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Lead(II) Fluoride

CAS #:

Linear Formula:

PbF2

MDL Number:

MFCD00011162

EC No.:

231-998-8

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Lead(II) Fluoride
PB2-F-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Lead(II) Fluoride
PB2-F-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Lead(II) Fluoride
PB2-F-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Lead(II) Fluoride
PB2-F-05
Pricing > SDS > Data Sheet >

Lead(II) Fluoride Properties

Compound Formula

F2Pb

Molecular Weight

245.2

Appearance

White to colorless crystals

Melting Point

824° C (1,515° F)

Boiling Point

1,293° C (2,359° F)

Density

8.445 g/cm3

Exact Mass

245.973 g/mol

Monoisotopic Mass

245.973 g/mol

Charge

N/A

Lead(II) Fluoride Health & Safety Information

Signal Word Danger
Hazard Statements H302 + H332-H310-H360Df-H373-H410
Hazard Codes T,N
Precautionary Statements P201-P260-P280-P301 + P312 + P330-P302 + P352 + P310-P308 + P313
Risk Codes 61-20/22-33-50/53-62
Safety Statements 53-45-60-61
RTECS Number OG1225000
Transport Information UN 2291 6.1 / PGIII
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/24/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lead(II) Fluoride

Product Number: All applicable American Elements product codes, e.g. PB2-F-02 , PB2-F-03 , PB2-F-04 , PB2-F-05

CAS #: 7783-46-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Xn If swallowed causes nausea, vomiting, stomach pains and diarrhoea. Also harmful in contact with skin. Particular care must be exercised when machining and creating dust or particles.
Class 6.1 Poison

Exclamation Mark - GHS07 Health Hazard - GHS08 Environment - GHS09

Signal: Warning
H302 Harmful if swallowed.
H332 Harmful if inhaled.
Signal: Health Hazard
H360 May damage fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
Signal: Environment
H410 Very toxic to aquatic life with long lasting effects.
Prevention:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when handling this product
Response:
P301+P310 IF SWALLOWED: Immediately call a poison centre or doctor. Rinse mouth.
P304+P312 IF INHALED: Call a poison centre or doctor/physician if you feel unwell.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENT NAME CAS number % EC number (EINECS) EU index UN number
Lead Fluoride 7783-46-2 100% 231-998-8 082-001-00-6 2291


SECTION 4. FIRST AID MEASURES

EYES: Irrigate thoroughly with water for at least 15 minutes. Obtain medical attention.
SKIN: Wash off thoroughly with soap and water. Gently dry area with clean towel. Remove contaminated clothing and wash clothing before re-use.
INHALATION: Remove to uncontaminated area. Perform artificial respiration if breathing has stopped. When breathing is difficult, properly trained personnel may administer oxygen. Keep affected person warm and at rest. Obtain medical attention.
INGESTION: Induce vomiting if conscious and as directed by a properly qualified personnel. Wash out mouth thoroughly with water. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS. Obtain Medical Attention Immediately!


SECTION 5. FIREFIGHTING MEASURES

FLASH POINT: Not Ignitable. Not Applicable
EXTINGUISHING MEDIA: Water, CO2, foam or dry chemical.
UNUSUAL FIRE HAZARDS: May evolve toxic fumes in a fire.


SECTION 6. ACCIDENTAL RELEASE MEASURES

CONTAMINATION CLEANUP: Wear suitable protective clothing & equipment as listed under Exposure / Personal protection. Take up and containerize for proper disposal. Avoid making dust. Containerize any cleaning materials used for proper disposal.


SECTION 7. HANDLING AND STORAGE

USAGE PRECAUTIONS: Keep away from heat. Avoid skin contact. Protect against physical damage and avoid generating dust.
STORAGE PRECAUTIONS: Keep away from foodstuffs.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Protective gloves made of nitrile rubber (0.11mm) are required. Use of a laboratory coat is suggested. Safety goggles or safety glasses with side shields are required if there is any possibility of chipping or dust creation. Respirators must be worn when the threshold limit is exceeded. Provide adequate general mechanical ventilation, and local exhaust ventilation.
OCCUPATIONAL EXPOSURE LIMITS (OEL) =0.15 mg/m3 as Lead in 8 hour Time Weighted Average (TWA)


