Controlled fabrication of osmium nanocrystals by electron, laser and microwave irradiation and characterisation by microfocus X-ray absorption spectroscopy.

Title Controlled fabrication of osmium nanocrystals by electron, laser and microwave irradiation and characterisation by microfocus X-ray absorption spectroscopy.
Authors A. Pitto-Barry; K. Geraki; M.D. Horbury; V.G. Stavros; F.W. Mosselmans; R.I. Walton; P.J. Sadler; N.P.E. Barry
Journal Chem Commun (Camb)
DOI 10.1039/c7cc07133g
Abstract

Osmium nanocrystals can be fabricated by electron (3-50 nm, formed by atom migration), 785-815 nm laser (20-50 nm, in micelle islands), and microwave (ca. 1 nm in arrays, >100 mg scale) irradiation of a polymer-encapsulated OsII carborane; microfocus X-ray absorption studies at the Os LIII-edge show differences between the three preparation methods, suggesting that the electron-beam irradiated materials have a significant support interaction and/or surface oxidation, while the laser and microwave samples are more like metallic osmium.

Citation A. Pitto-Barry; K. Geraki; M.D. Horbury; V.G. Stavros; F.W. Mosselmans; R.I. Walton; P.J. Sadler; N.P.E. Barry.Controlled fabrication of osmium nanocrystals by electron, laser and microwave irradiation and characterisation by microfocus X-ray absorption spectroscopy.. Chem Commun (Camb). 2017;53(96):1289812901. doi:10.1039/c7cc07133g

Related Elements

Osmium

See more Osmium products. Osmium (atomic symbol: Os, atomic number: 76) is a Block D, Group 8, Period 6 element with an atomic weight of 190.23. Osmium Bohr ModelThe number of electrons in each of osmium's shells is [2, 8, 18, 32, 14, 2] and its electron configuration is [Xe] 4f14 5d6 6s2. The osmium atom has a radius of 135 pm and a Van der Waals radius of 216 pm. Osmium was discovered and first isolated by Smithson Tennant in 1803. Elemental OsmiumIn its elemental form, osmium has a silvery blue cast apperance. Osmium has the highest melting point and the lowest vapor pressure of any of the platinum group of metals it is also the densest naturally ocurring element. Osmium is the least abundant stable element in the earth's crust. It is found in the alloys osmiridium and iridiosmium and as a free element. The origin of the name Osmium comes from the Greek word osme, meaning a smell or odor.

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