Cesium and Strontium Retentions Governed by Aluminosilicate Gel in Alkali-Activated Cements.

Title Cesium and Strontium Retentions Governed by Aluminosilicate Gel in Alkali-Activated Cements.
Authors J.Gook Jang; S.Moi Park; H.Ki Lee
Journal Materials (Basel)
DOI 10.3390/ma10040447
Abstract

The present study investigates the retention mechanisms of cesium and strontium for alkali-activated cements. Retention mechanisms such as adsorption and precipitation were examined in light of chemical interactions. Batch adsorption experiments and multi-technical characterizations by using X-ray diffraction, zeta potential measurements, and the N? gas adsorption/desorption methods were conducted for this purpose. Strontium was found to crystalize in alkali-activated cements, while no cesium-bearing crystalline phases were detected. The adsorption kinetics of alkali-activated cements having relatively high adsorption capacities were compatible with pseudo-second-order kinetic model, thereby suggesting that it is governed by complex multistep adsorption. The results provide new insight, demonstrating that characteristics of aluminosilicate gel with a highly negatively charged surface and high micropore surface area facilitated more effective immobilization of cesium and strontium in comparison with calcium silicate hydrates.

Citation J.Gook Jang; S.Moi Park; H.Ki Lee.Cesium and Strontium Retentions Governed by Aluminosilicate Gel in Alkali-Activated Cements.. Materials (Basel). 2017;10(4). doi:10.3390/ma10040447

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