Indium Acetylacetonate

CAS #

In(C5H7O2)3

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SAFETY DATA TECHNICAL DATA
(2N) 99% Indium Acetylacetonate IN-ACAC-02 Pricing
(3N) 99.9% Indium Acetylacetonate IN-ACAC-03 Pricing
(4N) 99.99% Indium Acetylacetonate IN-ACAC-04 Pricing
(5N) 99.999% Indium Acetylacetonate IN-ACAC-05 Pricing

Properties

Compound Formula C15H21InO6
Molecular Weight 412.15
Appearance White to light yellow powder
Melting Point 187-189 °C
Boiling Point N/A
Density N/A
Monoisotopic Mass 412.037691
Exact Mass 412.037691

Health & Safety Information

Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335-H351
Hazard Codes Xn
Risk Codes 20/21/22-36/37/38-40
Safety Statements 26-36
RTECS Number NL2025000
Transport Information N/A
WGK Germany 3

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SAFETY DATA SHEET

Date Accessed: 04/30/2016
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Indium Acetylacetonate

Product Number: All applicable American Elements product codes, e.g. IN-ACAC-02, IN-ACAC-03, IN-ACAC-04, IN-ACAC-05

CAS #: 14405-45-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

OSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 4] Acute Toxicity - Dermal [Category 4] Acute Toxicity - Inhalation [Category 4] Sensitization - Skin [Category 1] Specific Target Organ Toxicity (Single Exposure) [Category 3] Signal word: Warning! Hazard Statement(s): Harmful if swallowed Harmful in contact with skin Harmful if inhaled May cause an allergic skin reaction May cause respiratory irritation.
Exclamation Mark - GHS07
Pictogram(s) or Symbol(s): Precautionary Statement(s): [Prevention] Do not eat, drink or smoke when using this product. Wash hands and face thoroughly after handling. Wear protective gloves and protective clothing. Avoid breathing dusts or mists. Use only outdoors or in a wellventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. [Response] If swallowed: Immediately call a poison center or doctor. Rinse mouth. If on skin: Wash with plenty of water. Call a poison center or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. [Storage] Store in a well-ventilated place. Keep container tightly closed. Store locked up. [Disposal] Dispose of contents and container in accordance with US EPA guidelines for the classification and determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance/Mixture: Substance Components: Tris(2,4-pentanedionato)indium(III) Percent: >99.0%(T) CAS Number: 14405-45-9 Molecular Weight: 412.15 Chemical Formula: C15H21InO6 Synonyms: Acetylacetone Indium(III) Salt , Indium(III) Acetylacetonate

SECTION 4. FIRST AID MEASURES

Inhalation: May cause coughing, difficult breathing and nausea. Call a poison center or doctor if you feel unwell. Effects of exposure (inhalation) to substance may be delayed. Inhalation of vapors or contact with substance will result in contamination and potential harmful effects. Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Keep victim warm and quiet. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Skin contact: Call a poison center or doctor if you feel unwell. Effects of exposure (skin contact) to substance may be delayed. Remove and wash contaminated clothing before re-use. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Eye contact: If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper eyelids. If eye irritation persists get medical advice/attention. Move victim to fresh air. Check for and remove any contact lenses. Keep victim warm and quiet. Treat symptomatically and supportively. Effects of exposure to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Ingestion: Harmful if swallowed. Effects of exposure (ingestion) to substance may be delayed. Call a physician or Poison Control Center immediately. Do not use mouth-to-mouth method if victim ingested the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Loosen tight clothing such as a collar, tie, belt or waistband. If a person vomits place them in the recovery position so that vomit will not reenter the mouth and throat. Rinse mouth. Keep victim warm and quiet. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Symptoms/effects: Acute: No data available Delayed: May cause skin sensitization. May have effects on the respiratory tract. Immediate medical attention: WARNING: It might be hazardous to the person providing aid to give mouth-to-mouth respiration, because the inhaled material is harmful. CAUTION: Victim may be a source of contamination. If breathing has stopped, perform artificial respiration. Use first aid treatment according to the nature of the injury. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media: Dry chemical, CO2 , water spray, or alcohol-resistant foam. Consult with local fire authorities before attempting large scale fire fighting operations. Specific hazards arising from the chemical Hazardous combustion products: These products include: Carbon oxides Other specific hazards: Closed containers may explode from heat of a fire. Special precautions for fire-fighters: Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. Containers may explode when heated. Move containers from fire area if you can do it without risk. Special protective equipment for fire-fighters: Wear positive pressure self-contained breathing apparatus (SCBA). Structural fire fighters' protective clothing provides limited protection in fire situations ONLY; it may not be effective in spill situations. Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid contact with skin, eyes, and clothing. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing (Section 8). Warn unnecessary personnel to move away. Stop leak if you can do it without risk. Ensure adequate ventilation. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Personal protective equipment: Splash goggles. Wear protective clothing (chemical resistant suit and chemical resistant boots). Dust respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Wear protective gloves (nitrile). Emergency procedures: Prevent dust cloud. Do not clean-up or dispose except under supervision of a specialist. In case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and excercise caution. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Warn personnel to move away. Prevent entry into sewers, basements or confined areas; dike if needed. Methods and materials for containment and cleaning up: ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if without risk. Ventilate the area. Absorb with an inert material and put the spilled material in an appropriate waste disposal container. Use clean non-sparking tools to collect absorbed material. Environmental precautions: Keep away from living quarters. Prevent further leakage or spillage if safe to do so. Water runoff can cause environmental damage. Prevent entry into sewers, basements or confined areas; dike if needed.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling: Avoid inhalation of vapor or mist. Do not ingest. Avoid contact with skin and eyes. Avoid contact with skin. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Keep container dry. Handle and open container with care. Wear suitable protective clothing, gloves and eye/face protection. When using do not eat, drink, or smoke. Keep away from sources of ignition. Conditions for safe storage: Store locked up. Keep containers tightly closed in a cool, well-ventilated place. Keep away from incompatibles. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Avoid prolonged storage periods. Storage incompatibilities: Store away from oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limits: OSHA PEL (TWA): 0.1 mg (In)/m3 Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Ventilation is normally required when handling or using this product. Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance. Follow safe industrial engineering/laboratory practices when handling any chemical. Personal protective equipment Respiratory protection: Dust respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Hand protection: Nitrile gloves. Eye protection: Safety glasses. Skin and body protection: Lab coat.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state (20°C): Solid Form: Crystal - Powder Color: White - Slightly pale yellow Odor: No data available Odor threshold: No data available Melting point/freezing point: 186°C (367°F) Boiling point/range: No data available Decomposition temperature: No data available Relative density: No data available Kinematic Viscosity: No data available Partition coefficient: No data available n-octanol/water (log Pow) Flash point: 180°C (356°F) Flammability (solid, gas): No data available pH: No data available Vapor pressure: No data available Vapor density: No data available Dynamic Viscosity: No data available Evaporation rate: No data available (Butyl Acetate = 1) Autoignition temperature: No data available Flammability or explosive limits: No data available Lower: No data available Upper: No data available Solubility(ies): Water: Insoluble Soluble: Methanol, Benzene, Acetone, Chloroform, Toluene

