CAS No. 346417-97-8

Chemical Identifiers

Linear Formula LiNixMnyCozO2
MDL Number N/A
EC No. N/A

Health & Safety Information

Signal Word Warning
Hazard Statements H317-H351
Hazard Codes Xn
Risk Codes 40-43
Safety Statements 36/37
RTECS Number N/A
Transport Information N/A
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/04/2020
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #346417-97-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin sensitisation(Category 1), H317
Carcinogenicity(Category 2), H351
GHS Label elements, including precautionary statements
Pictogram

Exclamation Mark - GHS07 Health Hazard - GHS08

Signal word
Warning
Hazard statement(s)
H317
May cause an allergic skin reaction.
H351
Suspected of causing cancer.
Precautionary statement(s)
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P261
Avoid breathing dust/ fume/ gas/ mist/ Vapors/ spray.
P272
Contaminated work clothing should not be allowed out of the workplace.
P280
Wear protective gloves.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P308 + P313
IF exposed or concerned: Get medical advice/ attention.
P321
Specific treatment (see supplemental first aid instructions on this label).
P333 + P313
If skin irritation or rash occurs: Get medical advice/ attention.
P363
Wash contaminated clothing before reuse.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Lithium nickel manganese cobalt oxide
CAS-No.: 346417-97-8
Synonyms: NMC


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Nickel/nickel oxides, Lithium oxides, Cobalt/cobalt oxides, Manganese/manganese oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: powder
Color: black
Odor
No data available
Odor Threshold
No data available
pH
No data available
Melting point/freezing point
Melting point/range: > 290 °C (> 554 °F)-lit.
Initial boiling point and boiling range
No data available
Flash point
No data available
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapor pressure
No data available
Vapor density
No data available
Relative density
No data available
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
Germ cell mutagenicity
No data available
Carcinogenicity
Limited evidence of a carcinogenic effect.
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Large doses of lithium ion have caused dizziness and prostration, and can cause kidney damage if sodium intake is limited. Dehydration, weight loss, dermatological effects, and thyroid disturbances have been reported. Central nervous system effects that include slurred speech, blurred vision, sensory loss, ataxia, and convulsions may occur. Diarrhea, vomiting, and neuromuscular effects such as tremor, clonus, and hyperactive reflexes may occur as a result of
repeated exposure to lithium ion.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Lithium nickel manganese cobalt oxide
CAS-No.
346417-97-8
Revision Date
2007-07-01
New Jersey Right To Know Components
Lithium nickel manganese cobalt oxide
CAS-No.
346417-97-8
Revision Date
2007-07-01
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • A bi-functional lithium difluoro(oxalato)borate additive for lithium cobalt oxide/lithium nickel manganese cobalt oxide cathodes and silicon/graphite anodes in lithium-ion batteries at elevated temperatures. Sung Jun Lee, Jung-Gu Han, Yongwon Lee, Myung-Hwan Jeong, Nam-Soon Choi. Electrochimica Acta, Volume 137, 10 August 2014, Pages 1-8.
  • A comparative study of structural changes in lithium nickel cobalt manganese oxide as a function of Ni content during delithiation process. Kyoungmin Min, Kihong Kim, Changhoon Jung, Seung-Woo Seo, Eunseog Cho. Journal of Power Sources, Volume 315, 31 May 2016, Pages 111-119.
  • Atmospheric plasma spray pyrolysis of lithiated nickel-manganese-cobalt oxides for cathodes in lithium ion batteries. Babajide Patrick Ajayi, Arjun Kumar Thapa, Uroš Cvelbar, Jacek B. Jasinski, Mahendra K. Sunkara. Chemical Engineering Science, Volume 174, 31 December 2017, Pages 302-310.
  • Beneficial effect of propane sultone and tris(trimethylsilyl) borate as electrolyte additives on the cycling stability of the lithium rich nickel manganese cobalt (NMC) oxide. Agnese Birrozzi, Nina Laszczynski, Maral Hekmatfar, Jan von Zamory, Stefano Passerini. Journal of Power Sources, Volume 325, 1 September 2016, Pages 525-533.
  • Cycle aging studies of lithium nickel manganese cobalt oxide-based batteries using electrochemical impedance spectroscopy. Arpit Maheshwari, Michael Heck, Massimo Santarelli. Electrochimica Acta, Volume 273, 20 May 2018, Pages 335-348.
  • Domain formation in lithium-rich manganese-nickel-cobalt-oxide epitaxial thin films and implications for interpretation of electrochemical behavior. Aaron C. Johnston-Peck, Saya Takeuchi, K. Kamala Bharathi, Andrew A. Herzing, Leonid A. Bendersky. Thin Solid Films, Volume 647, 1 February 2018, Pages 40-49.
  • Effect of pristine nanostructure on first cycle electrochemical characteristics of lithium-rich lithium–nickel–cobalt–manganese-oxide cathode ceramics for lithium ion batteries. Lars Riekehr, Jinlong Liu, Björn Schwarz, Florian Sigel, Helmut Ehrenberg. Journal of Power Sources, Volume 306, 29 February 2016, Pages 135-147.
  • Effect of additives on electrochemical performance of lithium nickel cobalt manganese oxide at high temperature. Kyoung Seok Kang, Suneui Choi, JunHo Song, Sang-Gil Woo, Young-Jun Kim. Journal of Power Sources, Volume 253, 1 May 2014, Pages 48-54.
  • Enhanced high voltage performances of layered lithium nickel cobalt manganese oxide cathode by using trimethylboroxine as electrolyte additive. Qipeng Yu, Zhiting Chen, Lidan Xing, Dongrui Chen, Weishan Li. Electrochimica Acta, Volume 176, 10 September 2015, Pages 919-925.
  • Facile preparation of praseodymium oxide coated peanut-like lithium nickel cobalt manganese oxide microspheres for lithium ion batteries with high voltage capabilities. Zhaoting Meng, Yudai Huang, Yingchun Fang, Xingchao Wang, Lei Wang. Journal of Alloys and Compounds, Volume 784, 5 May 2019, Pages 620-627.