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Cobalt Arsenic Sulfide

Linear Formula:

CoAsS

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Cobalt Arsenic Sulfide
CO-ASS-02
Pricing > SDS > Data Sheet >
(2N5) 99.5% Cobalt Arsenic Sulfide
CO-ASS-025
Pricing > SDS > Data Sheet >
(3N) 99.9% Cobalt Arsenic Sulfide
CO-ASS-03
Pricing > SDS > Data Sheet >
(3N5) 99.95% Cobalt Arsenic Sulfide
CO-ASS-035
Pricing > SDS > Data Sheet >
(4N) 99.99% Cobalt Arsenic Sulfide
CO-ASS-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Cobalt Arsenic Sulfide
CO-ASS-05
Pricing > SDS > Data Sheet >

Cobalt Arsenic Sulfide Properties (Theoretical)

Compound Formula CoAsS
Molecular Weight 165.9
Appearance Reddish gray pieces
Melting Point N/A
Boiling Point N/A
Density 6.33 g/cm3
Solubility in H2O N/A
Crystal Phase / Structure Orthorhombic
Exact Mass 165.826874
Monoisotopic Mass 165.826874

Cobalt Arsenic Sulfide Health & Safety Information

Signal Word Danger
Hazard Statements H301+H311+H331-H350-H410-H410
Hazard Codes T, N
Precautionary Statements P201-P202-P261-P264-P270-P271-P273-P280-P281-P301+P310+P330-P302+P352+P312-P304+P340+P311-P308+P313-P361-P363-P391-P403+P233-P405-P501
Risk Codes N/A
Safety Statements N/A
Transport Information UN1557 6.1/PG III
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Created: 5/15/2015
Date Revised: 5/15/2015

SECTION 1. IDENTIFICATION

Product Name: Cobalt Arsenic Sulfide

Product Number: All applicable American Elements product codes, e.g. CO-ASS-02, CO-ASS-025, CO-ASS-03, CO-ASS-035, CO-ASS-04, CO-ASS-05

Relevant identified uses of the substance: Scientific research and development


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Carcinogenicity (Category 1A), H350
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
GHS Label elements, including precautionary statements
Pictogram

Skull and Crossbones - GHS06 Health Hazard - GHS08 Environment - GHS09

Signal word: Danger
Hazard statement(s)
H301 + H311 + H331
Toxic if swallowed, in contact with skin or if inhaled
H350
May cause cancer.
H410
Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P261
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264
Wash skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P273
Avoid release to the environment.
P280
Wear protective gloves/ protective clothing.
P281
Use personal protective equipment as required.
P301 + P310 + P330
IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse mouth.
P302 + P352 + P312
IF ON SKIN: Wash with plenty of soap and water. Call a POISON
CENTER or doctor/ physician if you feel unwell.
P304 + P340 + P311
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician.
P308 + P313
IF exposed or concerned: Get medical advice/ attention.
P361
Remove/Take off immediately all contaminated clothing.
P363
Wash contaminated clothing before reuse.
P391
Collect spillage.
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula: CoAsS
Molecular weight: N/A
CAS-No.: N/A
EC-No.: N/A
Index-No.: N/A


