Dynamics of water confined in mesoporous magnesium carbonate.

Title Dynamics of water confined in mesoporous magnesium carbonate.
Authors A.J. Soininen; M.S. Appavou; S. Frykstrand; K. Welch; M. Khaneft; A. Kriele; M.C. Bellissent-Funel; M. Strømme; J. Wuttke
Journal J Chem Phys
DOI 10.1063/1.4971285
Abstract

We have measured the dynamics of water confined in a porous magnesium carbonate material, Upsalite®, using the high-resolution neutron backscattering spectrometer SPHERES. We found quasielastic scattering that does not flatten out up to 360 K, which means that the dynamics of water are much slower than in other matrix materials. Specifically, a single Lorentzian line could be fitted to the quasielastic part of the acquired spectra between 220 and 360 K. This, accompanied by an elastic line from dynamically frozen water present at all experimental temperatures, even above the melting point, signaled a significant amount of bound or slow water.

Citation A.J. Soininen; M.S. Appavou; S. Frykstrand; K. Welch; M. Khaneft; A. Kriele; M.C. Bellissent-Funel; M. Strømme; J. Wuttke.Dynamics of water confined in mesoporous magnesium carbonate.. J Chem Phys. 2016;145(23):234503. doi:10.1063/1.4971285

Related Elements

Magnesium

Magnesium Bohr ModelSee more Magnesium products. Magnesium (atomic symbol: Mg, atomic number: 12) is a Block S, Group 2, Period 3 element with an atomic mass of 24.3050. The number of electrons in each of Magnesium's shells is [2, 8, 2] and its electron configuration is [Ne] 3s2. The magnesium atom has a radius of 160 pm and a Van der Waals radius of 173 pm. Magnesium was discovered by Joseph Black in 1775 and first isolated by Sir Humphrey Davy in 1808. Magnesium is the eighth most abundant element in the earth's crust and the fourth most common element in the earth as a whole. Elemental MagnesiumIn its elemental form, magnesium has a shiny grey metallic appearance and is an extremely reactive. It is can be found in minerals such as brucite, carnallite, dolomite, magnesite, olivine and talc. Commercially, magnesium is primarily used in the creation of strong and lightweight aluminum-magnesium alloys, which have numerous advantages in industrial applications. The name "Magnesium" originates from a Greek district in Thessaly called Magnesia.

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