Chromium(III) Boride

CAS #:

Linear Formula:

CrB

MDL Number:

MFCD00016042

EC No.:

234-487-8

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Chromium(III) Boride
CR3-B-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Chromium(III) Boride
CR3-B-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Chromium(III) Boride
CR3-B-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Chromium(III) Boride
CR3-B-05
Pricing > SDS > Data Sheet >

Chromium(III) Boride Properties (Theoretical)

Compound Formula BCr
Molecular Weight 62.807 g/mol
Appearance Refractory orthorhombic crystals
Melting Point 2100 °C
Boiling Point N/A
Density 6.10 g/cc
Solubility in H2O N/A
Crystal Phase / Structure Orthorhombic
Exact Mass 62.9498 g/mol
Monoisotopic Mass 62.949818 Da

Chromium(III) Boride Health & Safety Information

Signal Word Danger
Hazard Statements H317-H350
Hazard Codes Xn
Risk Codes N/A
Safety Statements N/A
Transport Information NONH for all modes of transport
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Chromium(III) Boride

Product Number: All applicable American Elements product codes, e.g. CR3-B-02 , CR3-B-03 , CR3-B-04 , CR3-B-05

CAS #: 12006-79-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin Sensitization: Category 1
Carcinogenicity: Category 1A
Label Elements
Signal Word: Danger
Hazard Statements:
May cause an allergic skin reaction
May cause cancer by inhalation

Health Hazard - GHS08

Precautionary Statements
Prevention:
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves
Response:
IF exposed or concerned: Get medical attention/advice
Skin:
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
Storage:
Store locked up
Disposal:
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects
WARNING. Cancer and Reproductive Harm - https://www.p65warnings.ca.gov/.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component: Chromium boride (CrB)
CAS-No: 12006-79-0
Weight: < 100%


SECTION 4. FIRST AID MEASURES

General Advice:
If symptoms persist, call a physician.
Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact:
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation:
Move to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.
Ingestion:
Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.
Most important symptoms and effects:
May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing
Notes to Physician:
Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media: Not combustible.
Unsuitable Extinguishing Media: No information available
Flash Point: No information available
Method - No information available
Autoignition Temperature: No information available
Explosion Limits
Upper: No data available
Lower: No data available
Sensitivity to Mechanical Impact: No information available
Sensitivity to Static Discharge: No information available
Specific Hazards Arising from the Chemical:
Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous Combustion Products:
Oxides of boron Chromium oxides
Protective Equipment and Precautions for Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA
Health: 2
Flammability: 0
Instability: 0
Physical hazards: -


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions:
Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation.
Environmental Precautions:
Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Should not be released into the environment.
Methods for Containment and CleanUp:
Sweep up or vacuum up spillage and collect in suitable container for disposal. Keep in suitable, closed containers for disposal.


SECTION 7. HANDLING AND STORAGE

Handling:
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.
Storage:
Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Component: Chromium boride (CrB)
ACGIH TLV:
OSHA PEL:
NIOSH IDLH: TWA: 0.0002 mg/m3
Mexico OEL (TWA): TWA: 0.5 mg/m3
Engineering Measures:
Ensure adequate ventilation, especially in confined area
Personal Protective Equipment
Eye/face Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection:
Long sleeved clothing.
Respiratory Protection:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Appearance: No information available
Odor: Odorless
Odor Threshold: No information available
pH: No information available
Melting Point/Range: No data available
Boiling Point/Range: No information available
Flash Point: No information available
Evaporation Rate: Not applicable
Flammability (solid,gas): No information available
Flammability or explosive limits
Upper: No data available
Lower: No data available
Vapor Pressure: No information available
Vapor Density: Not applicable
Specific Gravity: No information available
Solubility: No information available
Partition coefficient; n-octanol/water: No data available
Autoignition Temperature: No information available
Decomposition Temperature: No information available
Viscosity: Not applicable
Molecular Formula: CrB
Molecular Weight: 62.81


