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Lithium Hydroxide

CAS #:

Linear Formula:

LiOH

MDL Number:

MFCD00011095

EC No.:

215-183-4

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Lithium Hydroxide
LI-OH-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Lithium Hydroxide
LI-OH-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Lithium Hydroxide
LI-OH-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Lithium Hydroxide
LI-OH-05
Pricing > SDS > Data Sheet >

Lithium Hydroxide Properties (Theoretical)

Compound Formula HLiO
Molecular Weight 23.95
Appearance White Solid
Melting Point 462° C (863.6° F)
Boiling Point 924° C (1,695° F)
Density 1.46 g/cm3
Solubility in H2O 12.8 g/100 mL (20 °C)
Refractive Index 1.464
Exact Mass 24.018744
Monoisotopic Mass 24.018744

Lithium Hydroxide Health & Safety Information

Signal Word Danger
Hazard Statements H301-H314-H331
Hazard Codes C
Risk Codes 22-35
Safety Statements 26-36/37/39-45
RTECS Number N/A
Transport Information UN 2680 8/PG 2
WGK Germany 2
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/22/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lithium Hydroxide

Product Number: All applicable American Elements product codes, e.g. LI-OH-02 , LI-OH-03 , LI-OH-04 , LI-OH-05

CAS #: 1310-65-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H331 Toxic if inhaled.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1
H318 Causes serious eye damage.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms

Corrosion - GHS05 Skull and Crossbones - GHS06

GHS05 GHS06
Signal word
Danger
Hazard statements
H301+H331 Toxic if swallowed or if inhaled.
H314
Causes severe skin burns and eye damage.
Precautionary statements
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER/doctor/...
WHMIS classification
D1A - Very toxic material causing immediate and serious toxic effects
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
1310-65-2 Lithium hydroxide
Identification number(s):
EC number:
215-183-4


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Lithium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to enter drains, sewage systems, or other water courses.
Methods and materials for containment and cleanup:
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from air.
Store away from water/moisture.
Do not store together with acids.
Store away from oxidizing agents.
Further information about storage conditions:
Store under dry inert gas.
This product is hygroscopic.
This product is air sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and water.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1310-65-2 Lithium hydroxide (100.0%)
WEEL (USA) Ceiling limit value: 1 mg/m3
EL (Canada) Short-term value: C 1 mg/m3
EV (Canada) Short-term value: 1 mg/m3
anyhydrous
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use self-contained respiratory protective device in emergency situations.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Penetration time of glove material (in minutes)
No data available
Eye protection:
Tightly sealed goggles
Full face protection
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: White
Odor: Odorless
Odor threshold: No data available.
pH (0.4 g/l) at 20 °C (68 °F): 14
Melting point/Melting range: 462 °C (864 °F)
Boiling point/Boiling range: 924 °C (1695 °F)
Sublimation temperature / start: No data available
Flammability (solid, gas)
No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 2.54 g/cm3 (21.196 lbs/gal)
Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in / Miscibility with Water at 20 °C (68 °F): 71 g/l Soluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No data available
Incompatible materials:
Acids
Air
Water/moisture
Oxidizing agents
Hazardous decomposition products:
Lithium oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Toxic if inhaled.
Toxic if swallowed.
Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification:
Oral
LD50
210 mg/kg (rat)
Inhalative LC50/4H 960 mg/m3/4H (rat)
Skin irritation or corrosion:
Causes severe skin burns.
Eye irritation or corrosion:
Causes serious eye damage.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pHs. A high pH harms aquatic organisms. In the dilution of the use-level the pH is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Recommended cleansing agent:
Water, if necessary with cleansing agents.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN2680
UN proper shipping name
DOT
Lithium hydroxide
IMDG, IATA
LITHIUM HYDROXIDE
Transport hazard class(es)
DOT
Class
8 Corrosive substances.
Label
8
Class
8 (C6) Corrosive substances
Label
8
IMDG, IATA
Class
8 Corrosive substances.
Label
8
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
N/A
Special precautions for user
Warning: Corrosive substances
EMS Number: F-A,S-B
Segregation groups
Alkalis
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN2680, Lithium hydroxide, 8, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS GHS label elements, including precautionary statements
Hazard pictograms
GHS05
GHS06
Signal word
Danger
Hazard statements
H301+H331 Toxic if swallowed or if inhaled.
H314
Causes severe skin burns and eye damage.
Precautionary statements
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER/doctor/...
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lithium Hydroxide

Lithium Hydroxide is a highly water insoluble crystalline Lithium source for uses compatible with higher (basic) pH environments. Hydroxide, the OH- anion composed of an oxygen atom bonded to a hydrogen atom, is commonly present in nature and is one of the most widely studied molecules in physical chemistry. Hydroxide compounds have diverse properties and uses, from base catalysis to detection of carbon dioxide. In a watershed 2013 experiment, scientists at JILA (the Joint Institute for Laboratory Astrophysics) achieved evaporative cooling of compounds for the first time using hydroxide molecules, a discovery that may lead to new methods of controlling chemical reactions and could impact a range of disciplines, including atmospheric science and energy production technologies. Lithium Hydroxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lithium Hydroxide Synonyms

Lithium hydrate; Lithium hydroxide anhydrous; Lithine

Chemical Identifiers

Linear Formula LiOH
MDL Number MFCD00011095
EC No. 215-183-4
Beilstein Registry No. N/A
Pubchem CID 3939
IUPAC Name lithium hydroxide
SMILES [Li+].[OH-]
InchI Identifier InChI=1S/Li.H2O/h;1H2/q+1;/p-1
InchI Key WMFOQBRAJBCJND-UHFFFAOYSA-M

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Lithium Bohr ModelSee more Lithium products. Lithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics.

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