SECTION 1. IDENTIFICATION

Product Name: Lead Tungstate

Product Number: All applicable American Elements product codes, e.g. PB-WO-02 , PB-WO-03 , PB-WO-04 , PB-WO-05

CAS #: 7759-01-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887

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SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral(Category 4), H302
Acute toxicity, Inhalation(Category 4), H332
Carcinogenicity(Category 1B), H350
Reproductive toxicity(Category 1A), H360
Specific target organ toxicity -repeated exposure(Category 2), H373
Acute aquatic toxicity(Category 1), H400
Chronic aquatic toxicity(Category 1), H410
GHS Label elements, including precautionary statements
Pictogram

Signal word
Danger
Hazard statement(s)
H302 + H332
Harmful if swallowed or if inhaled
H350
May cause cancer.
H360
May damage fertility or the unborn child.
H373
May cause damage to organs through prolonged or repeated exposure.
H410
Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264
Wash skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P273
Avoid release to the environment.
P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 + P330
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.
P304 + P340 + P312
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.
P308 + P313
IF exposed or concerned: Get medical advice/ attention.
P391
Collect spillage.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula: O4PbW
Molecular weight: 455.04 g/mol
CAS-No.: 7759-01-5
EC-No.: 231-849-7

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Tungsten oxide, Lead oxides
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: solid
Odour
No data available
Odour Threshold
No data available
pH
No data available
Melting point/freezing point
No data available
Initial boiling point and boiling range
No data available
Flash point
Not applicable
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapour pressure
No data available
Vapour density
No data available
Relative density
No data available
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-No data available
In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
3-Group 3: Not classifiable as to its carcinogenicity to humans(Lead(II) tungstate)
2A-Group 2A: Probably carcinogenic to humans(Lead(II) tungstate)
IARC:
3-Group 3: Not classifiable as to its carcinogenicity to humans(Lead(II) tungstate)
2A-Group 2A: Probably carcinogenic to humans(Lead(II) tungstate)
NTP:
Reasonably anticipated to be a human carcinogenThe reference note has been added by TD
based on the background information of the NTP.(Lead(II) tungstate)
OSHA:
OSHA specifically regulated carcinogen(Lead(II) tungstate)
Reproductive toxicity
No data available
Known human reproductive toxicant
Specific target organ toxicity -single exposure
No data available
Specific target organ toxicity -repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Lead salts have been reported to cross the placenta and to induce embryo-and feto-mortality. They also have teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development, and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous, and digestive systems.
The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular dysfunction, possible paralysis, and encephalopathy can result. Additional symptoms of overexposure include: joint and muscle pain, weakness of the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal pain, diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia, and metallic taste. High body levels produce increased cerebrospinal pressure, brain damage, and stupor leading to coma and often death.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Very toxic to aquatic life with long lasting effects.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 2291
Class: 6.1
Packing group: III
Proper shipping name: Lead compounds, soluble, n.o.s.(Lead(II) tungstate)
Reportable Quantity(RQ):
Poison Inhalation Hazard: No
IMDG
UN number: 2291
Class: 6.1
Packing group: III
EMS-No: F-A, S-A
Proper shipping name: LEAD COMPOUND, SOLUBLE, N.O.S.(Lead(II) tungstate)
Marine pollutant: yes
IATA
UN number: 2291
Class: 6.1
Packing group: III
Proper shipping name: Lead compound, soluble, n.o.s.(Lead(II) tungstate)

SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Lead(II) tungstate
CAS-No.
7759-01-5
Revision Date
1993-04-24
Pennsylvania Right To Know Components
Lead(II) tungstate
CAS-No.
7759-01-5
Revision Date
1993-04-24
New Jersey Right To Know Components
Lead(II) tungstate
CAS-No.
7759-01-5
Revision Date
1993-04-24
California Prop. 65 Components
WARNING! This product contains a chemical known to the State of California to cause cancer.
Lead(II) tungstate

16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.