Heterogeneous sonocatalytic degradation of anazolene sodium by synthesized dysprosium doped CdSe nanostructures.

Title Heterogeneous sonocatalytic degradation of anazolene sodium by synthesized dysprosium doped CdSe nanostructures.
Authors A. Khataee; F.Toutounchi Mohamadi; T.Sadeghi Rad; B. Vahid
Journal Ultrason Sonochem
DOI 10.1016/j.ultsonch.2017.07.021
Abstract

Undoped and Dy-doped CdSe nanoparticles are synthesized and then characterized by the SEM, XRD, FT-IR, XPS and BET methods, which verify successful preparation of the doped catalyst. The sonocatalytic degradation of anazolene sodium as a model azo dye is higher than sonolysis process and the 2% Dy-doped CdSe with band gap of 1.42eV exhibits the greatest sonocatalytic performance. The decolorization efficiency (DE%) of sonocatalysis with 2% Dy-doped CdSe, undoped CdSe and sonolysis after 90min of the process is 91.32%, 56.13% and 39.14%, respectively. In addition, the sonocatalytic degradation of anazolene sodium increases with enhancement of the dopant, catalyst dosage, ultrasonic power, dissolved gasses and decreasing of initial anazolene sodium concentration. Furthermore, with addition of chloroform, sulfate, chloride and ethanol as the radical scavengers, the DE% decreases indicating the controlling mechanism of free radicals for the dye degradation. Besides, the results reveal the appropriate reusability of the catalyst and various degradation by-products are identified using the GC-MS technique. Eventually, the empirical kinetic model is expanded by nonlinear regression analysis for prediction of pseudo first-order constants in various operational conditions.

Citation A. Khataee; F.Toutounchi Mohamadi; T.Sadeghi Rad; B. Vahid.Heterogeneous sonocatalytic degradation of anazolene sodium by synthesized dysprosium doped CdSe nanostructures.. Ultrason Sonochem. 2018;40(Pt A):361372. doi:10.1016/j.ultsonch.2017.07.021

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Dysprosium

See more Dysprosium products. Dysprosium (atomic symbol: Dy, atomic number: 66) is a Block F, Group 3, Period 6 element with an atomic radius of 162.5. Dysprosium Bohr ModelThe number of electrons in each of dysprosium's shells is [2, 8, 18, 28, 8, 2] and its electron configuration is [Xe]4f10 6s2. The dysprosium atom has an atomic radius of 178 pm and a Van der Waals radius of 229 pm. Dysprosium was first discovered by Paul Emile Lecoq de Boisbaudran in 1886. In its elemental form, dysprosium has a silvery-white appearance. Elemental Dysprosium PictureIt is a member of the lanthanide or rare earth series of elements and, along with holmium, has the highest magnetic strength of all other elements on the periodic table, especially at low temperatures. Dysprosium is found in various minerals including bastnäsite, blomstrandine, euxenite, fergusonite, gadolinite, monazite, polycrase and xenotime. It is not found in nature as a free element. The element name originates from the Greek word dysprositos, meaning hard to get at.

Selenium

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Sodium

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