Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data.

Title Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data.
Authors L.A. Lapkina; V.E. Larchenko; G.A. Kirakosyan; A.Yu Tsivadze; S.I. Troyanov; Y.G. Gorbunova
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b01983
Abstract

The supramolecular dimeric complex [(?-oxo)bis(tetra-15-crown-5-phthalocyaninato)(nicotinato)aluminum(III)]tetra(rubidium) bis(nicotinate) was prepared by addition of an excess of a methanol solution of rubidium nicotinate to a chloroform solution of the aluminum crown-phthalocyaninate, [(HO)Al(15C5)4Pc]. A single-crystal X-ray diffraction study of {[Rb4(NicAl(15C5)4Pc)2(?-O)]2+(Nic-)2}·2.36HNic·11H2O demonstrated that two molecules of the aluminum crown-phthalocyaninate nicotinate are connected through an Al-O-Al bridge supported by sandwiching of crown ether moieties by Rb+ cations.

Citation L.A. Lapkina; V.E. Larchenko; G.A. Kirakosyan; A.Yu Tsivadze; S.I. Troyanov; Y.G. Gorbunova.Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data.. Inorg Chem. 2018;57(1):8285. doi:10.1021/acs.inorgchem.7b01983

Related Elements

Rubidium

See more Rubidium products. Rubidium (atomic symbol: Rb, atomic number: 37) is a Block S, Group 1, Period 5 element with an atomic weight of 5.4678. The number of electrons in each of Rubidium's shells is [2, 8, 18, 8, 1] and its electron configuration is [Kr] 5s1. The rubidium atom has a radius of 248 pm and a Van der Waals radius of 303 pm. Rubidium Bohr ModelRubidium is highly reactive, with properties similar to other Group 1 alkali metals, e.g., rapid oxidation in air. In its elemental form, rubidium has a gray white appearance. Rubidium is found in the minerals lepidolite, leucite, pollucite, carnallite, and zinnwaldite as well as some potassium minerals. Rubidium was discovered by Robert Bunsen and Gustav Kirchhoff in 1861 and was first isolated by George de Hevesy. The name Rubidium, originates from the Latin word rubidus, meaning "dark or deepest red."

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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