-40-42/43-48/23-52/53
Safety Statements 22-36/37-43-45-61
RTECS Number N/A
Transport Information N/A
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 05/22/2022
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #130469-99-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Chemicals which, in contact with water, emit flammable gases (Category 1), H260
Acute toxicity, Inhalation (Category 2), H330
Respiratory sensitization (Category 1), H334
Skin sensitization (Category 1), H317
Germ cell mutagenicity (Category 2), H341
Carcinogenicity (Category 1B), H350
Reproductive toxicity (Category 1B), H360
Specific target organ toxicity - repeated exposure, Inhalation (Category 1), H372
Short-term (acute) aquatic hazard (Category 2), H401
Long-term (chronic) aquatic hazard (Category 2), H411
Pictogram

Flame - GHS02 Skull and Crossbones - GHS06 Health Hazard - GHS08 Environment - GHS09

Signal word Danger
Hazard statement(s)
H260 In contact with water releases flammable gases which may
ignite spontaneously.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated
exposure if inhaled.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and
understood.
P223 Do not allow contact with water.
P231 + P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the
workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P284 Wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap
in wet bandages.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant
foam to extinguish.
P391 Collect spillage.
P402 + P404 Store in a dry place. Store in a closed container.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal
plant.
Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms : La2Co1Ni9


SECTION 4. FIRST AID MEASURES

Description of first-aid measures
General advice
First aiders need to protect themselves. Show this material safety data sheet to the doctor
in attendance.
If inhaled
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately
apply artificial respiration, if necessary also oxygen.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower. Consult a physician.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media
Water Foam
Special hazards arising from the substance or mixture
Nickel/nickel oxides
Cobalt/cobalt oxides
Lanthanum oxides
Not combustible.
May not get in touch with: Water
Ambient fire may liberate hazardous vapours.
Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire
extinguishing water from contaminating surface water or the ground water system.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all
circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the
danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains. Risk of explosion.
Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area.
Avoid generation of dusts.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling
Work under hood. Do not inhale substance/mixture. Keep workplace dry. Do not allow
product to come into contact with water.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands
and face after working with substance.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Keep away from heat and sources of ignition. Keep locked up or in an area
accessible only to qualified or authorized persons.
Never allow product to get in contact with water during storage.
Air and moisture sensitive.
Storage class (TRGS 510): 4.3: Hazardous materials, which set free flammable gases upon
contact with water
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash
hands and face after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
Handle with impervious gloves.
Body Protection
protective clothing
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains. Risk of explosion.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
a) Appearance Form: pieces
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting
point/freezing point
Melting point/range: 1,300 °C (2,372 °F)
f) Initial boiling point and boiling range
No data available
g) Flash point ()No data available
h) Evaporation rate No data available
i) Flammability (solid,
gas)
The product is not flammable.
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Relative density No data available
n) Water solubility No data available
o) Partition coefficient: n-octanol/water
No data available
p) Autoignition temperature
140 °C (284 °F)
Not applicable
q) Decomposition temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
No data available
Conditions to avoid
Moisture.
Incompatible materials
Oxidizing agents, Strong oxidizing agents, Strong acids, Sulfur compounds, acids,
Acetylene, Material readily reacts with acids generating flammable and/or explosive
hydrogen gas., Halogens, Phosphorus, Mineral acids, Hydrazinium nitrate
Hazardous decomposition products
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Mixture
Acute toxicity
Acute toxicity estimate Oral - > 5,000 mg/kg
(Calculation method)
Acute toxicity estimate Inhalation - 4 h - 0.075 mg/l
(Calculation method)
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
Mixture may cause allergy or asthma symptoms or breathing difficulties if inhaled. Mixture
may cause an allergic skin reaction.
Germ cell mutagenicity
Evidence of genetic defects.
Carcinogenicity
Possible carcinogen.
IARC: 2B - Group 2B: Possibly carcinogenic to humans (Nickel)
1 - Group 1: Carcinogenic to humans (Nickel)
2B - Group 2B: Possibly carcinogenic to humans (Nickel)
IARC: 2B - Group 2B: Possibly carcinogenic to humans (cobalt)
2A - Group 2A: Probably carcinogenic to humans (cobalt)
IARC: 2B - Group 2B: Possibly carcinogenic to humans (Nickel)
1 - Group 1: Carcinogenic to humans (Nickel)
2B - Group 2B: Possibly carcinogenic to humans (Nickel)
IARC: 2B - Group 2B: Possibly carcinogenic to humans (cobalt)
2A - Group 2A: Probably carcinogenic to humans (cobalt)
NTP: RAHC - Reasonably anticipated to be a human carcinogen (Nickel)
RAHC - Reasonably anticipated to be a human carcinogen (Nickel)
OSHA: No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
Reproductive toxicity
May harm the unborn child.
May impair fertility.
Specific target organ toxicity - single exposure
No data availableSpecific target organ toxicity - repeated exposure
Mixture causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
No data available
Additional Information
Not available
Kidney injury may occur., Damage to the eyes., Lung irritation, chest pain, pulmonary
edema, May cause irritation of the:, nose, Throat., sensation of heat
Other dangerous properties can not be excluded.
This substance should be handled with particular care.
Handle in accordance with good industrial hygiene and safety practice.
Stomach - Irregularities - Based on Human Evidence
Components
Nickel
Acute toxicity
LD50 Oral - Rat - male and female - > 9,000 mg/kg
(OECD Test Guideline 401)
Dermal: No data available
No data available
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitization
Germ cell mutagenicity
No data available
Carcinogenicity
Limited evidence of carcinogenicity in animal studies
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
Inhalation - Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
No data available
cobalt
Acute toxicity
LD50 Oral - Rat - female - 550 mg/kg
(OECD Test Guideline 425)
LC50 Inhalation - Rat - male and female - 4 h - <= 0.05 mg/l
(OECD Test Guideline 436)
Dermal: No data available
No data available
Skin corrosion/irritation
Skin - reconstructed human epidermis (RhE)
Result: No skin irritation - 15 min
(OECD Test Guideline 439)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: irritating
(OECD Test Guideline 405)
Respiratory or skin sensitization
May cause allergic respiratory and skin reactions
Germ cell mutagenicity
Suspected of causing genetic defects.
Carcinogenicity
Presumed to have carcinogenic potential for humans
Reproductive toxicity
May damage fertility.
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
No data available


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Mixture
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
Other adverse effects
No data available
Components
Nickel
Toxicity to fish LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates
EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h
cobalt
Toxicity to fish static test LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h
(OECD Test Guideline 203)
Remarks: (above the solubility limit in the test medium)
Toxicity to daphnia
and other aquatic
invertebrates
static test NOEC - Daphnia magna (Water flea) - 3.2 mg/l - 48h
(OECD Test Guideline 202)
Remarks: (above the solubility limit in the test medium)
Toxicity to algae Remarks: No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste. Handle uncleaned
containers like the product itself. See www.retrologistik.com for processes regarding the
return of chemicals and containers, or contact us there if you have further questions.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
Further information
Not classified as dangerous in the meaning of transport regulations.


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
This material does not contain any components with a section 302 EHS TPQ.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III,
Section 313:
cobalt
CAS-No.
7440-48-4
Revision Date
1989-08-11
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.