Dehydrogenation Properties of Magnesium Hydride Loaded with Fe, Fe-C, and Fe-Mg Additives.

Title Dehydrogenation Properties of Magnesium Hydride Loaded with Fe, Fe-C, and Fe-Mg Additives.
Authors D. Pukazhselvan; N. Nasani; T. Yang; I. Bdikin; A.V. Kovalevsky; D.P. Fagg
Journal Chemphyschem
DOI 10.1002/cphc.201601078
Abstract

This study highlights that Fe additives offer better catalytic properties than carbon, Fe-C (iron carbide/carbon composites), and Fe-Mg (Mg2 FeH6 ) additives for the low-temperature dehydrogenation of magnesium hydride. The in?situ X-ray diffraction measurements prove the formation of a Mg2 FeH6 phase in iron additive loaded MgH2 . Nonetheless, differential scanning calorimetry data suggest that this Mg2 FeH6 phase does not have any influence on dehydrogenation properties of MgH2 . On the other hand, the composite system Mg2 FeH6 /MgH2 shows significantly improved dehydrogenation properties even in absence of further additives. It is suggested that the improved system performance of Fe loaded MgH2 is attributed to restrictions on crystal growth of MgH2 and the catalytic behavior of Fe nanoparticles, rather than any intrinsic catalytic properties offered by the formed mixed metal phase Mg2 FeH6 .

Citation D. Pukazhselvan; N. Nasani; T. Yang; I. Bdikin; A.V. Kovalevsky; D.P. Fagg.Dehydrogenation Properties of Magnesium Hydride Loaded with Fe, Fe-C, and Fe-Mg Additives.. Chemphyschem. 2017;18(3):287291. doi:10.1002/cphc.201601078

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Magnesium

Magnesium Bohr ModelSee more Magnesium products. Magnesium (atomic symbol: Mg, atomic number: 12) is a Block S, Group 2, Period 3 element with an atomic mass of 24.3050. The number of electrons in each of Magnesium's shells is [2, 8, 2] and its electron configuration is [Ne] 3s2. The magnesium atom has a radius of 160 pm and a Van der Waals radius of 173 pm. Magnesium was discovered by Joseph Black in 1775 and first isolated by Sir Humphrey Davy in 1808. Magnesium is the eighth most abundant element in the earth's crust and the fourth most common element in the earth as a whole. Elemental MagnesiumIn its elemental form, magnesium has a shiny grey metallic appearance and is an extremely reactive. It is can be found in minerals such as brucite, carnallite, dolomite, magnesite, olivine and talc. Commercially, magnesium is primarily used in the creation of strong and lightweight aluminum-magnesium alloys, which have numerous advantages in industrial applications. The name "Magnesium" originates from a Greek district in Thessaly called Magnesia.

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