Cation Diffusion and Segregation at the Interface between Samarium-Doped Ceria and LSCF or LSFCu Cathodes Investigated with X-ray Microspectroscopy.

Title Cation Diffusion and Segregation at the Interface between Samarium-Doped Ceria and LSCF or LSFCu Cathodes Investigated with X-ray Microspectroscopy.
Authors F. Giannici; G. Canu; A. Chiara; M. Gambino; C. Aliotta; A. Longo; V. Buscaglia; A. Martorana
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.7b13377
Abstract

The chemical compatibility between electrolytes and electrodes is an extremely important aspect governing the overall impedance of solid-oxide cells. Because these devices work at elevated temperatures, they are especially prone to cation interdiffusion between the cell components, possibly resulting in secondary insulating phases. In this work, we applied X-ray microspectroscopy to study the interface between a samarium-doped ceria (SDC) electrolyte and lanthanum ferrite cathodes (La0.4Sr0.6Fe0.8Cu0.2O3 (LSFCu); La0.9Sr0.1Fe0.85Co0.15O3 (LSCF)), at a submicrometric level. This technique allows to combine the information about the diffusion profiles of cations on the scale of several micrometers, together with the chemical information coming from space-resolved X-ray absorption spectroscopy. In SDC-LSCF bilayers, we find that the prolonged thermal treatments at 1150 °C bring about the segregation of samarium and iron in micrometer-sized perovskite domains. In both SDC-LSCF and SDC-LSFCu bilayers, cerium diffuses into the cathode perovskite lattice A-site as a reduced Ce3+ cation, whereas La3+ is easily incorporated in the ceria lattice, reaching 30 atom % in the ceria layer in contact with LSFCu.

Citation F. Giannici; G. Canu; A. Chiara; M. Gambino; C. Aliotta; A. Longo; V. Buscaglia; A. Martorana.Cation Diffusion and Segregation at the Interface between Samarium-Doped Ceria and LSCF or LSFCu Cathodes Investigated with X-ray Microspectroscopy.. ACS Appl Mater Interfaces. 2017;9(51):4446644477. doi:10.1021/acsami.7b13377

Related Elements

Cerium

See more Cerium products. Cerium (atomic symbol: Ce, atomic number: 58) is a Block F, Group 3, Period 6 element with an atomic weight of 140.116. The number of electrons in each of cerium's shells is 2, 8, 18, 19, 9, 2 and its electron configuration is [Xe]4f2 6s2. Cerium Bohr ModelThe cerium atom has a radius of 182.5 pm and a Van der Waals radius of 235 pm. In its elemental form, cerium has a silvery white appearance. Cerium is the most abundant of the rare earth metals. It is characterized chemically by having two valence states, the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. Elemental CeriumIt is therefore strongly acidic and oxidizing, in addition to being moderately toxic.The cerous state closely resembles the other trivalent rare earths. Cerium is found in the minerals allanite, bastnasite, hydroxylbastnasite, monazite, rhabdophane, synchysite and zircon. Cerium was discovered by Martin Heinrich Klaproth, Jöns Jakob Berzelius, and Wilhelm Hisinger in 1803 and first isolated by Carl Gustaf Mosander in 1839. The element was named after the asteroid Ceres, which itself was named after the Roman god of agriculture.

Samarium

See more Samarium products. Samarium (atomic symbol: Sm, atomic number: 62) is a Block F, Group 3, Period 6 element with an atomic radius of 150.36. Samarium Bohr ModelThe number of electrons in each of samarium's shells is 2, 8, 18, 24, 8, 2 and its electron configuration is [Xe]4f6 6s2. The samarium atom has a radius of 180 pm and a Van der Waals radius of 229 pm. In its elemental form, samarium has a silvery-white appearance. Elemental Samarium PictureSamarium is not found as free element in nature. It is found in the minerals cerite, gadolinite, samarskite, monazite and bastnäsite. Samarium is classified as a rare earth element and is the 40th most abundant element in the Earth's crust. Samarium was discovered and first isolated by Lecoq de Boisbaudran in 1879. It is named after the mineral samarskite, the mineral from which it was isolated.

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