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Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex

CAS #:

Linear Formula:

(CF3COCHCOCF3)Cu(C8H12)

MDL Number:

MFCD00156517

EC No.:

N/A

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex
CU-FACA15C-01-P
Pricing > SDS > Data Sheet >

Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex Properties (Theoretical)

Compound Formula C13H13CuF6O2
Molecular Weight 378.78
Appearance Yellow powder
Melting Point 93-100 °C
Boiling Point 60°C/0.1mm subl.
Density N/A
Solubility in H2O Insoluble
Exact Mass 378.012 g/mol
Monoisotopic Mass 378.012 g/mol

Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Precautionary Statements P280g-P305+P351+P338
Risk Codes R36/37/38
Safety Statements N/A
Transport Information NONH for all modes of transport
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/18/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex

Product Number: All applicable American Elements product codes, e.g. CU-FACA15C-01-P 01

CAS #: 86233-74-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Skin Corrosion/irritation:
Category 2
Serious Eye Damage/Eye Irritation:
Category 2
Specific target organ toxicity (single exposure):
Category 3
Target Organs:
Respiratory system.

Label Elements
Signal Word: Warning

Pictogram

Exclamation Mark - GHS07

GHS07
Hazard Statements:
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation

Precautionary Statements
Prevention:
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area

Inhalation:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell

Skin:
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse

Eyes:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention

Storage:
Store in a well-ventilated place. Keep container tightly closed
Store locked up

Disposal:
Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC):
None identified


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component:
Copper(I) hexafluoro-2,4-pentanedionate
1,5-cyclooctadiene complex

CAS-No:
86233-74-1

Weight:
< 100%


SECTION 4. FIRST AID MEASURES

General Advice:
If symptoms persist, call a physician.

Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact:
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation:
Move to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.

Notes to Physician:
Treat symptomatically
Ingestion:
Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.

Most important symptoms and effects:
None reasonably foreseeable.


SECTION 5. FIREFIGHTING MEASURES

Unsuitable Extinguishing Media: No information available
Flash Point: No information available
Method: No information available

Autoignition Temperature: No information available
Explosion Limits
Upper: No data available
Lower: No data available
Sensitivity to Mechanical Impact: No information available
Sensitivity to Static Discharge: No information available

Specific Hazards Arising from the Chemical:
Keep product and empty container away from heat and sources of ignition.

Hazardous Combustion Products:
None known

Protective Equipment and Precautions for Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

NFPA
Health: 2
Flammability: 1
Instability: 0
Physical Hazards: -


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions:
Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation.

Environmental Precautions:
Should not be released into the environment. See Section 12 for additional ecological information.

Methods for Containment and Clean Up:
Keep in suitable, closed containers for disposal. Sweep up or vacuum up spillage and collect in suitable container for disposal.


SECTION 7. HANDLING AND STORAGE

Handling:
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage:
Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies.

Engineering Measures:
Ensure that eyewash stations and safety showers are close to the workstation location.

Personal Protective Equipment
Eye/face Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin and body protection:
Long sleeved clothing.

Respiratory Protection:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Appearance: Yellow
Odor: Odorless
Odor Threshold: No information available
pH: No information available
Melting Point/Range: 93 - 100 °C / 199.4 - 212 °F
Boiling Point/Range: 60 °C / 140 °F
Flash Point: No information available
Evaporation Rate: Not applicable
Flammability (solid,gas): No information available
Flammability or explosive limits
Upper: No data available
Lower: No data available
Vapor Pressure: No information available
Vapor Density: Not applicable
Specific Gravity: No information available
Solubility: No information available
Partition coefficient; n-octanol/water: No data available
Autoignition Temperature: No information available
Decomposition Temperature: No information available
Viscosity: Not applicable


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard:
None known, based on information available

Stability:
Stable under normal conditions.

Conditions to Avoid:
Incompatible products.

Incompatible Materials:
Strong oxidizing agents

Hazardous Decomposition Products:
None under normal use conditions

Hazardous Polymerization:
Hazardous polymerization does not occur.

Hazardous Reactions:
None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information:
Component Information:
Toxicologically Synergistic: No information available
Products:

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation: No information available
Sensitization: No information available

Carcinogenicity:
Component: Copper(I) hexafluoro-2,4-pentanedionate 1,5-cyclooctadiene complex
CAS-No: 86233-74-1
IARC: Not listed
NTP: Not listed
ACGIH: Not listed
OSHA: Not listed
Mexico: Not listed

Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.
STOT - single exposure: Respiratory system
STOT - repeated exposure: None known
Aspiration hazard: No information available
Symptoms / effects,both acute and delayed: No information available
Endocrine Disruptor Information: No information available
Other Adverse Effects: The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Do not empty into drains.

Persistence and Degradability: Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation: No information available.

Mobility: Will likely be mobile in the environment due to its volatility.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods:
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated


SECTION 15. REGULATORY INFORMATION

All of the components in the product are on the following Inventory lists:
X = listed

International Inventories
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule.

U.S. Federal Regulations
TSCA 12(b): Not applicable
SARA 313: Not applicable
SARA 311/312: Hazard Categories See section 2 for more information
CWA (Clean Water Act): Not applicable
Clean Air Act: Not applicable
OSHA: Not applicable
CERCLA: Not applicable
California Proposition 65: This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations: Not applicable

U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant: N
DOT Severe Marine Pollutant: N

U.S. Department of Homeland Security:
This product does not contain any DHS chemicals

Other International Regulations:
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex

Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex is an organometallic copper compound used as a precursor material for MOCVD applications. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available.

Copper(I) Hexafluoroacetylacetonate 1,5-cyclooctadiene Complex Synonyms

Copper(I) hexafluoro-2,4-pentanedionate 1,5-cyclooctadiene complex, copper(I) hexafluoroacetylacetonate complex with 1,5-cyclooctadiene, copper hexafluoroacetylacetonate cyclooctadiene, 1,5-Cyclooctadiene(hexafluoro-2,4-pentanedionato)copper(I)

Chemical Identifiers

Linear Formula (CF3COCHCOCF3)Cu(C8H12)
MDL Number MFCD00156517
EC No. N/A
Pubchem CID 92043567
IUPAC Name copper; cyclooctane; (Z)-1,1,1,5,5,5-hexafluoro-4-hydroxypent-3-en-2-one
SMILES C1C[CH][CH]CC[CH][CH]1.C(=C(C(F)(F)F)O)C(=O)C(F)(F)F.[Cu]
InchI Identifier InChI=1S/C8H12.C5H2F6O2.Cu/c1-2-4-6-8-7-5-3-1;6-4(7,8)2(12)1-3(13)5(9,10)11;/h1-2,7-8H,3-6H2;1,12H;/b;2-1-;
InchI Key WSAPIYREFIKPSH-FJOGWHKWSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Copper products. Copper Bohr Model Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. The number of electrons in each of copper's shells is 2, 8, 18, 1 and its electron configuration is [Ar] 3d10 4s1. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Copper was first discovered by Early Man prior to 9000 BC. In its elemental form, copper has a red-orange metallic luster appearance. Of all pure metals, only silver Elemental Copperhas a higher electrical conductivity.The origin of the word copper comes from the Latin word 'cuprium' which translates as "metal of Cyprus." Cyprus, a Mediterranean island, was known as an ancient source of mined copper.

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

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