SECTION 10. STABILITY AND REACTIVITY

Reactivity: Not Available. Chemical Stability: Stable under recommended storage conditions. (See Section 7) Possibility of Hazardous Reactions: No hazardous reactivity has been reported. Conditions to avoid: Avoid excessive heat and light. Incompatible materials: Strong oxidizing agents Hazardous Decomposition Products: No data available

SECTION 11. TOXICOLOGICAL INFORMATION

RTECS Number: NL2025000 Acute Toxicity: ivn-mus LD50:79 mg/kg Skin corrosion/irritation: No data available Serious eye damage/irritation: No data available Respiratory or skin sensitization: No data available Germ cell mutagenicity: No data available Carcinogenicity: No data available IARC: No data available NTP: No data available OSHA: No data available Reproductive toxicity: No data available Routes of Exposure: Inhalation, Eye contact, Ingestion, Skin contact. Symptoms related to exposure: Overexposure may result in serious illness or death. Skin contact may result in sensitization. Readily absorbed through skin. Inhalation causes irritation of the lungs and respiratory system. Potential Health Effects: Inhalation causes irritation of the lungs and respiratory system. Target organ(s): May cause respiratory irritation.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity Fish: No data available Crustacea: No data available Algae: No data available Persistence and degradability: No data available Bioaccumulative potential (BCF): No data available Mobillity in soil: No data available Partition coefficient: n-octanol/water (log Pow) No data available Soil adsorption (Koc): No data available Henry's Law: constant (PaM3/mol) No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal of product: Recycle to process if possible. It is the generator's responsibility to comply with Federal, State and Local rules and regulations. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. This section is intended to provide assistance but does not replace these laws, nor does compliance in accordance with this section ensure regulatory compliance according to the law. US EPA guidelines for Identification and Listing of Hazardous Waste are listed in 40 CFR Parts 261. The product should not be allowed to enter the environment, drains, water ways, or the soil. Disposal of container: Dispose of as unused product. Do not re-use empty containers. Other considerations: Observe all federal, state and local regulations when disposing of the substance.

SECTION 14. TRANSPORT INFORMATION

DOT (US) Non-hazardous for transportation. IATA Non-hazardous for transportation. IMDG Non-hazardous for transportation.

