Hierarchically Structured Macro with Nested Mesoporous Zinc Indium Oxide Conducting Film.

Title Hierarchically Structured Macro with Nested Mesoporous Zinc Indium Oxide Conducting Film.
Authors S. Bera; M. Pal; S. Sarkar; S. Jana
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.6b13143
Abstract

Fabrication of homogeneously distributed (HD) macropores by breath figure process is an active research area. Adopting the process, for the first time, we report the fabrication of HD macro with nested meso (hierarchical) porous nanocrystalline zinc indium oxide conducting sol-gel thin film on glass by dip-coating at 45-50% room relative humidity (RH) from a solution in ethanol-2-butanol (1:1, w/w) medium with a 1:1, Zn:In ratio. In this process, solution composition and RH are found to play key roles on HD macropore generation. The film is highly promising toward visible-light-driven photoelectrochemical water splitting.

Citation S. Bera; M. Pal; S. Sarkar; S. Jana.Hierarchically Structured Macro with Nested Mesoporous Zinc Indium Oxide Conducting Film.. ACS Appl Mater Interfaces. 2017;9(5):44204424. doi:10.1021/acsami.6b13143

Related Elements

Indium

See more Indium products. Indium (atomic symbol: In, atomic number: 49) is a Block P, Group 13, Period 5 element with an atomic weight of 114.818. The number of electrons in each of indium's shells is [2, 8, 18, 18, 3] and its electron configuration is [Kr] 4d10 5s2 5p1. The indium atom has a radius of 162.6 pm and a Van der Waals radius of 193 pm. Indium was discovered by Ferdinand Reich and Hieronymous Theodor Richter in 1863. Indium Bohr ModelIt is a relatively rare, extremely soft metal is a lustrous silvery gray and is both malleable and easily fusible. It has similar chemical properties to Elemental Indiumgallium such as a low melting point and the ability to wet glass. Fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium, especially in the form of Indiun Tin Oxide (ITO). Thin films of Copper Indium Gallium Selenide (CIGS) are used in high-performing solar cells. Indium's name is derived from the Latin word indicum, meaning violet.

Zinc

See more Zinc products. Zinc (atomic symbol: Zn, atomic number: 30) is a Block D, Group 12, Period 4 element with an atomic weight of 65.38. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d10 4s2. Zinc Bohr ModelThe zinc atom has a radius of 134 pm and a Van der Waals radius of 210 pm. Zinc was discovered by Indian metallurgists prior to 1000 BC and first recognized as a unique element by Rasaratna Samuccaya in 800. Zinc was first isolated by Andreas Marggraf in 1746. In its elemental form, zinc has a silver-gray appearance. It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C.Elemental Zinc It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. It is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). The name zinc originates from the German word "zin," meaning tin.

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