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Clear glassy geometric shapes, no odour.
pH IN AQUEOUS SOLUTION: Not determined
BOILING POINT (760mm Hg) 1293C
MELTING POINT: 824C
FLASH POINT: Not Applicable
FLAMMABILITY: Not Applicable
EXPLOSIVE PROPERTIES: Not Applicable
SPECIFIC GRAVITY: 7.75
VAPOUR PRESSURE: Not Applicable
SOLUBILITY IN WATER: Slightly soluble; 65mg/100ml H2O at 20C


SECTION 10. STABILITY AND REACTIVITY

STABILITY: Stable under normal conditions of storage and use.
HAZARDOUS DECOMPOSITION: Liberates toxic hydrogen fluoride gas in contact with mineral acid.
MATERIALS TO AVOID: Acids, Oxidisers, Concentrated Hot Sulphuric Acid


SECTION 11. TOXICOLOGICAL INFORMATION

TOXIC DOSE - LD50 Not Available
CARCINOGENICITY No evidence of carcinogenic properties
MUTAGENICITY/TERATOGENICITY Chronic exposure is associated with subtle effects to the male reproductive system and, if exposed, the developing fetus.
TOXICOLOGICAL FINDINGS Also harmful in contact with skin. Particular care must be exercised when machining and creating dust or particles. Human exposure to lead, both acutely and chronically, is associated with well defined adverse effects to health. The target organs are blood, kidney and nervous system for acute exposure to toxic amounts. Lead accumulates in exposed individuals and approximately 90% of the absorbed dose remains deposited in the bone. Removal from exposure can reverse effects to the blood, male reproductive system, and to a limited extent the central nervous system.


SECTION 12. ECOLOGICAL INFORMATION

The following applies to inorganic fluorides in general: biological effects: fish: L idus LC50 660mg/l; bacteria:Ps putida toxic from 231 mg/l up; algae: Sc quadricauda toxic from 249mg/l up; protozoa:E.sulcatum toxic from 101mg/l up; U parduczi toxic from 71mg/l up (all values as NaF). Hazard to drinking water.


SECTION 13. DISPOSAL CONSIDERATIONS

DISPOSAL METHODS: Chemical residues are generally classified as special waste, and are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company.


SECTION 14. TRANSPORT INFORMATION

Class UN Packing Group Proper Shipping Name
6.1 2291 III Lead compounds, soluble, N.O.S. (Lead II Fluoride)


SECTION 15. REGULATORY INFORMATION

Hazard Symbols: Xn – Harmful N – Dangerous for the Environment
Risk Phrases: R20/22 Harmful by inhalation and if swallowed.
R33 Danger of cumulative effects
Safety Phrases: S13 Keep away from food, drink and animal feeding stuffs.
S22/21 When using do not eat, drink or smoke
Note that the Risk and Safety Phrases included here for completeness are being replaced with the GHS Hazard and Precautionary statements given in section 2.
TSCA INVENTORY ITEM: Yes


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lead(II) Fluoride

Lead Fluoride is a water insoluble Lead source for use in oxygen-sensitive applications, such as metal production. Fluoride compounds have diverse applications in current technologies and science, from oil refining and etching to synthetic organic chemistry and the manufacture of pharmaceuticals. Magnesium Fluoride, for example, was used by researchers at the Max Planck Institute for Quantum Optics in 2013 to create a novel mid-infrared optical frequency comb composed of crystalline microresonators, a development that may lead to future advances in molecular spectroscopy. Fluorides are also commonly used to alloy metals and for optical deposition. Lead Fluoride is generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lead(II) Fluoride Synonyms

Lead fluoride, Lead(2+) fluoride, Lead difluoride, Plomb fluorure, Plumbous fluoride

Lead(II) Fluoride Chemical Identifiers

Linear Formula

PbF2

Pubchem CID

24549

MDL Number

MFCD00011162

EC No.

231-998-8

Beilstein Registry No.

N/A

IUPAC Name

difluorolead

SMILES

F[Pb]F

InchI Identifier

InChI=1S/2FH.Pb/h2*1H;/q;;+2/p-2

InchI Key

FPHIOHCCQGUGKU-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

Lead Bohr ModelSee more Lead products. Lead (atomic symbol: Pb, atomic number: 82) is a Block P, Group 14, Period 6 element with an atomic radius of 207.2. The number of electrons in each of Lead's shells is [2, 8, 18, 32, 18, 4] and its electron configuration is [Xe] 4f14 5d10 6s2 6p2. The lead atom has a radius of 175 pm and a Van der Waals radius of 202 pm. In its elemental form, lead has a metallic gray appearance. Lead occurs naturally as a mixture of four stable isotopes: 204Pb (1.48%), 206Pb (23.6%), 207Pb (22.6%), and 208Pb (52.3%). Elemental LeadLead is obtained mainly from galena (PbS) by a roasting process. Anglesite, cerussite, and minim are other common lead containing minerals. Lead does occur as a free element in nature, but it is rare. It is a dense, soft metal that is very resistant to corrosion and poorly conductive compared to other metals. Its density and low melting point make it useful in applications such as electrolysis and industrial materials.

