Indium triflate catalysed 3-aza-Cope rearrangement of amino acid derived ?,?-unsaturated esters to alkylidene oxindoles.

Title Indium triflate catalysed 3-aza-Cope rearrangement of amino acid derived ?,?-unsaturated esters to alkylidene oxindoles.
Authors S.Lavanya Kumar; S.Kumar Manna; S. Maji; G. Panda
Journal Org Biomol Chem
DOI 10.1039/c6ob02419j
Abstract

The first examples of amino acid derived ?,?-unsaturated esters to Z-alkylidene oxindoles via 3-aza-Cope rearrangement using In(OTf)3 are reported.

Citation S.Lavanya Kumar; S.Kumar Manna; S. Maji; G. Panda.Indium triflate catalysed 3-aza-Cope rearrangement of amino acid derived ?,?-unsaturated esters to alkylidene oxindoles.. Org Biomol Chem. 2017;15(8):17621766. doi:10.1039/c6ob02419j

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Fluorine

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

Sulfur

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