CAS No. 13709-95-0

Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information NONH for all modes of transport

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SAFETY DATA SHEET

Date Accessed: 12/08/2024
Date Revised: 01/15/2022

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #13709-95-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Not a hazardous substance or mixture.
GHS Label elements, including precautionary statements
Not a hazardous substance or mixture.
Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula : LaBO3
Molecular weight : 197.71 g/mol
CAS-No. : 13709-95-0
EC-No. : 237-263-8


SECTION 4. FIRST AID MEASURES

Description of first-aid measures
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Borane/boron oxides
Lanthanum oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapors, mist or gas.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Advice on protection against fire and explosion
Provide appropriate exhaust ventilation at places where dust is formed.
Hygiene measures
General industrial hygiene practice.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
Keep container tightly closed in a dry and well-ventilated place.
Storage class
Storage class (TRGS 510): 11: Combustible Solids
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Ingredients with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with
applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of
dangerous substances, and to the specific work-place., The type of protective
equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of
dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use
respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting
point/freezing point
Melting point/range: > 300 °C (> 572 °F)
f) Initial boiling point
and boiling range
No data available
g) Flash point ()Not applicable
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Density No data available
Relative density No data available
n) Water solubility No data available
o) Partition coefficient:
n-octanol/water
No data available
p) Autoignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
glass, Steel (all types and surface treatments), Aluminum
Hazardous decomposition products
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
Oral: No data available
Inhalation: No data available
Dermal: No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH: No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
Toxicity reported for borates in humans: ingestion or absorption may cause nausea,
vomiting, diarrhea, abdominal cramps, anderythematous lesions on the skin and mucous
membranes. Other symptoms include: circulatory collapse, tachycardia, cyanosis, delirium,
convulsions, and coma. Death has been reported to occur in infants from less than 5 grams
and in adults from 5 to 20 grams., To the best of our knowledge, the chemical, physical,
and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
Endocrine disrupting properties
No data available
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
Further information
Not classified as dangerous in the meaning of transport regulations.


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that
exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section
313.
SARA 311/312 Hazards
No SARA Hazards
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
boron lanthanum(3+) trioxide CAS-No.
13709-95-0
Revision Date
New Jersey Right To Know Components
boron lanthanum(3+) trioxide CAS-No.
13709-95-0
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to the State of California to cause
cancer, birth, or any other reproductive defects.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • Microwave-assisted synthesis of Eu3+ doped lanthanum orthoborates, their characterizations and luminescent properties. Cansin Badan, Okan Esenturk, Ayşen Yılmaz. Solid State Sciences, Volume 14, Issues 11–12, November 2012, Pages 1710-1716.
  • Nonlinear optical studies of lead lanthanum borate glass doped with Au nanoparticles. R. Rajaramakrishna, Safakath Karuthedath, R. V. Anavekar, H. Jain. Journal of Non-Crystalline Solids, Volume 358, Issue 14, 15 July 2012, Pages 1667-1672.
  • Preparation, friction and wear properties of hydrophobic lanthanum borate nanorods in rapeseed oil. Ke-cheng Gu, Bo-shui Chen, Xue-mei Wang, Jiu Wang, Li-chuan Huang. Transactions of Nonferrous Metals Society of China, Volume 24, Issue 11, November 2014, Pages 3578-3584.
  • Structure and nonlinear optical studies of Au nanoparticles embedded in lead lanthanum borate glass. R. Rajaramakrishna, Chatree Saiyasombat, R. V. Anavekar, H. Jain. Journal of Non-Crystalline Solids, Volume 406, 15 December 2014, Pages 107-110.
  • Structure modeling of terbium doped strontium-lanthanum borate. A. Shyichuk, S. Lis, G. Meinrath. Journal of Rare Earths, Volume 32, Issue 3, March 2014, Pages 248-253.
  • Key factors in Sr-doped LaBO3 (B=Co or Mn) perovskites for NO oxidation in efficient diesel exhaust purification. Jon A. Onrubia, B. Pereda-Ayo, U. De-La-Torre, Juan R. González-Velasco. Applied Catalysis B: Environmental, Volume 213, 15 September 2017, Pages 198-210.
  • Synthesis, characterization, and dielectric properties of low loss LaBO3 ceramics. Xingyu Chen, Shuxin Bai, Ming Li, Weijun Zhang. Journal of the European Ceramic Society, Volume 33, Issues 15–16, December 2013, Pages 3001-3006.
  • Ultraviolet and near-infrared luminescence of LaBO3:Ce3+,Yb3+. Heng-Wei Wei, Li-Ming Shao, Huan Jiao, Xi-Ping Jing. Optical Materials, Volume 75, January 2018, Pages 442-447.
  • Novel LaBO3 hollow nanospheres of size 34±2nm templated by polymeric micelles. Manickam Sasidharan, Nanda Gunawardhana, Hom Nath Luitel, Toshiyuki Yokoi, Kenichi Nakashima. Journal of Colloid and Interface Science, Volume 370, Issue 1, 15 March 2012, Pages 51-57