SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
The substance is not classified according to the Globally Harmonized System (GHS).
GHS label elements not applicable
Hazard pictograms not applicable
Signal word not applicable
Hazard statements not applicable
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P232 Protect from moisture.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
1
0 
0 
Health = 1
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*1
0 
0 
Health = *1
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS # / Substance Name
7773-01-5 Manganese dichloride
Identification number(s)
EC number: 231-869-6

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information: No special measures required.
If inhaled: Supply fresh air; consult doctor in case of complaints.
In case of skin contact: Generally the product does not irritate the skin.
In case of eye contact: Rinse opened eye for several minutes under running water.
If swallowed: If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No data available
Advice for firefighters
Protective equipment: No special measures required.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions: No special measures required.
Methods and materials for containment and cleanup: Pick up mechanically.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling No special measures required.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
Specific end use(s) No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
7773-01-5 manganese dichloride
PEL Ceiling limit value: 5 mg/m3
as Mn
REL Short-term value: 3 mg/m3
Long-term value: 1 mg/m3
as Mn
TLV Long-term value: 0.02* 0.1* mg/m³
as Mn; *respirable **inhalable fraction
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
ersonal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Breathing equipment: Not required.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies by manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection: Safety glasses