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Dodecacarbonyltriosmium

CAS #:

Linear Formula:

Os3(CO)12

MDL Number:

MFCD00011149

EC No.:

239-789-3

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Dodecacarbonyltriosmium Catalysts
CBL12-OS-02-C
Pricing > SDS > Data Sheet >
(2N5) 99.5% Dodecacarbonyltriosmium Catalysts
CBL12-OS-025-C
Pricing > SDS > Data Sheet >
(3N) 99.9% Dodecacarbonyltriosmium Catalysts
CBL12-OS-03-C
Pricing > SDS > Data Sheet >
(3N5) 99.95% Dodecacarbonyltriosmium Catalysts
CBL12-OS-035-C
Pricing > SDS > Data Sheet >
(4N) 99.99% Dodecacarbonyltriosmium Catalysts
CBL12-OS-04-C
Pricing > SDS > Data Sheet >
(5N) 99.999% Dodecacarbonyltriosmium Catalysts
CBL12-OS-05-C
Pricing > SDS > Data Sheet >

Properties

Compound Formula

Os3(CO)12

Molecular Weight

906.8112

Appearance

Yellow Powder or Crystals

Melting Point

224 °C

Boiling Point

N/A

Density

N/A

Exact Mass

909.820384

Monoisotopic Mass

911.823418

Health & Safety Information

Signal Word N/A
Hazard Statements H302-H315-H319-H335
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
RTECS Number N/A
Transport Information N/A
WGK Germany N/A

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 04/24/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Dodecacarbonyltriosmium

Product Number: All applicable American Elements product codes, e.g. CBL12-OS-02-C , CBL12-OS-025-C , CBL12-OS-03-C , CBL12-OS-035-C , CBL12-OS-04-C , CBL12-OS-05-C

CAS #: 15696-40-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
For the full text of the H-Statements mentioned in this Section, see Section 16.

Exclamation Mark - GHS07

2.2 GHS Label elements, including precautionary statements
Pictogram
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves.
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you
feel unwell. Rinse mouth.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/ physician if
you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Synonyms : Osmium carbonyl
tri-Osmium dodecacarbonyl
Formula : C12O12Os3
Molecular weight : 906.81 g/mol
CAS-No. : 15696-40-9
EC-No. : 239-789-3
Hazardous components
Component Classification Concentration
Triangulo-dodecacarbonyltriosmium
Acute Tox. 4; Skin Irrit. 2; Eye
Irrit. 2A; STOT SE 3; H302,
H315, H319, H335
<= 100 %
For the full text of the H-Statements mentioned in this Section, see Section 16.


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
General advice
Move out of dangerous area.Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate
ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible
dust formation should be taken into consideration before additional processing occurs.Avoid contact with skin and
eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510): Non Combustible Solids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved
under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to
the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level
protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: 224 °C (435 °F) - lit.
f) Initial boiling point and
boiling range
No data available
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density No data available
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
No data available
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity
No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Triangulo-dodecacarbonyltriosmium
CAS-No.
15696-40-9
Revision Date
New Jersey Right To Know Components
Triangulo-dodecacarbonyltriosmium
CAS-No.
15696-40-9
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Dodecacarbonyltriosmium is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Triosmium dodecacarbonyl, Dodecacarbonyl-triangulo-triosmium Osmium (0) Carbonyl Osmium, dodecacarbonyltri-, triangulo Triosmium dodecacarbonyl, tri-Osmium dodecacarbonyl, osmium carbonyl

Chemical Identifiers

Linear Formula

Os3(CO)12

Pubchem CID

6096995

MDL Number

MFCD00011149

EC No.

239-789-3

Beilstein Registry No.

N/A

IUPAC Name

carbon monoxide; osmium

SMILES

[Os].[Os].[Os].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-]

InchI Identifier

InChI=1S/12CO.3Os/c12*1-2;;;

InchI Key

VUBLMKVEIPBYME-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Osmium products. Osmium (atomic symbol: Os, atomic number: 76) is a Block D, Group 8, Period 6 element with an atomic weight of 190.23. Osmium Bohr ModelThe number of electrons in each of osmium's shells is [2, 8, 18, 32, 14, 2] and its electron configuration is [Xe] 4f14 5d6 6s2. The osmium atom has a radius of 135 pm and a Van der Waals radius of 216 pm. Osmium was discovered and first isolated by Smithson Tennant in 1803. Elemental OsmiumIn its elemental form, osmium has a silvery blue cast apperance. Osmium has the highest melting point and the lowest vapor pressure of any of the platinum group of metals it is also the densest naturally ocurring element. Osmium is the least abundant stable element in the earth's crust. It is found in the alloys osmiridium and iridiosmium and as a free element. The origin of the name Osmium comes from the Greek word osme, meaning a smell or odor.

