Chromium(III) Chloride Hexahydrate

CAS 10060-12-5
Linear Formula: CrCl3• 6H2O
MDL Number: MFCD00149660
EC No.: 233-038-3

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PRODUCT Product Code REQUEST A QUOTE SAFETY DATA TECHNICAL DATA
(2N) 99% Chromium(III) Chloride Hexahydrate
CR-CL-02-6HYD Pricing
(3N) 99.9% Chromium(III) Chloride Hexahydrate
CR-CL-03-6HYD Pricing
(4N) 99.99% Chromium(III) Chloride Hexahydrate
CR-CL-04-6HYD Pricing
(5N) 99.999% Chromium(III) Chloride Hexahydrate
CR-CL-05-6HYD Pricing

Properties

Compound Formula Cl3CrH12O6
Molecular Weight 266.45
Appearance dark green solid
Melting Point 83°C
Boiling Point N/A
Density 1.76
Monoisotopic Mass 264.910454
Exact Mass 264.910454

Health & Safety Information

Signal Word Warning
Hazard Statements H302
Hazard Codes Xn
Precautionary Statements P301 + P312 + P330
Risk Codes 22
Safety Statements N/A
RTECS Number GB5450000
Transport Information NONH
WGK Germany 1

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SAFETY DATA SHEET

Date Accessed: 09/26/2016
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Chromium(III) Chloride Hexahydrate

Product Number: All applicable American Elements product codes, e.g. CR-CL-02-6HYD , CR-CL-03-6HYD , CR-CL-04-6HYD , CR-CL-05-6HYD

CAS #: 10060-12-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
C; Corrosive
R34: Causes burns.
Xn; Harmful
R22: Harmful if swallowed.
Xn; Sensitizing
R42/43: May cause sensitization by inhalation and skin contact.
Information concerning particular hazards for human and environment:
Not applicable
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Corrosion - GHS05 Exclamation Mark - GHS07 Health Hazard - GHS08

GHS05
GHS07
GHS08
Signal word
Danger
Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P284 In case of inadequate ventilation wear respiratory protection.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3

1
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
10060-12-5 Chromium(III) chloride hexahydrate
Identification number(s):
EC number:
233-038-3


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Toxic metal oxide fume
Hydrogen chloride (HCl)
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Prevent formation of dust.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values
that have to be monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Tightly sealed goggles
Full face protection
Body protection:
Protective work clothing


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Color: Dark green to black
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 83 °C (181 °F)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 1.76 g/cm³ (14.687 lbs/gal)
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water at 25 °C (77 °F): 585 g/l
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Toxic metal oxide fume
Hydrogen chloride (HCl)


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if swallowed.
Swallowing will lead to a strong corrosive effect on mouth and
throat and to the danger of perforation of esophagus and stomach.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
Oral LD50 1790 mg/kg (rat)
Skin irritation or corrosion:
Causes severe skin burns.
Eye irritation or corrosion:
Causes serious eye damage.
Sensitization:
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Germ cell mutagenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this substance.
Carcinogenicity:
EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of carcinogenicity or no data are available.
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3260
UN proper shipping name
DOT
Corrosive solid, acidic, inorganic, n.o.s. (chromium (III) chloride)
IMDG, IATA
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Chromium(III) chloridehexahydrate)
Transport hazard class(es)
DOT
Class
8 Corrosive substances.
Label
8
Class
8 (C2) Corrosive substances
Label
8
IMDG, IATA
Class
8 Corrosive substances.
Label
8
Packing group
DOT, IMDG, IATA
III
Environmental hazards: Not applicable.
Special precautions for user
Warning: Corrosive substances
Segregation groups
Acids
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3260, Corrosive solid, acidic, inorganic, n.o.s. (chromium (III) chloride), 8, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
10060-12-5 Chromium(III) chloride hexahydrate
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Chloride IonChromium(III) Chloride Hexahydrate is an excellent water soluble crystalline Chromium source for uses compatible with chlorides. Chromium Chloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. We also produce Chromium Chloride Solution. Additional technical, research and safety information is available.

