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Erbium(III) Hexafluoroacetylacetonate Hydrate

Er(III)(tfc)3

CAS #:

Linear Formula:

Er(CF3COCHCOCF3)3• xH2O

MDL Number:

MFCD03427337

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Erbium(III) Hexafluoroacetylacetonate Hydrate
ER-FACA-02-C.XHYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Erbium(III) Hexafluoroacetylacetonate Hydrate
ER-FACA-03-C.XHYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Erbium(III) Hexafluoroacetylacetonate Hydrate
ER-FACA-04-C.XHYD
Pricing > SDS > Data Sheet >

Erbium(III) Hexafluoroacetylacetonate Hydrate Properties (Theoretical)

Compound Formula C15H8ErF18O7
Molecular Weight 809.45
Appearance Pink crystals
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O Insoluble
Exact Mass 807.928554 g/mol

Erbium(III) Hexafluoroacetylacetonate Hydrate Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Precautionary Statements P262-P280-P305+P351+P338-P304+P340-P403+P233-P422-P501
Risk Codes N/A
Safety Statements N/A
Transport Information NONH for all modes of transport

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/19/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Erbium(III) Hexafluoroacetylacetonate Hydrate

Product Number: All applicable American Elements product codes, e.g. ER-FACA-02-C.XHYD 02 , ER-FACA-03-C.XHYD 03 , ER-FACA-04-C.XHYD 04

CAS #: 18923-92-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
d~GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).

Exclamation Mark - GHS07

Hazard pictograms
d~GHS07
Signal word Warning
Hazard-determining components of labeling:
Erbium(III) hexafluoroacetylacetonate hydrate (99.9%-Er) (REO)
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
1


Health = 1
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
1


Health = 1
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS # / Substance Name
18923-92-7 Erbium(III) hexafluoroacetylacetonate hydrate (99.9%-Er)
(REO)


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled: In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact: Immediately wash with soap and water; rinse thoroughly.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed: If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No data available
Advice for firefighters
Protective equipment: No special measures required.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions: No special measures required.
Methods and materials for containment and cleanup:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling:
Precautions for safe handling No special precautions are necessary if used correctly.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
SProtective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
RTightly sealed goggles


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Crystalline
Color: Pink
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: no data °C
Boiling point/Boiling range: no data °C
Flash point: N/A
Flammability (solid, gas): Product is not flammable.
Ignition temperature:
Decomposition temperature: No data available.
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: no data hPa
Density: No data available.
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water: Insoluble.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Solids content: 100.0 %
Other information No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No data available
Incompatible materials: No data available
Hazardous decomposition products: No dangerous decomposition products known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Behavior in environmental systems:
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information: Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user N/A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code N/A
UN "Model Regulation": not regulated


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
Substance is not listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
d~GHS07
Signal word Warning
Hazard-determining components of labeling:
Erbium(III) hexafluoroacetylacetonate hydrate (99.9%-Er) (REO)
Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Erbium(III) Hexafluoroacetylacetonate Hydrate

Erbium(III) Hexafluoroacetylacetonate Hydrate is one of numerous organometallic compounds sold by American Elements under the trade name AE Organometallics™. Organometallics are useful reagent, catalyst, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. American Elements supplies Erbium(III) Hexafluoroacetylacetonate Hydrate in most volumes including bulk quantities and also can produce materials to customer specifications. Please request a quote above for more information on pricing and lead time.

Erbium(III) Hexafluoroacetylacetonate Hydrate Synonyms

Erbium hexafluoropentanedionate hydrate; erbium hexafluoro-2,4-pentanedionate hydrate; Hexafluoroacetylacetono erbium(III) salt hydrate; erbium hexafluoroacetylacetonate hydrate, erbium(III) tris(1,1,1-hexafluoro-4-oxo-2-pentene-2-olate) hydrate

Chemical Identifiers

Linear Formula Er(CF3COCHCOCF3)3• xH2O
MDL Number MFCD03427337
EC No. N/A
Pubchem CID 72376405
IUPAC Name erbium; (Z)-1,1,1,5,5,5-hexafluoro-4-hydroxypent-3-en-2-one; hydrate
SMILES C(=C(C(F)(F)F)O)C(=O)C(F)(F)F.C(=C(C(F)(F)F)O)C(=O)C(F)(F)F.C(=C(C(F)(F)F)O)C(=O)C(F)(F)F.O.[Er]
InchI Identifier InChI=1S/3C5H2F6O2.Er.H2O/c3*6-4(7,8)2(12)1-3(13)5(9,10)11;;/h3*1,12H;;1H2/b3*2-1-;;
InchI Key WLJRJAVIMPXKRE-AHUNZLEGSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Erbium products. Erbium (atomic symbol: Er, atomic number: 68) is a Block F, Group 3, Period 6 element with an atomic radius of 167.259. Erbium Bohr Modelhe number of electrons in each of Erbium's shells is [2, 8, 18, 30, 8, 2] and its electron configuration is [Xe]4f12 6s2. The erbium atom has a radius of 176 pm and a Van der Waals radius of 235 pm. Erbium was discovered by Carl Mosander in 1843. Sources of Erbium include the mineral monazite and sand ores. Erbium is a member of the lanthanide or rare earth series of elements.Elemental Erbium Picture In its elemental form, erbium is soft and malleable it is fairly stable in air and does not oxidize as rapidly as some of the other rare earth metals. Erbiums ions fluoresce in a bright pink color, making them highly useful for imaging and optical applications. It is named after the Swedish town, Ytterby where it was first discovered.

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

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