CAS No. 99652-26-3

Chemical Identifiers

Linear Formula Ti-Cu
Pubchem CID 14818427
MDL Number MFCD00192503
EC No. N/A
IUPAC Name copper; titanium
SMILES [Ti].[Cu]
InchI Identifier InChI=1S/Cu.Ti
InchI Key IUYOGGFTLHZHEG-UHFFFAOYSA-N

Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Precautionary Statements N/A
Risk Codes N/A
Safety Statements N/A
Transport Information NONH for all modes of transport
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 04/19/2024
Date Revised: 01/15/2022

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #99652-26-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified as hazardous to health or the environment according to the CLP regulation.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
N/A
Information concerning particular hazards for human and environment:
No data available
Hazards not otherwise classified
No data available
Label elements
Labelling according to Regulation (EC) No 1272/2008
N/A
Hazard pictograms
N/A
Signal word
N/A
Hazard statements
N/A
WHMIS classification
Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 0
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
7440-50-8 Copper
7440-32-6 Titanium


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
No special measures required.
If inhaled:
Seek medical treatment in case of complaints.
In case of skin contact:
Generally the product does not irritate the skin.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed:
If symptoms persist consult doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Copper oxides
Advice for firefighters
Protective equipment:
No special measures required.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Do not allow product to enter drains, sewage systems, or other water courses.
Do not allow material to penetrate the ground or soil.
Methods and materials for containment and cleanup:
Pick up mechanically.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Information about protection against explosions and fires:
No special measures required.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
No data available
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace: 7440-50-8 Copper (100.0%)
PEL (USA) Long-term value: 1* 0.1** mg/m3 as Cu *dusts and mists **fume
REL (USA) Long-term value: 1* 0.1** mg/m3 as Cu *dusts and mists **fume
TLV (USA) Long-term value: 1* 0.2** mg/m3 *dusts and mists; **fume; as Cu
EL (Canada) Long-term value: 1* 0.2** mg/m3 *dusts and mists; **fume
EV (Canada) Long-term value: 0.2* 1** mg/m3 as copper, *fume;**dust and mists
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Not required.
Protection of hands: Not required.
Penetration time of glove material (in minutes)
No data available
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Solid in various forms
Color: No data available
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 1083 °C (1981 °F)
Boiling point/Boiling range: 2562 °C (4644 °F)
Sublimation temperature / start: No data available
Flammability (solid, gas): No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure at 20 °C (68 °F): 0 hPa
Density at 20 °C (68 °F): 8.94 g/cm3 (74.604 lbs/gal)
Relative density: No data available.
Vapor density: N/A
Evaporation rate: N/A
Solubility in Water (H2O): Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
Copper oxides


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification:
Oral LD50 >5000 mg/kg (mouse)
Skin irritation or corrosion: No irritant effect.
Eye irritation or corrosion: No irritant effect.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity:
EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of carcinogenicity or no data are available.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carc inogenic and/or neoplastic data for this substance.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA
N/A
UN proper shipping name
DOT, ADN, IMDG, IATA
N/A
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
N/A
Packing group
DOT, IMDG, IATA
N/A
Environmental hazards:
Marine pollutant (IMDG):
Yes (PP)
Yes (P)
Special precautions for user
N/A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7440-50-8 Copper
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • Galvanic corrosion behavior of copper/titanium galvanic couple in artificial seawater. Xiao-qing DU, Qing-song YANG, Yu CHEN, Yang YANG, Zhao ZHANG. Transactions of Nonferrous Metals Society of China, Volume 24, Issue 2, February 2014, Pages 570-581.
  • A new antibacterial titanium–copper sintered alloy: Preparation and antibacterial property. Erlin Zhang, Fangbing Li, Hongying Wang, Jie Liu, Ke Yang. Materials Science and Engineering: C, Volume 33, Issue 7, October 2013, Pages 4280-4287.
  • Antibacterial investigation of titanium-copper alloys using luminescent Staphylococcus epidermidis in a direct contact test. Lee Fowler, Oscar Janson, Håkan Engqvist, Susanne Norgren, Caroline Öhman-Mägi. Materials Science and Engineering: C, Volume 97, April 2019, Pages 707-714.
  • Microstructural, electrochemical and tribo-electrochemical characterisation of titanium-copper biomedical alloys. V. Guiñón Pina, V. Amigó, A. Igual Muñoz. Corrosion Science, Volume 109, August 2016, Pages 115-125.
  • Effect of Cu content on the antibacterial activity of titanium–copper sintered alloys. Jie Liu, Fangbing Li, Cong Liu, Hongying Wang, Erlin Zhang. Materials Science and Engineering: C, Volume 35, 1 February 2014, Pages 392-400.
  • Spark plasma sintering of titanium-coated diamond and copper–titanium powder to enhance thermal conductivity of diamond/copper composites. Q. L. Che, J. J. Zhang, X. K. Chen, Y. Q. Ji, Y. G. Jiang. Materials Science in Semiconductor Processing, Volume 33, May 2015, Pages 67-75.
  • Improving hemocompatibility and accelerating endothelialization of vascular stents by a copper-titanium film. Hengquan Liu, Changjiang Pan, Shijie Zhou, Junfeng Li, Lihua Dong. Materials Science and Engineering: C, Volume 69, 1 December 2016, Pages 1175-1182.
  • First-principles calculations of the structural, elastic and thermodynamic properties of tetragonal copper-titanium intermetallic compounds. Yong Li, Xiao-Juan Ma, Qi-Jun Liu, Fu-Sheng Liu, Zheng-Tang Liu. Journal of Alloys and Compounds, Volume 687, 5 December 2016, Pages 984-989.
  • Influence of processing parameters on laser metal deposited copper and titanium alloy composites. Mutiu F. ERINOSHO, Esther T. AKINLABI, Sisa PITYANA. Transactions of Nonferrous Metals Society of China, Volume 25, Issue 8, August 2015, Pages 2608-2616.
  • Hemocompatibility and anti-endothelialization of copper–titanium coating for vena cava filters. Hengquan Liu, Deyuan Zhang, Feng Shen, Gui Zhang, Shenhua Song. Surface and Coatings Technology, Volume 206, Issue 16, 15 April 2012, Pages 3501-3507.
  • Microstructural evolution of copper–titanium alloy during in-situ formation of TiB2 particles. M. SOBHANI, H. ARABI, A. MIRHABIBI, R. M. D. BRYDSON. Transactions of Nonferrous Metals Society of China, Volume 23, Issue 10, October 2013, Pages 2994-3001.
  • Antibacterial effect of copper-bearing titanium alloy (Ti-Cu) against Streptococcus mutans and Porphyromonas gingivalis. Liu R, Memarzadeh K, Chang B, Zhang Y, Ma Z, Allaker RP, Ren L, Yang K. Scientific reports. 2016 Jul 26;6:29985.