Enlarge the biologic coating-induced absorbance enhancement of Au-Ag bimetallic nanoshells by tuning the metal composition.

Title Enlarge the biologic coating-induced absorbance enhancement of Au-Ag bimetallic nanoshells by tuning the metal composition.
Authors J. Zhu; X. Li; J.J. Li; J.W. Zhao
Journal Spectrochim Acta A Mol Biomol Spectrosc
DOI 10.1016/j.saa.2017.08.064
Abstract

Surface plasmon resonance (SPR) absorption properties of biologic layer-coated Au-Ag core-shell nanoparticle have been studied theoretically. By comparing with pure Au and Ag nanoparticles, the absorption peak intensity of Au-Ag bimetallic nanoparticle is more dependent on the dielectric coating, and the longer wavelength peak corresponding to the Au-Ag interface is more sensitive to the coating thickness. As the Au-Ag composition ratio is increased, the dielectric coating-dependent peak intensity change is always non-monotonous, and the critical Au-Ag composition ratio corresponding to the greatest peak intensity increase could be further tuned by changing the dielectric constant of the coated dielectric layer. The physical mechanism of the non-monotonous sensitivity change has been attributed to the Au-Ag composition ratio-dependent separation and overlap of the two SPR peaks from Au-Ag interface and outer Ag surface. These results indicate that the plasmonic absorption intensity of Au-Ag core-shell nanoparticle could be used in refractive index sensing and biologic detection.

Citation J. Zhu; X. Li; J.J. Li; J.W. Zhao.Enlarge the biologic coating-induced absorbance enhancement of Au-Ag bimetallic nanoshells by tuning the metal composition.. Spectrochim Acta A Mol Biomol Spectrosc. 2018;189:571577. doi:10.1016/j.saa.2017.08.064

Related Elements

Gold

See more Gold products. Gold (atomic symbol: Au, atomic number: 79) is a Block D, Group 11, Period 6 element with an atomic weight of 196.966569. The number of electrons in each of Gold's shells is 2, 8, 18, 32, 18, 1 and its electron configuration is [Xe]4f142 5d10 6s1. Gold Bohr ModelThe gold atom has a radius of 144 pm and a Van der Waals radius of 217 pm. Gold was first discovered by Early Man prior to 6000 B.C. In its elemental form, gold has a metallic yellow appearance. Gold is a soft metal and is usually alloyed to give it more strength.Elemental Gold It is a good conductor of heat and electricity, and is unaffected by air and most reagents. It is one of the least reactive chemical elements. Gold is often found as a free element and with silver as a gold-silver alloy. Less commonly, it is found in minerals as gold compounds, usually with tellurium.

Silver

See more Silver products. Silver (atomic symbol: Ag, atomic number: 47) is a Block D, Group 11, Period 5 element with an atomic weight of 107.8682. Silver Bohr ModelThe number of electrons in each of Silver's shells is 2, 8, 18, 18, 1 and its electron configuration is [Kr]4d10 5s1. The silver atom has a radius of 144 pm and a Van der Waals radius of 203 pm. Silver was first discovered by Early Man prior to 5000 BC. In its elemental form, silver has a brilliant white metallic luster. Elemental SilverIt is a little harder than gold and is very ductile and malleable, being exceeded only by gold and perhaps palladium. Pure silver has the highest electrical and thermal conductivity of all metals and possesses the lowest contact resistance. It is stable in pure air and water, but tarnishes when exposed to ozone, hydrogen sulfide, or air containing sulfur. It is found in copper, copper-nickel, lead, and lead-zinc ores, among others. Silver was named after the Anglo-Saxon word "seolfor" or "siolfur," meaning 'silver'.

Related Forms & Applications