Intense 2.7?m emission in Er(3+) doped zinc fluoride glass.

Title Intense 2.7?m emission in Er(3+) doped zinc fluoride glass.
Authors F. Huang; Y. Guo; Y. Tian; S. Xu; J. Zhang
Journal Spectrochim Acta A Mol Biomol Spectrosc
DOI 10.1016/j.saa.2017.02.020
Abstract

A novel erbium ion doped zinc fluoride glass was prepared. 2.7?m emission and transmittance properties together with thermal ability were investigated. An enhanced 2.7?m emission was observed by introducing ZnF2 in the ZrF4-based fluoride glass. Meanwhile, the J-O parameters and branching ratios (?) of Er(3+)-doped zinc fluoride glass were calculated and analyzed. The present Er(3+)-doped zinc fluoride glass with large emission cross-section (0.92×10(-20)cm(2)) and long decay lifetime (2.05ms) at 2.7?m indicates that it have very promising applications for solid state lasers around 3?m.

Citation F. Huang; Y. Guo; Y. Tian; S. Xu; J. Zhang.Intense 2.7?m emission in Er(3+) doped zinc fluoride glass.. Spectrochim Acta A Mol Biomol Spectrosc. 2017;179:4245. doi:10.1016/j.saa.2017.02.020

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Fluorine

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

Zinc

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