SECTION 15. REGULATORY INFORMATION

Toxic Substance Control Act (TSCA 8b.): This product is ON the EPA Toxic Substances Control Act (TSCA) inventory. US Federal Regulations CERCLA Hazardous substance and Reportable Quantity: SARA 313: Not Listed SARA 302: Not Listed State Regulations State Right-to-Know Massachusetts Not Listed New Jersey Not Listed Pennsylvania Not Listed California Proposition 65: Not Listed Other Information NFPA Rating: Health: 2 Flammability: 1 Instability: 0 HMIS Classification: Health: 2 Flammability: 1 Physical: 0 International Inventories WHMIS hazard class: D2A: Materials causing other toxic effects. (Very Toxic) D2B: Materials causing other toxic effects. (Toxic) Canada: NDSL On NDSL EC-No: 238-378-6

16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Indium Acetylacetonate is a Indium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Indium Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Indium include making bearing alloys, germanium transistors, rectifiers, and photoconductors. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Indium(III) acetylacetonate; 2, 4-Pentanedione indium(III) derivative; In(acac)3; Indium(III) 2, 4-pentanedionate; Indium tris[(2Z)-4-oxopent-2-en-2-olate]; (z)-4-bis[(z)-1-methyl-3-oxobut-1-enoxy]indiganyloxypent-3-en-2-one

Chemical Identifiers

Formula In(C5H7O2)3
CAS 14405-45-9
Pubchem CID 16687813
MDL MFCD00013494
EC No. 238-378-6
IUPAC Name (z)-4-bis[(z)-1-methyl-3-oxobut-1-enoxy]indiganyloxypent-3-en-2-one
SMILES [In+3].O=C(/C=C(\[O-])C)C.[O-]\C(=C/C(=O)C)C.[O-]\C(=C/C(=O)C)C
InchI Identifier InChI=1S/3C5H8O2.In/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InchI Key SKWCWFYBFZIXHE-LNTINUHCSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

See more Indium products. Indium (atomic symbol: In, atomic number: 49) is a Block P, Group 13, Period 5 element with an atomic weight of 114.818. The number of electrons in each of indium's shells is [2, 8, 18, 18, 3] and its electron configuration is [Kr] 4d10 5s2 5p1. The indium atom has a radius of 162.6 pm and a Van der Waals radius of 193 pm. Indium was discovered by Ferdinand Reich and Hieronymous Theodor Richter in 1863. Indium Bohr ModelIt is a relatively rare, extremely soft metal is a lustrous silvery gray and is both malleable and easily fusible. It has similar chemical properties to Elemental Indiumgallium such as a low melting point and the ability to wet glass. Fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium, especially in the form of Indiun Tin Oxide (ITO). Thin films of Copper Indium Gallium Selenide (CIGS) are used in high-performing solar cells. Indium's name is derived from the Latin word indicum, meaning violet.

Recent Research

Effects of a powered air-purifying respirator intervention on indium exposure reduction and indium related biomarkers among ITO sputter target manufacturing workers., Liu, Hung-Hsin, Chen Chang-Yuh, Lan Cheng-Hang, Chang Cheng-Ping, and Peng Chiung-Yu , J Occup Environ Hyg, 2016 May, Volume 13, Issue 5, p.346-55, (2016)

Effect of organic solar cells using various power O2 plasma treatments on the indium tin oxide substrate., Ke, Jhong-Ciao, Wang Yeong-Her, Chen Kan-Lin, and Huang Chien-Jung , J Colloid Interface Sci, 2016 Mar 1, Volume 465, p.311-5, (2016)

Pulse electrodeposited nickel-indium tin oxide nanocomposite as an electrocatalyst for non-enzymatic glucose sensing., Sivasakthi, P, Bapu G N. K. Ramesh, and Chandrasekaran Maruthai , Mater Sci Eng C Mater Biol Appl, 2016 Jan 1, Volume 58, p.782-9, (2016)

Indium acetate toxicity in male reproductive system in rats., Lee, Kuo-Hsin, Chen Hsiu-Ling, Leung Chung-Man, Chen Hsin-Pao, and Hsu Ping-Chi , Environ Toxicol, 2016 Jan, Volume 31, Issue 1, p.68-76, (2016)

Utility of indium-111 octreotide to identify a cardiac metastasis of a carcinoid neoplasm., Farooqui, Mohammed, Rathore Sulaiman, and Ball Timothy , Proc (Bayl Univ Med Cent), 2016 Jan, Volume 29, Issue 1, p.76-8, (2016)

Investigation of activation cross sections of proton induced reactions on indium up to 70MeV for practical applications., Tárkányi, F, Ditrói F, Hermanne A, Takács S, and Baba M , Appl Radiat Isot, 2016 Jan, Volume 107, p.391-400, (2016)

Fabrication of Metal-Deposited Indium Tin Oxides: Its Applications to 385 nm Light-Emitting Diodes., Kim, Min Ju, and Kim Tae Geun , ACS Appl Mater Interfaces, 2016 Feb 9, (2016)

Core-shell Vanadium Modified Titania@β-In2S3 Hybrid Nanorod Arrays for Superior Interface Stability and Photochemical Activity., Mumtaz, Asad, Mohamed Norani Muti, Mazhar Muhammad, Ehsan Muhammad Ali, and Saheed Mohamed Shuaib Moh , ACS Appl Mater Interfaces, 2016 Feb 8, (2016)

High-Throughput Synthesis, Screening, and Scale-Up of Optimized Conducting Indium Tin Oxides., Marchand, Peter, Makwana Neel M., Tighe Christopher J., Gruar Robert I., Parkin Ivan P., Carmalt Claire J., and Darr Jawwad A. , ACS Comb Sci, 2016 Feb 8, Volume 18, Issue 2, p.130-7, (2016)