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Lead Oxide Nanoparticles / Nanopowder

CAS #:

Linear Formula:

PbO

MDL Number:

MFCD00011164

EC No.:

215-267-0

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Lead Oxide Nanopowder
PB-OX-02-NP
Pricing > SDS > Data Sheet >
(3N) 99.9% Lead Oxide Nanopowder
PB-OX-03-NP
Pricing > SDS > Data Sheet >
(4N) 99.99% Lead Oxide Nanopowder
PB-OX-04-NP
Pricing > SDS > Data Sheet >
(5N) 99.999% Lead Oxide Nanopowder
PB-OX-05-NP
Pricing > SDS > Data Sheet >
(6N) 99.9999% Lead Oxide Nanopowder
PB-OX-06-NP
Pricing > SDS > Data Sheet >

Lead Oxide Nanoparticles / Nanopowder Properties

Compound Formula OPb
Molecular Weight 223.2
Appearance Red or Yellow Crystalline Solid
Melting Point 888 °C (1630 °F)
Boiling Point 1477 °C (2691 °F)
Density (Theoretical) 9.53 g/cm3
Exact Mass 223.972
Monoisotopic Mass 223.972

Lead Oxide Nanoparticles / Nanopowder Health & Safety Information

Signal Word Danger
Hazard Statements H302 + H332-H351-H360Df-H362-H372-H410
Hazard Codes T,N
Precautionary Statements P201-P260-P263-P280-P301 + P312 + P330-P308 + P313
Risk Codes 61-20/22-33-50/53-62
Safety Statements 53-45-60-61
RTECS Number OG1750000
Transport Information UN 2291 6.1 / PGIII
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 12/18/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lead Oxide Nanoparticles / Nanopowder

Product Number: All applicable American Elements product codes, e.g. PB-OX-02-NP , PB-OX-03-NP , PB-OX-04-NP , PB-OX-05-NP , PB-OX-06-NP

CAS #: 1317-36-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
Repr. 1A H360 May damage fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Hazards not otherwise classified No information known.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Exclamation Mark - GHS07 Health Hazard - GHS08

GHS07 GHS08
Signal word Danger
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P281 Use personal protective equipment as required.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2


Health (acute effects) = 2
Flammability = 0
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
1317-36-8 Lead(II) oxide
Identification number(s):
EC number: 215-267-0
Index number: 082-001-00-6


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Lead oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1317-36-8 Lead(II) oxide (100.0%)
PEL (USA) Long-term value: 0.05 mg/m³
as Pb; See 29 CFR 1910.1025
REL (USA) Long-term value: 0.05* mg/m³
as Pb;*8-hr TWA; See Pocket Guide App. C
TLV (USA) Long-term value: 0.05 mg/m³
as Pb; BEI
EL (Canada) Long-term value: 0.05 mg/m³
as Pb; IARC 2A, R
EV (Canada) Long-term value: 0.05 mg/m³
as Pb, Skin (organic compounds)
Ingredients with biological limit values:
1317-36-8 Lead(II) oxide (100.0%)
BEI (USA) 30 μg/100 ml
Medium: blood
Time: not critical
Parameter: Lead
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if airpurifying
respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves Nitrile rubber, NBR
Penetration time of glove material (in minutes) Not determined
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder or solid in various forms
Color: Yellow
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 886 °C (1627 °F)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous) Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 9.53 g/cm³ (79.528 lbs/gal)
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts with strong oxidizing agents
Conditions to avoid No further relevant information available.
Incompatible materials:
Acids
Oxidizing agents
Hazardous decomposition products: Lead oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this substance.
Carcinogenicity:
EPA-B2: Probable human carcinogen, sufficient evidence from animal studies; inadequate evidence or no data from epidemiologic studies.
NTP-R: Reasonably anticipated to be a carcinogen: limited evidence from studies in humans or sufficient evidence from studies in experimental animals.
ACGIH A3: Animal carcinogen: Agent is carcinogenic in experimental animals at a relatively high dose, by route(s) of administration, at site(s), of histologic type(s),
or by mechanism(s) not considered relevant to worker exposure. Available epidemologic studies do not confirm an increased risk of cancer in exposed humans.
Available evidence suggests that the agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure.
IARC-2A: Probably carcinogenic to humans: limited human evidence; sufficient evidence in experimental animals
Reproductive toxicity:
May damage fertility or the unborn child.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure: May cause damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark: Very toxic for aquatic organisms
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN3077
UN proper shipping name
DOT Environmentally hazardous substances, solid, n.o.s. (Lead(II) oxide)
IMDG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead(II)
oxide)
Transport hazard class(es)
DOT, IMDG
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Class 9 (M7) Miscellaneous dangerous substances and articles
Label 9
IATA
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Special marking (ADR): Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
EMS Number: F-A,S-F
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3077, Environmentally hazardous substances, solid, n.o.s. (Lead(II) oxide), 9, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS07 GHS08
Signal word Danger
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P281 Use personal protective equipment as required.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
1317-36-8 Lead(II) oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
1317-36-8 Lead(II) oxide
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
This substance is included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH).
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lead Oxide Nanoparticles / Nanopowder

Lead Oxide ( PbO) Nanopowder or Nanoparticles, nanodots or nanocrystals are spherical or faceted high surface area oxide magnetic nanostructured particles. Nanoscale Lead Oxide Particles are typically 20-40 nanometers (nm) with specific surface area (SSA) in the 30 - 50 m2/g range and also available in with an average particle size of 100 nm range with a specific surface area of approximately 7 m2/g. Nano Lead Oxide Particles are also available in ultra high purity and high purity, transparent, and coated and dispersed forms. They are also available as a nanofluid through the AE Nanofluid production group. Nanofluids are generally defined as suspended nanoparticles in solution either using surfactant or surface charge technology. Nanofluid dispersion and coating selection technical guidance is also available. Other nanostructures include nanorods, nanowhiskers, nanohorns, nanopyramids and other nanocomposites. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers.

Lead Oxide Nanoparticles / Nanopowder Synonyms

Lead oxide (PbO), lead-contg, lead monoxide, lead(2+); oxygen(2-)

Chemical Identifiers

Linear Formula PbO
MDL Number MFCD00011164
EC No. 215-267-0
Beilstein Registry No. N/A
Pubchem CID 14827
IUPAC Name oxolead
SMILES O=[Pb]
InchI Identifier InChI=1S/O.Pb
InchI Key YEXPOXQUZXUXJW-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Lead Bohr ModelSee more Lead products. Lead (atomic symbol: Pb, atomic number: 82) is a Block P, Group 14, Period 6 element with an atomic radius of 207.2. The number of electrons in each of Lead's shells is [2, 8, 18, 32, 18, 4] and its electron configuration is [Xe] 4f14 5d10 6s2 6p2. The lead atom has a radius of 175 pm and a Van der Waals radius of 202 pm. In its elemental form, lead has a metallic gray appearance. Lead occurs naturally as a mixture of four stable isotopes: 204Pb (1.48%), 206Pb (23.6%), 207Pb (22.6%), and 208Pb (52.3%). Elemental LeadLead is obtained mainly from galena (PbS) by a roasting process. Anglesite, cerussite, and minim are other common lead containing minerals. Lead does occur as a free element in nature, but it is rare. It is a dense, soft metal that is very resistant to corrosion and poorly conductive compared to other metals. Its density and low melting point make it useful in applications such as electrolysis and industrial materials.

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