Graphene-like boron nitride modified bismuth phosphate materials for boosting photocatalytic degradation of enrofloxacin.

Title Graphene-like boron nitride modified bismuth phosphate materials for boosting photocatalytic degradation of enrofloxacin.
Authors Z. Chen; X. Chen; J. Di; Y. Liu; S. Yin; J. Xia; H. Li
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2016.12.050
Abstract

A novel graphene-like BN modified BiPO4 material was prepared for the first time via a simple solvothermal process with the assistance of reactable ionic liquid 1-decyl-3-methylimidazolium dihydrogen phosphate ([Omim]H2PO4). The as-prepared photocatalyst was characterized by XRD, FT-IR, Raman, XPS, TEM, DRS, BET, PL, EIS and ESR to investigate the structure, morphology, optical property, surface area, electrical property and active species. The photocatalytic activities of graphene-like BN/BiPO4 materials were evaluated by the degradation of antibiotic enrofloxacin (ENR) under UV light irradiation and the 1wt% graphene-like BN/BiPO4 displayed the best activity among the BN/BiPO4 composites. The enhanced photocatalytic activity for the removal of enrofloxacin was attributed to higher separation efficiency of photogenerated electron-hole pairs, and the generated more O2(-) and OH radicals when the BN was modified on BiPO4. Moreover, a probable degradation mechanism was proposed for the improved photocatalytic activity of BN modified BiPO4.

Citation Z. Chen; X. Chen; J. Di; Y. Liu; S. Yin; J. Xia; H. Li.Graphene-like boron nitride modified bismuth phosphate materials for boosting photocatalytic degradation of enrofloxacin.. J Colloid Interface Sci. 2017;492:5160. doi:10.1016/j.jcis.2016.12.050

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Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

Boron

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808 and was first isolated by Humphry Davy later that year. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

Phosphorus

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Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Carbon

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