Recent Research

Intense 2.7μm emission in Er(3+) doped zinc fluoride glass., Huang, Feifei, Guo Yanyan, Tian Ying, Xu Shiqing, and Zhang Junjie , Spectrochim Acta A Mol Biomol Spectrosc, 2017 May 15, Volume 179, p.42-45, (2017)

Highly selective "turn-on" fluorescent sensing of fluoride ion based on a conjugated polymer thin film-Fe(3+) complex., Ding, Wanchuan, Xu Jingkun, Wen Yangping, Zhang Jie, Liu Hongtao, and Zhang Zhouxiang , Anal Chim Acta, 2017 May 15, Volume 967, p.78-84, (2017)

A selective chemosensor for fluoride ion and its interaction with Calf Thymus DNA., Ghosh, Soumen, Masum Abdulla Al, Ganguly Aniruddha, Islam Md Maidul, Alam Md Akhtarul, and Guchhait Nikhil , Spectrochim Acta A Mol Biomol Spectrosc, 2017 May 05, Volume 178, p.24-31, (2017)

Upconversion color tuning in Ce(3+)-doped LiYF4:Yb(3+)/Ho(3+)@LiYF4 nanoparticles towards ratiometric fluorescence detection of chromium(III)., Liu, Shijiang, Li Yangjie, Zhang Cheng, Yang Liang, Zhao Tingting, Zhang Ruilong, and Jiang Changlong , J Colloid Interface Sci, 2017 May 01, Volume 493, p.10-16, (2017)

Tunable passively Q-switched thulium-fluoride fiber laser in the S+/S band (1450.0 to 1512.0  nm) region using a single-walled carbon-nanotube-based saturable absorber., Ahmad, H, Reduan S A., Zulkifli A Z., and Tiu Z C. , Appl Opt, 2017 May 01, Volume 56, Issue 13, p.3841-3847, (2017)

Thulium fiber pumped tunable Ho:CaF2 laser., Němec, Michal, Šulc Jan, Jelínek Michal, Kubeček Václav, Jelínková Helena, Doroshenko Maxim E., Alimov Olimkhon K., Konyushkin Vasilii A., Nakladov Andrei N., and Osiko Vyatcheslav V. , Opt Lett, 2017 May 01, Volume 42, Issue 9, p.1852-1855, (2017)

Can Spatiotemporal Fluoride ((18)F(-)) Uptake be Used to Assess Bone Formation in the Tibia? A Longitudinal Study Using PET/CT., Lundblad, Henrik, Karlsson-Thur Charlotte, Maguire Gerald Q., Jonsson Cathrine, Noz Marilyn E., Zeleznik Michael P., and Weidenhielm Lars , Clin Orthop Relat Res, 2017 May, Volume 475, Issue 5, p.1486-1498, (2017)

Synthesis of Novel Thiazole Based Carbaldehyde as Potential Sensor for Fluoride Anion and their Spectroscopic Properties., Tayade, Rajratna P., and Sekar Nagaiyan , J Fluoresc, 2017 May, Volume 27, Issue 3, p.1117-1128, (2017)

In vitro enamel erosion and abrasion-inhibiting effect of different fluoride varnishes., Alexandria, Adílis Kalina, Vieira Thiago Isidro, Pithon Matheus Melo, Fidalgo Tatiana Kelly da S., Fonseca-Gonçalves Andréa, Valença Ana Maria Gond, Cabral Lúcio Mendes, and Maia Lucianne Cople , Arch Oral Biol, 2017 May, Volume 77, p.39-43, (2017)

Characterization and extinction measurement of potassium terbium fluoride single crystal for high laser power applications., Jalali, Amir A., Rogers Evan, and Stevens Kevin , Opt Lett, 2017 Mar 01, Volume 42, Issue 5, p.899-902, (2017)

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