Synonyms

Chromium trichloride hexahydrate, Hexaaquachromium(III) chloride, Chromic chloride hexahydrate, trichlorochromium hexahydrate, chromic chloride

Chemical Identifiers

Linear Formula CrCl3• 6H2O
CAS 10060-12-5
Pubchem CID 104957
MDL Number MFCD00149660
EC No. 233-038-3
Beilstein Registry No. N/A
IUPAC Name trichlorochromium; hexahydrate
SMILES O.O.O.O.O.O.Cl[Cr](Cl)Cl
InchI Identifier InChI=1S/3ClH.Cr.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3
InchI Key LJAOOBNHPFKCDR-UHFFFAOYSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

SUCCESS

See more Chromium products. Chromium (atomic symbol: Cr, atomic number: 24) is a Block D, Group 6, Period 4 element with an atomic weight of 51.9961. Chromium Bohr ModelThe number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electron configuration is [Ar] 3d5 4s1. Chromium was first discovered by Louis Nicolas Vauquelin in 1797. It was first isolated in 1798, also by Louis Nicolas Vauquelin. The chromium atom has a radius of 128 pm and a Van der Waals radius of 189 pm. In its elemental form, chromium has a lustrous steel-gray appearance. Elemental ChromiumChromium is the hardest metal element in the periodic table and the only element that exhibits antiferromagnetic ordering at room temperature, above which it tranforms into a paramagnetic solid. The most common source of chromium is chromite ore (FeCr2O4). Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color.

Recent Research

Combined nano-biotechnology for in-situ remediation of mixed contamination of groundwater by hexavalent chromium and chlorinated solvents., Němeček, Jan, Pokorný Petr, Lhotský Ondřej, Knytl Vladislav, Najmanová Petra, Steinová Jana, Černík Miroslav, Filipová Alena, Filip Jan, and Cajthaml Tomáš , Sci Total Environ, 2016 Sep 1, Volume 563-564, p.822-34, (2016)

Adverse effects and bioconcentration of chromium in two freshwater rotifer species., Hernández-Ruiz, Esmeralda, Alvarado-Flores Jesús, Rubio-Franchini Isidoro, Ventura-Juárez Javier, and Rico-Martínez Roberto , Chemosphere, 2016 Sep, Volume 158, p.107-15, (2016)

Chromium speciation in tannery effluent after alkaline precipitation: Isolation and characterization., Wang, Dandan, He Shiya, Shan Chao, Ye Yuxuan, Ma Hongrui, Zhang Xiaolin, Zhang Weiming, and Pan Bingcai , J Hazard Mater, 2016 Oct 5, Volume 316, p.169-77, (2016)

Chromium immobilization by extra- and intraradical fungal structures of arbuscular mycorrhizal symbioses., Wu, Songlin, Zhang Xin, Sun Yuqing, Wu Zhaoxiang, Li Tao, Hu Yajun, Lv Jitao, Li Gang, Zhang Zhensong, Zhang Jing, et al. , J Hazard Mater, 2016 Oct 5, Volume 316, p.34-42, (2016)

Investigation of the adsorption-reduction mechanisms of hexavalent chromium by ramie biochars of different pyrolytic temperatures., Zhou, Lu, Liu Yunguo, Liu Shaobo, Yin Yicheng, Zeng Guangming, Tan Xiaofei, Hu Xi, Hu Xinjiang, Jiang Luhua, Ding Yang, et al. , Bioresour Technol, 2016 Oct, Volume 218, p.351-9, (2016)

A novel electro-driven membrane for removal of chromium ions using polymer inclusion membrane under constant D.C. electric current., Kaya, Ahmet, Onac Canan, and H Alpoguz Korkmaz , J Hazard Mater, 2016 Nov 5, Volume 317, p.1-7, (2016)

Graphene/biofilm composites for enhancement of hexavalent chromium reduction and electricity production in a biocathode microbial fuel cell., Song, Tian-Shun, Jin Yuejuan, Bao Jingjing, Kang Dongzhou, and Xie Jingjing , J Hazard Mater, 2016 Nov 5, Volume 317, p.73-80, (2016)

Synthesis and characterization of polyurethane-cellulose acetate blend membrane for chromium (VI) removal., Riaz, Tabinda, Ahmad Adnan, Saleemi Sidra, Adrees Muhammad, Jamshed Fahad, Hai Abdul Moqeet, and Jamil Tahir , Carbohydr Polym, 2016 Nov 20, Volume 153, p.582-91, (2016)

Physiological responses and tolerance of kenaf (Hibiscus cannabinus L.) exposed to chromium., Ding, Han, Wang Guodong, Lou Lili, and Lv Jinyin , Ecotoxicol Environ Saf, 2016 Nov, Volume 133, p.509-18, (2016)

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