CAS #:

Linear Formula:

LiNb(OC2H5)6

MDL Number:

MFCD00210625

EC No.:

N/A

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
Lithium Niobium Ethoxide
LINB-ETOX-01
Pricing > SDS > Data Sheet >

Lithium Niobium Ethoxide Properties (Theoretical)

Compound Formula C12H30LiNbO6
Molecular Weight 370.21
Appearance Pale Yellow Liquid
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 370.126621
Monoisotopic Mass 370.126621

Lithium Niobium Ethoxide Health & Safety Information

Signal Word Danger
Hazard Statements H225-H315-H319
Hazard Codes F, C, Xi
Risk Codes 11-36/38
Safety Statements 16-26-37
RTECS Number N/A
Transport Information UN1170 3/PG II
WGK Germany N/A
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/19/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Lithium Niobium Ethoxide

Product Number: All applicable American Elements product codes, e.g. LINB-ETOX-01

CAS #: 86745-52-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements

Flame - GHS02 Corrosion - GHS05 Exclamation Mark - GHS07

Signal Word
Danger
Hazard Statements
Highly flammable liquid and vapor
Causes severe skin burns and eye damage
May cause respiratory irritation
Precautionary Statements
Prevention
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component
Ethyl alcohol 64-17-5
Lithium niobium ethoxide 86745-52-0


SECTION 4. FIRST AID MEASURES

General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Call a physician
immediately.
Inhalation If not breathing, give artificial respiration. Remove from exposure, lie down. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration
with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
medical device. Call a physician immediately.
Ingestion Do NOT induce vomiting. Clean mouth with water. Never give anything by mouth to an
unconscious person. Call a physician immediately.
Most important symptoms and effects
Causes burns by all exposure routes. Difficulty in breathing. Inhalation of high vapor
concentrations may cause symptoms like headache, dizziness, tiredness, nausea and
vomiting: Product is a corrosive material. Use of gastric lavage or emesis is
contraindicated. Possible perforation of stomach or esophagus should be investigated:
Ingestion causes severe swelling, severe damage to the delicate tissue and danger of
perforation
Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media Carbon dioxide (CO 2). Powder. Water spray. In case of major fire and large quantities:
Evacuate area. Fight fire remotely due to the risk of explosion. CO 2, dry chemical, dry sand,
alcohol-resistant foam. Water mist may be used to cool closed containers.
Unsuitable Extinguishing Media No information available
Flash Point 17 °C / 62.6 °F
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.
Hazardous Combustion Products
Carbon monoxide (CO). Carbon dioxide (CO2). Lithium oxide. Niobium oxide.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Take precautionary measures against static discharges.
Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system.
Methods for Containment and Clean Up
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.
Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.


SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on
clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not
ingest. If swallowed then seek immediate medical assistance. Keep away from open
flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition
of vapors by static electricity discharge, all metal parts of the equipment must be grounded.
Take precautionary measures against static discharges.
Storage Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep away from heat, sparks and flame.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Ensure adequate ventilation, especially in confined areas. Use explosion-proof
electrical/ventilating/lighting/equipment.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid
Appearance Yellow
Odor Alcohol
Odor Threshold No information available
pH No information available
Melting Point/Range No data available
Boiling Point/Range No information available
Flash Point 17 °C / 62.6 °F
Evaporation Rate No information available
Flammability (solid,gas) Not applicable
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure <=1100 hPa @ 50 °C
Vapor Density No information available
Specific Gravity No information available
Solubility Reacts with water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity No information available
Molecular Formula LiNb(OC2 H5)6
Molecular Weight 370.21


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Moisture sensitive.
Conditions to Avoid Keep away from open flames, hot surfaces and sources of ignition.
Incompatible Materials Acids, Reducing Agent, Acid chlorides, Acid anhydrides, Oxidizing agent
Hazardous Decomposition ProductsCarbon monoxide (CO), Carbon dioxide (CO2), Lithium oxide, Niobium oxide
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Vapor LC50 Based on ATE data, the classification criteria are not met. ATE > 20 mg/l.
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and delayed
Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting: Product is a corrosive material. Use of gastric lavage or
emesis is contraindicated. Possible perforation of stomach or esophagus should be
investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and
danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Contains a substance which is:. Toxic to aquatic organisms. The product contains following substances which are hazardous for the environment. May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.
Persistence and Degradability May persist based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Is not likely mobile in the environment due its low water solubility.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN1170
Proper Shipping Name Ethanol solution
Hazard Class 3
Packing Group II
TDG
UN-No UN1170
Proper Shipping Name Ethanol solution
Hazard Class 3
Packing Group II
IATA
UN-No UN1170
Proper Shipping Name Ethanol solution
Hazard Class 3
Packing Group II
IMDG/IMO
UN-No UN1170
Proper Shipping Name Ethanol solution
Hazard Class 3
Packing Group II


SECTION 15. REGULATORY INFORMATION

TSCA 12(b) - Notices of Export Not applicable
U.S. Federal Regulations
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lithium Niobium Ethoxide

Lithium Niobium Ethoxide is an organometallic compound used as a precursor for chemical vapor deposition of thin films for lithium ion battery electrolyte materials. American Elements can produce most materials in high purity and ultra high purity (up to 99.99999%) forms and follows applicable ASTM testing standards; a range of grades are available including Mil Spec (military grade), ACS, Reagent and Technical Grade, Food, Agricultural and Pharmaceutical Grade, Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia). We can also produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. Typical and custom packaging is available, as is additional research, technical and safety (MSDS) data.

Lithium Niobium Ethoxide Synonyms

Lithium niobium ethanolate

Chemical Identifiers

Linear Formula LiNb(OC2H5)6
MDL Number MFCD00210625
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 14693679
IUPAC Name lithium; ethanolate; niobium(5+)
SMILES [Li+].CC[O-].CC[O-].CC[O-].CC[O-].CC[O-].CC[O-].[Nb+5]
InchI Identifier InChI=1S/6C2H5O.Li.Nb/c6*1-2-3;;/h6*2H2,1H3;;/q6*-1;+1;+5
InchI Key AVEKRHJBCCYCED-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Lithium

Lithium Bohr ModelSee more Lithium products. Lithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics.

Niobium

See more Niobium products. Niobium (atomic symbol: Nb, atomic number: 41) is a Block D, Group 5, Period 5 element with an atomic weight of 92.90638. Niobium Bohr ModelThe number of electrons in each of niobium's shells is 2, 8, 18, 12, 1 and its electron configuration is [Kr] 4d4 5s1. The niobium atom has a radius of 146 pm and a Van der Waals radius of 207 pm. Niobium was discovered by Charles Hatchett in 1801 and first isolated by Christian Wilhelm Blomstrand in 1864. In its elemental form, niobium has a gray metallic appearance. Niobium has the largest magnetic penetration depth of any element and is one of three elemental type-II superconductors (Elemental Niobiumalong with vanadium and technetium). Niobium is found in the minerals pyrochlore, its main commercial source, and columbite. The word Niobium originates from Niobe, daughter of mythical Greek king Tantalus.

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