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard:
None known, based on information available
Stability:
Stable under normal conditions.
Conditions to Avoid:
Incompatible products.
Incompatible Materials:
Oxidizing agents
Hazardous Decomposition Products:
Oxides of boron, Chromium oxides
Hazardous Polymerization:
Hazardous polymerization does not occur.
Hazardous Reactions:
None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component: Chromium boride (CrB)
CAS-No: 12006-79-0
IARC: Not listed
NTP: Known
ACGIH: Not listed
OSHA: Not listed
Mexico: A1
Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.
STOT - single exposure None known
STOT - repeated exposure None known
Symptoms / effects,both acute and delayed:
Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing
Endocrine Disruptor Information:
No information available
Other Adverse Effects:
The toxicological properties have not been fully investigated.
Aspiration hazard No information available


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment. May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.
Persistence and Degradability:
Insoluble in water May persist
Bioaccumulation/ Accumulation:
No information available.
Mobility:
Is not likely mobile in the environment due its low water solubility


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods:
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG/IMO Not regulated


SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
TSCA 12(b) Not applicable
Component: Chromium boride (CrB)
TSCA 12(b): Section 6
SARA 313
Component: Chromium boride (CrB)
CAS-No: 12006-79-0
Weight: < 100%
SARA 313 - Threshold Values: 0.1 %
CWA (Clean Water Act)
Component: Chromium boride (CrB)
CWA - Hazardous Substances
CWA - Reportable Quantities
CWA - Toxic Pollutants X
CWA - Priority Pollutants
Clean Air Act
Component: Chromium boride (CrB)
HAPS Data: X
Class 1 Ozone Depletors
Class 2 Ozone Depletors
OSHA: Not applicable
Component: Chromium boride (CrB)
Specifically Regulated Chemicals: 5 µg/m3 TWA 2.5 µg/m3 Action Level
Highly Hazardous Chemical
California Proposition 65
Component: Chromium boride (CrB)
CAS-No: 12006-79-0
California Prop 65: Carcinogen
Developmental
Female Reproductive
Male Reproductive
Prop 65 NSRL: 0.001 ug/day
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals. Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Chromium(III) Boride

Boride IonChromium Boride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Borides are hard, high-melting materials with metal-like conductivity. They are stable to nonoxidizing acids but break down in strong oxidizing agents and strong alkalis. Borides are used in semiconductors, superconductors, diamagnetic, paramagnetic, ferromagnetic, anti-ferromagnetic, turbine blades, and rocket nozzles. Borides have recently been discovered to be superconductive and ultra-incompressible. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Chromium(III) Boride Synonyms

Chromium boride (CrB), Borylidynechromium, Chromium monoboride, Chromium(3+) monoboride, chromium boron alloy, B-Cr boron-chromium

Chemical Identifiers

Linear Formula CrB
MDL Number MFCD00016042
EC No. 234-487-8
Beilstein/Reaxys No. N/A
Pubchem CID 24860421
IUPAC Name boranylidynechromium
SMILES B#[Cr]
InchI Identifier InChI=1S/B.Cr
InchI Key NUEWEVRJMWXXFB-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Boron

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808 and was first isolated by Humphry Davy later that year. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

Chromium

See more Chromium products. Chromium (atomic symbol: Cr, atomic number: 24) is a Block D, Group 6, Period 4 element with an atomic weight of 51.9961. Chromium Bohr ModelThe number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electron configuration is [Ar] 3d5 4s1. Louis Nicolas Vauquelin first discovered chromium in 1797 and first isolated it the following year. The chromium atom has a radius of 128 pm and a Van der Waals radius of 189 pm. In its elemental form, chromium has a lustrous steel-gray appearance. Elemental ChromiumChromium is the hardest metallic element in the periodic table and the only element that exhibits antiferromagnetic ordering at room temperature, above which it transforms into a paramagnetic solid. The most common source of chromium is chromite ore (FeCr2O4). Due to its various colorful compounds, Chromium was named after the Greek word 'chroma.' meaning color.

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