Recent Research

Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes., Eguillor, Beatriz, Esteruelas Miguel A., Lezáun Virginia, Oliván Montserrat, and Oñate Enrique , Chemistry, 2017 Jan 31, Volume 23, Issue 7, p.1526-1530, (2017)

In-Cell Activation of Organo-Osmium(II) Anticancer Complexes., Needham, Russell J., Sanchez-Cano Carlos, Zhang Xin, Romero-Canelón Isolda, Habtemariam Abraha, Cooper Margaret S., Meszaros Levente, Clarkson Guy J., Blower Philip J., and Sadler Peter J. , Angew Chem Int Ed Engl, 2017 Jan 19, Volume 56, Issue 4, p.1017-1020, (2017)

Introducing the 4-Phenyl-1,2,3-Triazole Moiety as a Versatile Scaffold for the Development of Cytotoxic Ruthenium(II) and Osmium(II) Arene Cyclometalates., Riedl, Christoph A., Flocke Lea S., Hejl Michaela, Roller Alexander, Klose Matthias H. M., Jakupec Michael A., Kandioller Wolfgang, and Keppler Bernhard K. , Inorg Chem, 2017 Jan 03, Volume 56, Issue 1, p.528-541, (2017)

mer, fac, and Bidentate Coordination of an Alkyl-POP Ligand in the Chemistry of Nonclassical Osmium Hydrides., Esteruelas, Miguel A., García-Yebra Cristina, Martín Jaime, and Oñate Enrique , Inorg Chem, 2017 Jan 03, Volume 56, Issue 1, p.676-683, (2017)

Anticancer osmium complex inhibitors of the HIF-1α and p300 protein-protein interaction., Yang, Chao, Wang Wanhe, Li Guo-Dong, Zhong Hai-Jing, Dong Zhen-Zhen, Wong Chun-Yuen, Kwong Daniel W. J., Ma Dik-Lung, and Leung Chung-Hang , Sci Rep, 2017 Feb 22, Volume 7, p.42860, (2017)

Synchrotron X-Ray Fluorescence Nanoprobe Reveals Target Sites for Organo-Osmium Complex in Human Ovarian Cancer Cells., Sanchez-Cano, Carlos, Romero-Canelón Isolda, Yang Yang, Hands-Portman Ian J., Bohic Sylvain, Cloetens Peter, and Sadler Peter J. , Chemistry, 2017 Feb 21, Volume 23, Issue 11, p.2512-2516, (2017)

Single-Site Osmium Catalysts on MgO: Reactivity and Catalysis of CO Oxidation., Yang, Dong, Zhang Shengjie, Xu Pinghong, Browning Nigel D., Dixon David A., and Gates Bruce C. , Chemistry, 2017 Feb 21, Volume 23, Issue 11, p.2532-2536, (2017)

Dual Pathways in the Oxidation of an Osmium(III) Guanidine Complex. Formation of Osmium(VI) Nitrido and Osmium Nitrosyl Complex., Xiang, Jing, Wang Qian, Yiu Shek-Man, and Lau Tai-Chu , Inorg Chem, 2017 Feb 20, Volume 56, Issue 4, p.2022-2028, (2017)

Tris-bipyridine based dinuclear ruthenium(ii)-osmium(iii) complex dyads grafted onto TiO2 nanoparticles for mimicking the artificial photosynthetic Z-scheme., Favereau, Ludovic, Makhal Abhinandan, Provost David, Pellegrin Yann, Blart Errol, Göransson Erik, Hammarström Leif, and Odobel Fabrice , Phys Chem Chem Phys, 2017 Feb 08, Volume 19, Issue 6, p.4778-4786, (2017)

Novel Osmium-based Coordination Complexes as Photosensitizers for Panchromatic Photodynamic Therapy., Lazic, Savo, Kaspler Pavel, Shi Ge, Monro Susan, Sainuddin Tariq, Forward Sarah, Kasimova Kamola, Hennigar Robie, Mandel Arkady, McFarland Sherri, et al. , Photochem Photobiol, 2017 Apr 03, (2017)

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