Electrodeposited-hydroxide surface-covered porous nickel-cobalt alloy electrodes for efficient oxygen evolution reaction.

Title Electrodeposited-hydroxide surface-covered porous nickel-cobalt alloy electrodes for efficient oxygen evolution reaction.
Authors R.K.Vishnu Prataap; S. Mohan
Journal Chem Commun (Camb)
DOI 10.1039/c7cc00712d
Abstract

Herein, we present the electrochemical fabrication of a hydroxide surface-covered nickel-cobalt alloy and its superior catalytic activity towards the electrochemical oxygen evolution reaction in alkaline media. Electrodes were fabricated via the galvanostatic and potentiostatic electrodeposition methods in various electrolytic compositions, in which a nanopyramid-like morphology was obtained under the galvanostatic conditions and a porous structure was obtained under the potentiostatic deposition conditions. The optimized porous electrode shows the overpotential of 1.537 V (? = 307 mV) vs. RHE for the current density of 10 mA cm(-2) in 1 M NaOH solution. Comparatively, the porous Ni-Co alloy electrode exhibits a better performance than the other morphologies obtained in this study. Owing to its highly active surface area with porous structures, it promotes the molecular oxygen evolution reaction.

Citation R.K.Vishnu Prataap; S. Mohan.Electrodeposited-hydroxide surface-covered porous nickel-cobalt alloy electrodes for efficient oxygen evolution reaction.. Chem Commun (Camb). 2017;53(23):33653368. doi:10.1039/c7cc00712d

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

Related Forms & Applications