Magnesium Hexafluorophosphate

Linear Formula:

Mg(PF₆)₂

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT	Product Code	ORDER	SAFETY DATA	TECHNICAL DATA
(1N8) 98% Magnesium Hexafluorophosphate (Gel)	MG-PF6-018-GL	Pricing >	SDS >	Data Sheet >
(2N) 99% Magnesium Hexafluorophosphate	MG-PF6-02	Pricing >	SDS >	Data Sheet >
(3N) 99.9% Magnesium Hexafluorophosphate	MG-PF6-03	Pricing >	SDS >	Data Sheet >
(4N) 99.99% Magnesium Hexafluorophosphate	MG-PF6-04	Pricing >	SDS >	Data Sheet >
(5N) 99.999% Magnesium Hexafluorophosphate	MG-PF6-05	Pricing >	SDS >	Data Sheet >

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Magnesium Hexafluorophosphate Properties (Theoretical)

Compound Formula	F₁₂MgP₂
Molecular Weight	314.25
Appearance	Colorless crystals or gel
Melting Point	N/A
Boiling Point	N/A
Density	N/A
Solubility in H2O	N/A
Exact Mass	313.913404
Monoisotopic Mass	313.913404

Magnesium Hexafluorophosphate Health & Safety Information

Signal Word	Danger
Hazard Statements	H314-H302+H312+H332
Hazard Codes	C
Precautionary Statements	P260-P301+P330+P33-P303+P361+P353-P305+P351+P338-P405-P501
Risk Codes	N/A
Safety Statements	N/A
Transport Information	UN 3264 8/PG II
GHS Pictograms	GHS05 Corrosive GHS07 Exclamation Point

View and Print SDS

SAFETY DATA SHEET

Date Created: 5/15/2015

Date Revised: 5/15/2015

SECTION 1. IDENTIFICATION

Product Name: Magnesium Hexafluorophosphate

Product Number: All applicable American Elements product codes, e.g. MG-PF6-018-GL, MG-PF6-02, MG-PF6-03, MG-PF6-04, MG-PF6-05

Relevant identified uses of the substance: Scientific research and development

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1
H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms

GHS05 GHS07
Signal word
Danger
Hazard statements
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
H314
Causes severe skin burns and eye damage.
Precautionary statements
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Formula: Mg(PF6)2

SECTION 4. FIRST AID MEASURES

Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

SECTION 5. FIREFIGHTING MEASURES

Fire Fighting:
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Small spills/leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

SECTION 7. HANDLING AND STORAGE

Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation.
Keep from contact with moist air and steam.
Please do safeguard well, wear mask and glove. Use plastic spoon to separate it , then sealed stock in plastic bottle.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal Protection:
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin
exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects: Effects may be delayed.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colorless Gel
Molecular Weight: 314.25

SECTION 10. STABILITY AND REACTIVITY

Incompatibilities:
Moisture, water, strong oxidizing agents.
Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Hygroscopic: absorbs moisture or water from the air.
Decomposition:
Phosphine, oxides of phosphorus, irritating and toxic fumes and gases, hydrogen fluoride.

SECTION 11. TOXICOLOGICAL INFORMATION

Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Skin: Causes skin irritation.
Eyes: Causes eye irritation. May cause chemical conjunctivitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.

SECTION 12. ECOLOGICAL INFORMATION

GENERAL NOTES
Do not allow material to be released to the environment without official permits.

SECTION 13. DISPOSAL CONSIDERATIONS

APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.

SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN-Number: 3264 Class: 8 Packing group: II
Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s. (Magnesium Hexafluorophosphate)
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN-Number: 3264 Class: 8 Packing group: II EMS-No: F-A, S-B
Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Magnesium Hexafluorophosphate )
Marine pollutant: No
IATA
UN-Number: 3264 Class: 8 Packing group: II
Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s. (Magnesium Hexafluorophosphate )
15. REGULATORY

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS GHS label elements, including precautionary statements
Hazard pictograms
GHS05
GHS07
Signal word
Danger
Hazard statements
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
H314
Causes severe skin burns and eye damage.
Precautionary statements
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.

16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Magnesium Hexafluorophosphate

Magnesium Hexafluorophosphate is a hygroscopic magnesium source for use in oxygen-sensitive applications, such as metal production. In extremely low concentrations (ppm), fluoride compounds are used in health applications. Fluoride compounds also have significant uses in synthetic organic chemistry. They are commonly also used to alloy metal and for optical deposition. Certain fluoride compounds can be produced at nanoscale and in ultra high purity forms. Magnesium Hexafluorophosphate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards. Typical and custom packaging is available, as is additional research, technical and safety (MSDS) data. Please contact us for information on lead time and pricing above.

Magnesium Hexafluorophosphate Synonyms

Magnesium Dihexafluorophosphate, Phosphate(1-), hexafluoro-, magnesium (2:1) (CAS No. 113359-60-7)

Chemical Identifiers

Linear Formula	Mg(PF₆)₂
MDL Number	N/A
EC No.	N/A
Beilstein Registry No.	N/A
Pubchem CID	14389152
IUPAC Name	magnesium; dihexafluorophosphate
SMILES	F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Mg+2]
InchI Identifier	InChI=1S/2F6P.Mg/c21-7(2,3,4,5)6;/q2-1;+2
InchI Key	BNMGWRMLSYNPEX-UHFFFAOYSA-N

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Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Magnesium products. Magnesium (atomic symbol: Mg, atomic number: 12) is a Block S, Group 2, Period 3 element with an atomic mass of 24.3050. The number of electrons in each of Magnesium's shells is [2, 8, 2] and its electron configuration is [Ne] 3s². The magnesium atom has a radius of 160 pm and a Van der Waals radius of 173 pm. Magnesium was discovered by Joseph Black in 1775 and first isolated by Sir Humphrey Davy in 1808. Magnesium is the eighth most abundant element in the earth's crust and the fourth most common element in the earth as a whole. Elemental Magnesium In its elemental form, magnesium has a shiny grey metallic appearance and is an extremely reactive. It is can be found in minerals such as brucite, carnallite, dolomite, magnesite, olivine and talc. Commercially, magnesium is primarily used in the creation of strong and lightweight aluminum-magnesium alloys, which have numerous advantages in industrial applications. The name "Magnesium" originates from a Greek district in Thessaly called Magnesia.

See more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s² 3p³. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s²2p⁵. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.