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Arsenic oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration before additional processing occurs.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510):
Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type
N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate gov
ernment standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: solid
Odour
No data available
Odour Threshold
No data available
pH
No data available
Melting point/freezing point
Melting point/range: No data available
Initial boiling point and boiling range
No data available
Flash point
Not applicable
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Relative density
No data available
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
Heat
Incompatible materials acids, Oxidizing agents, Halogens
Hazardous decomposition products
Other decomposition products-No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
LD50
Oral-Rat-185 mg/kg
Remarks:
Behavioral:Muscle weakness. Lungs, Thorax, or Respiration:Dyspnea. Diarrhea
LD50
Dermal-Rat-936 mg/kg
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
1-Group 1: Carcinogenic to humans
No data available
1-Group 1: Carcinogenic to humans
No data available
NTP:
Known to be human carcinogen
No data available
OSHA:
OSHA specifically regulated carcinogen
No data available
Reproductive toxicity
No data available
No data available
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS:
Not available
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Toxicity to fish
LC50-Pimephales promelas (fathead minnow)-82.3 mg/l-96.0 h
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Very toxic to aquatic life with long lasting effects.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number:1557
Class: 6.1
Packing group: III
Proper shipping name:
Arsenic compounds, solid, n.o.s. (Cobalt arsenic sulfide)
Reportable Quantity
(RQ): 1lbs
Poison Inhalation Hazard: No
IMDG
UN number: 1557
Class: 6.1
Packing group: III
EMS-No: F-A, S-A
Proper shipping name: ARSENIC COMPOUND, SOLID, N.O.S. (Cobalt arsenic sulfide)
Marine pollutant:yes
IATA
UN number:1557
Class: 6.1
Packing group: III
Proper shipping name: Arsenic compound, solid, n.o.s.(Cobalt arsenic sulfide)


SECTION 15. REGULATORY INFORMATION

SARA 302
Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Arsenic(III) sulfide
CAS-No.1303-33-9
Revision Date
1993-04-24
SARA 311/312
Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know
Components
Arsenic(III) sulfide
CAS-No.1303-33-9
Revision Date
1993-04-24
Pennsylvania Right To Know
Components
Arsenic(III) sulfide
CAS-No.1303-33-9
Revision Date
1993-04-24
New Jersey Right To Know
Components
Arsenic(III) sulfide
CAS-No.1303-33-9
Revision Date
1993-04-24
California Prop. 65
Components
WARNING! This product contains a chemical known to the State of California to cause cancer.
Arsenic(III) sulfide
CAS-No.1303-33-9
Revision Date
2007-09-28


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Cobalt Arsenic Sulfide

Cobalt Arsenic Sulfide is generally immediately available in most volumes. American Elements manufactures materials to many standard grades when applicable including Mil Spec (military grade), ACS, Reagent and Technical Grades; Food, Agricultural and Pharmaceutical Grades, Optical, Semiconductor, and Electronics Grades, and follows applicable USP, EP/BP, and ASTM testing standards. Most materials can be produced in high and ultra high purity forms (99%, 99.9%, 99.99%, 99.999%, and higher). Standard and custom packaging is available. Additional technical, research and safety (SDS) information is available. Please request a quote above to receive pricing information based on your specifications.

Cobalt Arsenic Sulfide Synonyms

Cobalt arsenide sulfide, cobalt sulfoarsenide, synthetic cobaltite

Chemical Identifiers

Linear Formula CoAsS
MDL Number N/A
EC No. N/A
IUPAC Name (sulfidoarsoranilidyne)cobalt
SMILES S=[As]#[Co]
InchI Identifier InChI=1S/AsS.Co/c1-2;/q-1;+1
InchI Key XYEOKRQSKMNMCE-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Arsenic products. Arsenic (atomic symbol: As, atomic number: 33) is a Block P, Group 15, Period 4 element with an atomic radius of 74.92160. Arsenic Bohr ModelThe number of electrons in each of arsenic's shells is 2, 8, 18, 5 and its electron configuration is [Ar] 3d10 4s2 4p3. The arsenic atom has a radius of 119 pm and a Van der Waals radius of 185 pm. Arsenic was discovered in the early Bronze Age, circa 2500 BC. It was first isolated by Albertus Magnus in 1250 AD. In its elemental form, arsenic is a metallic grey, brittle, crystalline, semimetallic solid. Elemental ArsenicArsenic is found in numerous minerals including arsenolite (As2O3), arsenopyrite (FeAsS), loellingite (FeAs2), orpiment (As2S3), and realgar (As4S4). Arsenic has numerous applications as a semiconductor and other electronic applications as indium arsenide, silicon arsenide and tin arsenide. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors.

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit." For more information on cobalt, including properties, safety data, research, and American Elements' catalog of cobalt products, visit the Cobalt element page.

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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