Green synthesis of a novel flower-like cerium vanadate microstructure for electrochemical detection of tryptophan in food and biological samples.

Title Green synthesis of a novel flower-like cerium vanadate microstructure for electrochemical detection of tryptophan in food and biological samples.
Authors V. Kumar; R. Karthik; S.M. Chen; S. Marikkani; A. Elangovan; V. Muthuraj
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2017.02.009
Abstract

In this present investigation, we introduced a novel electrochemical sensor for the detection of tryptophan (TRP) based on green pompoms flower-like cerium vanadate (CeVO4). The flower-like CeVO4 microstructure was prepared by the simple hydrothermal treatment with the assistance of urea for the first time. The as-prepared flower-like CeVO4 microstructure was characterized by various analytical and spectroscopic techniques such as X-ray diffraction, Raman spectroscopy fourier transform infrared spectroscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy studies. The electrochemical properties are evaluated by the cyclic voltammetry (CV) and differential pulse voltammetry (DPV). As an electrochemical sensor, the green pompoms flower-like CeVO4 modified glassy carbon electrode (GCE) displayed an excellent electrocatalytic activity for the detection of TRP. The obtained electrochemical results revealed that the oxidation of TRP, exhibited a lower potential and higher anodic peak current when compared to unmodified GCE. These results were suggested that the flower-like CeVO4/GCE have a good electrocatalytic activity towards the TRP oxidation. The flower-like CeVO4 sensor exhibited the wide linear concentration range and low detection limit of 0.1-94µM and 0.024µM respectively. Finally, the proposed sensor was successfully applied to the determination of TRP in real sample analysis such as food and biological samples with satisfied recoveries.

Citation V. Kumar; R. Karthik; S.M. Chen; S. Marikkani; A. Elangovan; V. Muthuraj.Green synthesis of a novel flower-like cerium vanadate microstructure for electrochemical detection of tryptophan in food and biological samples.. J Colloid Interface Sci. 2017;496:7886. doi:10.1016/j.jcis.2017.02.009

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Cerium

See more Cerium products. Cerium (atomic symbol: Ce, atomic number: 58) is a Block F, Group 3, Period 6 element with an atomic weight of 140.116. The number of electrons in each of cerium's shells is 2, 8, 18, 19, 9, 2 and its electron configuration is [Xe]4f2 6s2. Cerium Bohr ModelThe cerium atom has a radius of 182.5 pm and a Van der Waals radius of 235 pm. In its elemental form, cerium has a silvery white appearance. Cerium is the most abundant of the rare earth metals. It is characterized chemically by having two valence states, the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. Elemental CeriumIt is therefore strongly acidic and oxidizing, in addition to being moderately toxic.The cerous state closely resembles the other trivalent rare earths. Cerium is found in the minerals allanite, bastnasite, hydroxylbastnasite, monazite, rhabdophane, synchysite and zircon. Cerium was discovered by Martin Heinrich Klaproth, Jöns Jakob Berzelius, and Wilhelm Hisinger in 1803 and first isolated by Carl Gustaf Mosander in 1839. The element was named after the asteroid Ceres, which itself was named after the Roman god of agriculture.

Vanadium

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