SECTION 1. IDENTIFICATION
Product Name: Cobalt 2-Ethylhexanoate
Product Number: All applicable American Elements product codes, e.g. CO-2EH-02-LIQ
, CO-2EH-03-LIQ
, CO-2EH-04-LIQ
, CO-2EH-05-LIQ
CAS #: 136-52-7
Relevant identified uses of the substance: Scientific research and development
Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351
Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS02 GHS06 GHS08
· Signal word Danger
· Hazard-determining components of labeling:
cobalt bis(2-ethylhexanoate)
· Hazard statements
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H351 Suspected of causing cancer.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
2
2
0
Health = 2
Fire = 2
Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
2
2
0
Health = 2
Fire = 2
Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
136-52-7 cobalt bis(2-ethylhexanoate)
SECTION 4. FIRST AID MEASURES
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Immediately call a doctor.
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: No special measures required.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep receptacle tightly sealed.
· Specific end use(s) No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
136-52-7 cobalt bis(2-ethylhexanoate)
TLV Long-term value: 0.02 mg/m³
as Co, BEI
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Color: Violet
· Odor: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: 40 °C (104 °F)
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 229 °C (444 °F)
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
· Explosion limits:
Lower: 0.7 Vol %
Upper: 8.9 Vol %
· Vapor pressure: Not determined.
· Density: Not determined.
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 0.0 %
· Other information No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11. TOXICOLOGICAL INFORMATION
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
136-52-7 cobalt bis(2-ethylhexanoate) 2B
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
SECTION 12. ECOLOGICAL INFORMATION
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes: Not known to be hazardous to water.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
· UN-Number
· DOT, IMDG, IATA UN1993
· UN proper shipping name
· DOT Flammable liquids, n.o.s.
· IMDG, IATA FLAMMABLE LIQUID, N.O.S.
· Transport hazard class(es)
· DOT
· Class 3 Flammable liquids
· Label 3
· IMDG, IATA
· Class 3 Flammable liquids
· Label 3
· Packing group
· DOT, IMDG, IATA III
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids
· EMS Number: F-E,S-E
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· UN "Model Regulation": UN1993, Flammable liquids, n.o.s., 3, III
SECTION 15. REGULATORY INFORMATION
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
All ingredients are listed.
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
~GHS02~GHS06~GHS08
· Signal word Danger
· Hazard-determining components of labeling:
cobalt bis(2-ethylhexanoate)
· Hazard statements
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H351 Suspected of causing cancer.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
compounds). 
The number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. 
Cobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of 