"Hot" Stryker's Reagent

CAS #:

Linear Formula:

CuH

MDL Number:

MFCD16621396

EC No.:

803-023-1

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Copper Hydride Solution
CU-HID-01-SOL
Pricing > SDS > Data Sheet >

Copper Hydride Solution Properties (Theoretical)

Compound Formula HCu
Molecular Weight 64.55
Appearance Liquid
Melting Point N/A
Boiling Point N/A
Density 0.906 g/mL
Solubility in H2O N/A
Exact Mass 63.937422 g/mol
Monoisotopic Mass 63.937422 g/mol

Copper Hydride Solution Health & Safety Information

Signal Word Danger
Hazard Statements H225-H304-H315-H336-H361-H373-H412
Hazard Codes F, Xn
Precautionary Statements P201-P210-P273-P301+P310+P331-P302+P352-P308+P313
Flash Point 6 °C
Risk Codes N/A
Safety Statements N/A
Transport Information UN 1294 3/PG II
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 04/16/2021
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Copper Hydride Solution

Product Number: All applicable American Elements product codes, e.g. CU-HID-01-SOL

CAS #: 13517-00-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 2), H225
Skin irritation (Category 2), H315
Reproductive toxicity (Category 2), H361
Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336
Specific target organ toxicity - repeated exposure (Category 2), Central nervous system,
H373
Aspiration hazard (Category 1), H304
Short-term (acute) aquatic hazard (Category 2), H401
Long-term (chronic) aquatic hazard (Category 3), H412
For the full text of the H-Statements mentioned in this Section, see Section 16.
GHS Label elements, including precautionary statements
Pictogram

Flame - GHS02 Health Hazard - GHS08 Exclamation Mark - GHS07

Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs (Central nervous system) through
prolonged or repeated exposure.
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and
understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant
foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal
plant.
Sensitising components:
Triphenylphosphine
May produce an allergic reaction.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Mixtures
Copmpnent
Copper Hydride
CAS-No. 13517-00-5
Molecular weight : 64.55 g/mol
Component
Toluene
CAS-No.
108-88-3
Classification
Flam. Liq. 2; Skin Irrit. 2;
Repr. 2; STOT SE 3; STOT
RE 2; Asp. Tox. 1; Aquatic
Acute 2; Aquatic Chronic
3; H225, H315, H361,
H336, H373, H304, H401,
H412
Concentration limits:
20 %: STOT SE 3, H336;


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of
dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Dry powder Dry sand
Unsuitable extinguishing media
Do NOT use water jet.
Special hazards arising from the substance or mixture
Carbon oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
Use water spray to cool unopened containers.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Use explosion-proof equipment.Keep away from sources of ignition - No smoking.Take
measures to prevent the build up of electrostatic charge.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature -20 °C
Handle and store under inert gas. Air and moisture sensitive.
Storage class (TRGS 510): 3: Flammable liquids
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands
before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with
applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective
clothing., The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a fullface
respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing point No data available
f) Initial boiling point and boiling range No data available
g) Flash point 6 °C (43 °F)
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower flammability or explosive limits No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density 0.906 g/cm3
n) Water solubility No data available
o) Partition coefficient: n-octanol/water No data available
p) Auto-ignition temperature No data available
q) Decomposition temperature No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
Conditions to avoid
Avoid moisture.
Heat, flames and sparks.
Incompatible materials
Strong bases, Water, Strong oxidizing agents, Strong acids
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
NTP: No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Lung irritation, chest pain, pulmonary edema, Inhalation studies on toluene have
demonstrated the development of inflammatory and ulcerous lesions of the penis, prepuce,
and scrotum in animals., To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Stomach - Irregularities - Based on Human Evidence


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not
conducted
Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or
disposal.
Toxic to aquatic life.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Burn in a
chemical incinerator equipped with an afterburner and scrubber but exert extra care in
igniting as this material is highly flammable. Contact a licensed professional waste
disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 1294 Class: 3 Packing group: II
Proper shipping name: TolueneSOLUTION
Reportable Quantity (RQ): 1408 lbs
Poison Inhalation Hazard: No
IMDG
UN number: 1294 Class: 3 Packing group: II EMS-No: F-E, S-D
Proper shipping name: TOLUENESOLUTION
IATA
UN number: 1294 Class: 3 Packing group: II
Proper shipping name: TolueneSOLUTION


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III,
Section 313:
Toluene
CAS-No.
108-88-3
Revision Date
2007-07-01
SARA 311/312 Hazards
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2021 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Copper Hydride Solution

Copper Hydride Solutions are moderate to highly concentrated liquid solutions of copper hydride for use in chemical synthesis, solution deposition and other applications. Solvents include THF, hexanes, methanol, and other organic compounds. American Elements can prepare dissolved homogeneous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. Additional technical, research and safety (SDS) information is available. Please request a quote above to receive pricing information based on your specifications.

Copper Hydride Solution Synonyms

Hydridocopper, copper(I) hydride, (BDP)Cu(H) Copper monohydride, Cuprous hydride,"Hot" Stryker's Reagent, Copper hydride (CuH) solution, in toluene

Chemical Identifiers

Linear Formula CuH
MDL Number MFCD16621396
EC No. 803-023-1
Beilstein/Reaxys No. N/A
Pubchem CID 3335333
IUPAC Name copper monohydride
SMILES [CuH]
InchI Identifier InChI=1S/Cu.H
InchI Key JJFLDSOAQUJVBF-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Copper

See more Copper products. Copper Bohr Model Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. The number of electrons in each of copper's shells is 2, 8, 18, 1 and its electron configuration is [Ar] 3d10 4s1. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Copper was first discovered by Early Man prior to 9000 BC. In its elemental form, copper has a red-orange metallic luster appearance. Of all pure metals, only silver Elemental Copperhas a higher electrical conductivity.The origin of the word copper comes from the Latin word 'cuprium' which translates as "metal of Cyprus." Cyprus, a Mediterranean island, was known as an ancient source of mined copper.

TODAY'S SCIENCE POST!

April 16, 2021
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day
From dinner to sustainable electronics, the surprising versatility of crabs

From dinner to sustainable electronics, the surprising versatility of crabs